Magnetic recording medium comprising a specified binder resin, specified ferromagnetic metal powder and .alpha.-alumina

• US 5,242,752 A
• Filed: 11/04/1991
• Issued: 09/07/1993
• Est. Priority Date: 04/14/1988
• Status: Expired due to Term

• Current Assignee: Konica Corporation (Konica Minolta Inc.)
• Original Assignee: Konica Corporation (Konica Minolta Inc.)
• Inventors: Itozawa, Kenji, Mori, Takahiro, Koyama, Noboru, Isobe, Ryosuke
• Primary Examiner(s): Thibodeau, Paul J.
• Assistant Examiner(s): Resan, Stevan A.
• Application Number:
  US07/787,736
• Time in Patent Office: 673 Days
• Field of Search: 428/694, 428/900, 428/695, 428/425.9, 428/328, 428/329, 428/403, 428/412, 428/480, 428/522
• US Class Current: 428/329
• CPC Class Codes: G11B 5/702 characterised by the bonding agent
• CPC Class Codes: Y10S 428/90 Magnetic feature
• CPC Class Codes: Y10T 428/257 Iron oxide or aluminum oxide
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31609 Particulate metal or metal compound-containing
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A magnetic recording medium having a support and provided thereon, a magnetic layer containing a ferromagnetic metal powder and a binder is disclosed. The ferromagnetic powder comprises an adsorbed moisture of not less than 1.0 weight % and not more than 2.5 weight % of said ferromagnetic metal powder, a pH value of not less than 9.0 and not morer than 11.5, and a specific surface area of not less than 45 m² /g measured by a BET method; and the binder comprises at least one polar group selected from the group consisting of: ##STR1## wherein M represents an atom selected from the group consisting of hydrogen, lithium, sodium, and potassium; and M¹ and M² represent atoms of hydrogen, lithium, sodium and potassium, and an alkyl group, provided that M¹ and M² may be same with or different from each other.

Claims

1. A magnetic recording medium comprising a support having provided thereon a magnetic layer, said magnetic layer containing;

(1) a ferromagnetic powder having an adsorbed moisture content of 1.0% to 2.5% by weight based on said ferromagnetic powder,

a specific surface area of at least 45 m² /g as measured by the BET method, and

a pH value of 9.0 to 11.5,

(2) α

-alumina having a BET specific surface area of 11 m² /g to 35 m² /g; and

(3) a binder resin having at least one polar group selected form the group consisting of ##STR10## wherein M represents hydrogen, lithium, sodium, or potassium; and

M¹ and M² each represents hydrogen, lithium, sodium, potassium, or an alkyl group,

said resin having a molecular weight of 2,000 to 70,000, the molecular weight of said resin is 200 to 70,000 per polar group.

2. The recording medium of claim 1 wherein the moisture content is 1.0 to 2.0% by weight.

3. The recording medium of claim 1 wherein the surface area is at least 50 m² /gram.

4. The recording medium of claim 1 wherein the pH is 9.5 to 10.5.

5. The recording medium of claim 1 wherein the specific surface area of α

-alumina is 15 m² /gram to 28 m² /gram.

6. The recording medium of claim 1 wherein the binder resin comprises a vinyl chloride copolymer, polyurethane, polyester, or polycarbonate each having said polar group.

7. The recording medium of claim 1 wherein the ferromagnetic powder contains aluminum or nickel.

8. The recording medium of claim 1 wherein the magnetic layer further contains Cr₂ O₃ having an average particle size not larger than 0.5 μ

m.

9. The recording medium of claim 1 wherein the magnetic layer further contains carbon black having an average particle size of 40 μ

m to 400 μ

m.

10. A magnetic recording medium comprising a support having a magnetic layer provided thereon, said magnetic layer containing;

(1) a ferromagnetic powder having an adsorbed moisture content of 1.0% to 2.5% by weight based on said ferromagnetic powder, and a specific surface area of at least 45 m² /g as measured by the BET method and a pH value of 9.0-11.5;

(2) alpha alumina having a BET specific surface area of 11 m² /g to 35 m² /g,

(3) a fatty acid in an amount of not more than 4 mg/m², and a fatty acid ester in an amount of 5 mg/m² to 100 mg/m² based on said recording medium, as determined by extraction dipping said medium in cyclohexane for three minutes; and

(4) a binder resin having at least one polar group selected from the group consisting of;

##STR11## wherein M represents hydrogen, lithium, sodium, or potassium; and

M¹ and M² each represent hydrogen, lithium, sodium, potassium, or an alkyl group,

said resin having a molecular weight of 2,000 to 70,000, and each polar group having a molecular weight of 200 to 70,000.

11. The recording medium of claim 10 wherein the moisture content is 1.0 to 2.0% by weight.

12. The recording medium of claim 10 wherein the specific surface area is at least 50 m² /gram.

13. The recording medium of claim 10 wherein the pH of the ferromagnetic powder is 9.5 to 10.5.

14. The recording medium of claim 10 wherein the amount of fatty acid is 0.01 mg/m² to 3 mg/m², and the amount of fatty acid ester is 10 mg/m² to 80 mg/m².

15. The recording medium of claim 10 wherein the binder resin comprises a vinyl chloride copolymer, polyurethane, polyester, or polycarbonate each having said polar group.

16. The recording medium of claim 10 wherein the ferromagnetic powder contains aluminum or nickel.

17. The recording medium of claim 10 wherein the magnetic layer further contains Cr₂ O₃ having an average particle size not larger than 0.5 μ

m.

18. The recording medium of claim 10 wherein the magnetic layer further contains carbon black having an average particle size of 40 μ

m to 400 μ

m.