Process for zinc electroplating of aluminum strip

• US 5,245,847 A
• Filed: 02/06/1992
• Issued: 09/21/1993
• Est. Priority Date: 02/07/1991
• Status: Expired due to Fees

• Current Assignee: Sumitomo Metal Industries Limited (Nippon Steel Corporation)
• Original Assignee: Sumitomo Metal Industries Limited (Nippon Steel Corporation)
• Inventors: Bando, Seiji, Yoshimori, Hisao, Tsuji, Masanori, Fujita, Kazuyuki, Hoboh, Yoshihiko, Ueda, Naotaka
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Leader, William T.
• Application Number:
  US07/832,082
• Time in Patent Office: 593 Days
• Field of Search: 205/139, 205/172, 205/213, 205/222, 72/47
• US Class Current: 72/47
• CPC Class Codes: C25D 3/22 of zinc
• CPC Class Codes: C25D 5/44 Aluminium

Abstract

A process for zinc electroplating of aluminum strip which can be performed continuously at a high speed and a high current density. The process comprises subjecting aluminum strip to anodic electrolysis in an acidic solution which may be an acidic plating bath solution or a pickling solution before the strip is subjected to cathodic electrolysis in an acidic zinc plating bath to perform zinc electroplating.

Claims

1. A process for zinc electroplating and press forming of aluminum strip into an automobile body panel comprising sequential steps of subjecting aluminum strip to anodic electrolysis in an acidic solution so as to form a porous aluminum oxide coating on the aluminum strip, forming a zinc coating on the aluminum strip by cathodic electrolysis in an acidic zinc plating bath, and press forming the aluminum strip into an automobile body panel, the acidic solution being an acidic plating bath solution used in the subsequent cathodic electrolysis.

2. The process of claim 1, wherein the aluminum strip is subjected to anodic electrolysis for a period between 0.2 and 180 seconds.

3. The process of claim 2, wherein the duration of anodic electrolysis is less than 10 seconds.

4. The process of claim 1, wherein the anodic electrolysis is performed at a voltage of 300 V or less.

5. The process of claim 1, wherein the acidic solution for anodic electrolysis has a pH of 4 or less.

6. The process of claim 5, wherein the acidic solution for anodic electrolysis has a pH of 2.5 or less.

7. The process of claim 1, wherein the aluminum oxide coating has a thickness of at least 100 angstroms and the zinc electroplating provides a zinc or a zinc alloy coating anchored in the porous aluminum oxide coating.

8. The process of claim 1, wherein the zinc plating bath is a sulfate or chloride bath.

9. A process for zinc electroplating and press forming of aluminum strip comprising sequential steps of pretreating aluminum strip by alkaline degreasing, pickling the aluminum strip, subjecting the aluminum strip to anodic electrolysis in an acidic solution so as to form a porous aluminum oxide coating on the aluminum strip, zinc electroplating the aluminum strip by cathodic electrolysis in an acidic zinc plating bath, and press forming the aluminum strip, the acidic solution being an acidic plating bath solution used in the subsequent cathodic electrolysis.

10. The process of claim 9, wherein the aluminum strip is subjected to anodic electrolysis for a period between 0.2 and 180 seconds.

11. The process of claim 10, wherein the duration of anodic electrolysis is less than 10 seconds.

12. The process of claim 9, wherein the anodic electrolysis is performed at a voltage of 300 V or less.

13. The process of claim 9, wherein the acidic solution for anodic electrolysis has a pH of 4 or less.

14. The process of claim 13, wherein the acidic solution for anodic electrolysis has a pH of 2.5 or less.

15. The process of claim 9, wherein a body panel of an automobile is formed during the press forming step.

16. The process of claim 9, wherein the aluminum oxide coating has a thickness of at least 100 angstroms and the zinc electroplating provides a zinc or a zinc alloy coating anchored in the porous aluminum oxide coating.

17. The process of claim 9, wherein the zinc plating bath is a sulfate or chloride bath.