Removing unreacted dye from fabric: bath liquors treated with absorbent hydrotalcite

• US 5,246,467 A
• Filed: 03/18/1992
• Issued: 09/21/1993
• Est. Priority Date: 06/15/1990
• Status: Expired due to Fees

• Current Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Original Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Inventors: Concannon, Martin, Cockett, Keith R. F., Webb, Maurice
• Primary Examiner(s): CLINGMAN, A
• Application Number:
  US07/834,315
• Time in Patent Office: 552 Days
• Field of Search: 8/543, 8/618
• US Class Current: 8/543
• CPC Class Codes: B01D 15/00 Separating processes involving the treatment of liquids with solid sorbents using liquid sorbents B01D11/00; ion exchange processes or materials, sorbent materials in general B01J, e.g. sorbents for chromatography B01J20/281; for investigating or analysing materials G01N30/00; Apparatus therefor
• CPC Class Codes: C02F 1/281 using inorganic sorbents
• CPC Class Codes: D06P 1/38 using reactive dyes
• CPC Class Codes: D06P 5/02 After-treatment
• CPC Class Codes: Y10S 8/917 Wool or silk
• CPC Class Codes: Y10S 8/918 Cellulose textile

Abstract

It is necessary to remove unbound reactive dyes from the surfaces of textile substrates treated with dyes of this class; this is to ensure the dyed substrate is fast. In the invention dye is removed from a wash medium by contracting the medium with an absorbent, preferably a hydrotalcite-like material, which removes suspended dye. This removal allows re-use of the wash medium or its disposal.

Claims

1. In a method for dyeing a substrate in an aqueous dyebath, using a reactive dye and thereafter removing unreacted dye from the substrate by washing the substrate with water in a washing stage, the improvement whereby the amount of water used for removing the unreacted dye is minimized, said improvement comprising the steps of contacting the wash water containing the unreacted dye with an absorbent material which absorbs the unreacted dye in the wash water wherein the absorbent material is hydrotalcite-like material.

2. A method according to claim 1 wherein the wash water, after washing the colored substrate, is removed from the washing stage for contact with said absorbent and therafter returned to the washing stage for further use.

3. A method according to claim 1 or 2 wherein the washing stage is operated at a temperature in the range 60°

C. to 100°

C.

4. A method according to claim 1 or 2 wherein the absorbent material has a particle size, as measured by light scattering, less than 250 micron.

5. A method according to claim 1 or 2 wherein the absorbent is present in an amount of from 1% to 10% by weight of the substrate.