Process for the separation of plastics by flotation

• US 5,248,041 A
• Filed: 12/20/1991
• Issued: 09/28/1993
• Est. Priority Date: 09/14/1991
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Deiringer, Gunther, Edelmann, Gerhard, Rauxloh, Bernhard
• Primary Examiner(s): Lithgow, Thomas M.
• Application Number:
  US07/811,472
• Time in Patent Office: 648 Days
• Field of Search: 209/3, 209/4, 209/9, 209/11, 209/166, 209/167, 241/19, 241/20, 241/24, 241/DIG. 38, 241/21, 521/42.5, 521/43.5, 521/45, 521/46.5, 521/48, 521/48.5
• US Class Current: 209/166
• CPC Class Codes: B03B 1/04 by additives
• CPC Class Codes: B03D 1/002 Inorganic compounds
• CPC Class Codes: B03D 1/008 containing oxygen
• CPC Class Codes: B03D 1/02 Froth-flotation processes
• CPC Class Codes: B03D 2201/02 Collectors
• CPC Class Codes: B03D 2203/005 Fine and commodity chemicals
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 2017/0203 Separating plastics from plastics
• CPC Class Codes: B29B 2017/0248 Froth flotation, i.e. wherein gas bubbles are attached to suspended particles in an aerated liquid
• CPC Class Codes: B29K 2023/06 PE, i.e. polyethylene
• CPC Class Codes: B29K 2023/12 PP, i.e. polypropylene
• CPC Class Codes: B29K 2025/00 Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
• CPC Class Codes: B29K 2027/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling
• CPC Class Codes: Y10S 241/38 Solid waste disposal

Abstract

The invention relates to a process for separating off polyester plastics from a mixture of polyester, polyvinyl chloride and, if present, other plastics, wherein in the flotation the polyester remains as the residue and the polyvinyl chloride and, if present, other plastics are recovered in floated form, which comprises treating the mixture of plastics with an aqueous alkaline solution and separating off the polyester from polyvinyl chloride and, if present, other plastics by flotation.

Claims

1. A process for separating off polyester plastic from a plastics mixture containing polyester and polyvinyl chloride plastics, which comprises:

treating the plastics mixture with a sufficient amount of an aqueous alkaline solution to render the polyester plastic more hydrophilic than the polyvinyl chloride plastics, suspending and subjecting to froth flotation the thus-treated plastics mixture in a flotation zone, said froth flotation being carried out in the presence of at least one flotation froth-forming agent and a collecting agent comprising natural oils having a chain length of 8 to 20 carbon atoms or fatty acids having 8 to 20 carbon atoms, said at least one flotation froth forming agent being present with said collecting agent in a ratio range of from 9;

1 to 1;

9, whereby the polyester remains as the residue and the polyvinyl chloride becomes recoverably in froth floated form as a foam product, and separating off the polyester from the polyvinyl chloride by isolating the residue and the foam product.

2. The process as claimed in claim 1, wherein the proportion of the plastics mixture in the aqueous alkaline solution during the treating of the plastics mixture with the aqueous alkaline solution is about 1 to 30 parts by weight, relative to 100 parts by weight of the aqueous alkaline solution.

3. The process as claimed in claim 2, wherein said proportion of the plastics mixture in the aqueous alkaline solution is about 15 to 25 parts by weight, relative to 100 parts by weight of the aqueous alkaline solution.

4. The process as claimed in claim 1, wherein the aqueous alkaline solution is the solution of an alkaline earth metal oxide or alkali metal oxide, alkaline earth metal hydroxide or alkali metal hydroxide, alkaline earth metal carbonate or alkali metal carbonate or alkaline earth metal bicarbonate or alkali metal bicarbonate.

5. The process as claimed in claim 4, wherein the aqueous alkaline solution is an at least 2% by weight solution.

6. The process as claimed in claim 4, wherein the aqueous alkaline solution is a 5-15% by weight solution.

7. The process as claimed in claim 1, wherein said at least one flotation froth-forming agent is selected from the group consisting of alcohols, polyglycols, polyglycol esters and alkylpolyglycol ethers and the collecting agent is selected from mineral oils having a chain length of 8 to 20 carbon atoms.

8. The process as claimed in claim 1, wherein the plastics mixture comprises polyester plastic, polyvinyl chloride plastic and at least one plastic other than polyester or polyvinyl chloride plastic, and said plastic other than polyester or polyvinyl chloride plastic is recovered in froth floated form.

9. The process as claimed in claim 8, wherein in the plastics mixture the proportions of polyester, polyvinyl chloride and at least one plastic other than polyester or polyvinyl chloride plastic are in the following ranges:

1-99% by weight of polyester, 99-1% by weight of polyvinyl chloride, and 0-98% by weight of said at least one plastic other than polyester or polyvinyl chloride plastic.

10. The process as claimed in claim 1, wherein the polyester present in the plastics mixture is at least one of polyethylene terephthalate, polybutylene terephthalate, acid-modified polyester and glycol-modified polyester.

11. The process as claimed in claim 10, wherein in the plastics mixture the proportions of polyester and polyvinyl chloride are in the following ranges:

1-99% by weight of polyester and 99-1% by weight of polyvinyl chloride.

12. The process as claimed in claim 1, wherein the amount of flotation froth-forming agents and collecting agent is in the range of 100 to 3000 grams per metric ton of the plastics mixture.