Method and apparatus for cleaning stereolithographically produced objects

• US 5,248,456 A
• Filed: 05/17/1991
• Issued: 09/28/1993
• Est. Priority Date: 06/12/1989
• Status: Expired due to Term

• Current Assignee: 3D Systems, Inc. (3D Systems Corporation)
• Original Assignee: 3D Systems, Inc. (3D Systems Corporation)
• Inventors: Evans, Herbert E. Jr., Ertley, Ernest W., Hull, Charles W., Leyden, Richard N.
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US07/702,030
• Time in Patent Office: 865 Days
• Field of Search: 264/22, 264/37, 264/40.1, 264/69, 264/233, 264/308, 264/341, 264/343, 264/571, 425/135, 425/174.4, 425/404, 425/445, 156/64, 156/273.3, 156/273.5, 156/275.5, 156/307.1, 156/378, 156/379.6, 156/538, 427/8, 427/53.1, 427/54.1, 427/508, 427/541, 427/553, 427/560, 118/57, 118/423, 118/428, 118/429, 118/620, 118/712, 134/21, 134/32, 134/34, 134/61, 134/82, 134/113, 134/137, 134/184, 134/198
• US Class Current: 264/401
• CPC Class Codes: B08B 3/12 by sonic or ultrasonic vibrations washing or rinsing machines for crockery or tableware using sonic or ultrasonic waves A47L15/13; of natural teeth, of prostheses using ultrasonic techniques similar to those used for natural teeth A61C17/20; application of ultrasonic vibrations to chemical, physical or physico-chemical processes in general B01J19/10
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B29C 64/35 Cleaning
• CPC Class Codes: B29C 64/357 Recycling
• CPC Class Codes: B29C 71/0009 using liquids, e.g. solvents, swelling agents spectacle cases, e.g. for cleaning contact lenses A45C11/04; disinfecting or sterilising contact lenses A61L12/00, using liquid substances A61L2/20; cleaning involving the use of liquid in general B08B3/00; for hydrating contact lenses B29D11/00067
• CPC Class Codes: B29C 71/04 by wave energy or particle radiation , e.g. for curing or vulcanising preformed articles during moulding, e.g. in a mould B29C35/08
• CPC Class Codes: B29K 2995/0073 smooth
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing
• CPC Class Codes: Y10T 156/17 Surface bonding means and/or assemblymeans with work feeding or handling means

Abstract

An improved stereolithographic apparatus and method is described. In one embodiment, the improvement includes immersing at least a portion of a part in a volume of a liquid solvent in a vapor degreaser while subjecting the portion to ultrasonic agitation to substantially remove excess resin. Several examples of solvents are provided, including ethanol, and Freon TMS. In a second embodiment, the improvement includes building the part on a layer of liquid resin supported by a volume of a dense, immiscible, and UV transparent intermediate liquid, and integratably immersing at least a portion of the built part in the intermediate liquid, and then either subjecting the immersed portion to ultrasonic agitation to substantially remove excess resin, or subjecting the immersed portion to UV light. Several examples of intermediate liquids are provided, including perfluorinated fluids, such as Fluorinert FC-40, and water-based salt solutions, such as solutions of magnesium sulfate or sodium chloride in water.

Claims

1. A method for producing and cleaning a three-dimensional object which is stereolithographically produced substantially layer by layer from a building material solidifiable upon exposure to synergistic stimulation, comprising:

forming successive layers of said building material;

forming successive cross-sectional layers of structure of said object by selectively exposing said successive layers of building material to said synergistic stimulation;

adhering said successive cross-sectional layers to form said object;

removing bulk excess building material from around said object;

applying a stripping material to a surface of said formed object to substantially remove excess building material wherein said stripping material is capable of dissolving at least one percent (1%) building material by weight; and

rinsing the surface with a rinsing substance which is different than the stripping material to substantially remove any residual building material and stripping material from the surface.

2. The method of claim 1 wherein said stripping material is soluble in said rinsing substance, and has a flashpoint greater than or equal to 97 degrees F.

3. The method according to claim 2 wherein the stripping material is capable of dissolving at least ten percent (10%) building material by weight.

4. The method according to claim 2 wherein the stripping material has a flashpoint greater than or equal to 140 degrees F.

5. The method according to claim 2 wherein the stripping material is substantially water soluble.

6. The method according to claim 3 wherein the stripping material has a flash point greater than 140 degrees F., and wherein the stripping material leaches into the object less than an amount necessary to cause greater than zero point two percent (0.2%) linear expansion of any dimension of the object in a period of time necessary to remove substantially all excess resin from a surface of the object, and wherein the stripping material is soluble in water.

7. The method according to claim 6 wherein the rinsing substance is water.

20. The method of claim 2 wherein said stripping material leaches into the object less than an amount necessary to cause greater than zero point two percent (0.2%) linear expansion of any dimension of the object in a period of time necessary to remove substantially all excess building material from the surface of the object.

21. The method of claim 1 wherein adhering said successive cross-sectional layers of structure occurs at the time said cross-sectional layers of structure are formed.

22. The method of claim 2 wherein the stripping material comprises primarily a glycol ether.

23. The method of claim 22 wherein at least a primary portion of the glycol ether is selected from the group consisting of tripropylene glycol monomethylether, dipropylene glycol monomethylether, and glycol monobutylether.

24. The method of claim 1 wherein the step of removing bulk excess building material from around the object further includes using suction means to extract at least a portion of said bulk excess building material.

25. The method of claim 1 further comprising the step of recovering the stripping material for reuse.

26. The method of claim 25 further comprising the step of periodically determining the amount of building material contained in the recovered stripping material in order to determine the ability of the stripping material to remove additional building material.

27. The method of claim 2 further comprising the step of causing relative motion between the object surface and the stripping material to speed the cleaning process.

28. The method of claim 2 wherein excess building material is substantially removed in less than half the time necessary for the stripping material to substantially damage the object.

29. The method of claim 28 wherein excess building material is substantially removed in less than one-third the time necessary for the stripping material to substantially damage the object.

30. The method of claim 2 wherein the rinsing substance is sprayed onto the object surface.

38. The method of claim 2 wherein said building material is a resin.

8. A method for producing and cleaning a three-dimensional object which is stereolithographically produced substantially layer by layer from a building material solidifiable upon exposure to synergistic stimulation, comprising:

forming successive layers of said building material;

forming successive cross-sectional layers of structure of said object by selectively exposing said successive layers of building material to said synergistic stimulation;

adhering said successive cross-sectional layers to form said object;

removing bulk excess building material from around said object;

applying a stripping material comprising primarily a glycol ether to a surface of the formed object to substantially remove excess building material from the surface of said object.

9. The method according to claim 8 further comprising rinsing the surface with a rinsing substance for removing the stripping material, the rinsing substance being different than the stripping material.

10. The method according to claim 9 wherein the rinsing substance is water.

11. An improved apparatus for producing and cleaning a three-dimensional object which is stereolithographically produced substantially layer by layer from a building material solidifiable upon exposure to synergistic stimulation, comprising means for forming successive layers of said building material, means for forming successive cross-sectional layers of structure of said object by selectively exposing said successive layers of building material to said synergistic stimulation, and means for adhering said successive cross-sectional layers to form said object, the improvement comprising:

means for removing excess building material from said object using a stripping material capable of dissolving at least one percent (1%) building material by weight, having a flashpoint greater than or equal to 97 degrees F., and which is soluble in a rinsing substance which is different than the stripping material; and

means for rinsing said stripping material from said object with said rinsing substance.

12. The apparatus of claim 11 wherein the adhesion of cross-sectional layers of said object occurs during formation of successive cross-sectional layers of structure.

13. The apparatus of claim 11 wherein the means for removing excess building material uses a stripping material having a flashpoint greater than or equal to 140 degrees F.

14. The apparatus of claim 11 wherein the means for removing excess building material uses a stripping material capable of dissolving at least ten percent (10%) building material by weight.

15. The apparatus of claim 11 wherein the means for removing excess building material uses a stripping material which leaches into the object less than an amount necessary to cause greater than (0.2%) linear expansion of any dimension of the object in a period of time necessary to remove substantially all excess resin from a surface of the object.

16. The apparatus of claim 11 where the means for removing excess building material uses a stripping material which is substantially soluble in water.

17. The apparatus of claim 16 wherein the means for removing excess building material uses a stripping material having a flashpoint greater than or equal to 140 degrees F., wherein the stripping material is capable of dissolving at least ten percent (10%) building material by weight, and wherein the stripping material leaches into the object less than an amount necessary to cause greater than zero point two percent (0.2%) linear expansion of any dimension of the object in a period of time necessary to remove substantially all excess resin from a surface of the object.

18. The apparatus of claim 17 wherein the means for rinsing said stripping material uses water.

19. The apparatus of claim 11 wherein the means for rinsing said stripping material completes the cleaning process leaving the object substantially tack free.

31. An apparatus for producing and cleaning a three-dimensional object which is stereolithographically produced substantially layer by layer from a building material solidifiable upon exposure to synergistic stimulation, comprising:

means for forming successive layers of said building material;

means for forming successive cross-sectional layers of structure of said object by selectively exposing said successive layers of building material to said synergistic stimulation;

means for adhering said successive cross-sectional layers of structure to form said object;

means for removing bulk excess building material from around said object;

means for applying a stripping material to a surface of said formed object to substantially remove excess building material wherein said stripping material is capable of dissolving at least one percent (1%) building material by weight; and

means for rinsing the surface with a rinsing substance, the rinsing substance being different than the stripping material.

32. The apparatus of claim 31 wherein the means for applying a stripping material uses a stripping material which is soluble in said rinsing substance, and has a flashpoint greater than or equal to 97 degrees F.

33. The apparatus of claim 31, further comprising:

a computer which controls the means for forming successive layers of building material, means for forming successive cross-sectional layers of structure, means for adhering, means for applying the stripping material, and means for rinsing.

34. The apparatus of claim 33 further comprising a platform on which said object is built and computer controlled means to separate said object from said platform.

35. The apparatus of claim 34 further comprising computer controlled means for post curing the object.

36. The apparatus of claim 34 further comprising computer controlled means for removing the building platform from a transporter after the object is built thereon.

37. The apparatus of claim 36 further comprising computer controlled means for replacing the removed platform with a clean platform.