Starch-based, biodegradable packing filler and method of preparing same

• US 5,248,702 A
• Filed: 08/21/1992
• Issued: 09/28/1993
• Est. Priority Date: 01/21/1992
• Status: Expired due to Fees

• Current Assignee: Kansas State University Research Foundation
• Original Assignee: Kansas State University Research Foundation
• Inventors: Seib, Paul A., Neumann, Paul E.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/933,207
• Time in Patent Office: 403 Days
• Field of Search: 521/84.1, 521/91, 521/916, 106/122
• US Class Current: 521/84.1
• CPC Class Codes: B65D 65/466 Bio- or photodegradable packaging materials
• CPC Class Codes: B65D 81/09 using flowable discrete elements of shock-absorbing material, e.g. pellets or popcorn
• CPC Class Codes: C08L 2201/06 Biodegradable
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 3/02 Starch; Degradation products thereof, e.g. dextrin
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: Y02W 90/10 Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
• CPC Class Codes: Y10S 521/916 Cellular product having enhanced degradability

Abstract

Starch-based biodegradable packaging fillers are provided which have high volumes, low weights, and excellent compressibility and resiliency properties. The products of the invention are fabricated by extrusion of a starch substrate, most preferably normal wheat starch, in the presence of minor amounts of a polyalkylene glycol or derivative thereof and/or a particulate bubble-nucleating agent. Effective biodegradable packaging fillers can thus be fabricated without the use of expensive modified starch substrates; however, such substrates can also be employed if desired, and the additives of the invention improve these products as well. In preferred production procedures, the additives are mixed with the starch substrate, and the mixture is preconditioned and then extruded through a twin screw extruder.

Claims

1. A starch product adapted for use as a packing filler or the like, said product comprising an expanded, cellular, compressible and resilient body having a matrix comprising from about 93-99.5% by weight starch supplemented with from about 0.1-1% by weight of a particulate bubble-nucleating agent having a particle size of from about 5-100 microns and a surface area of from about 190-450 m² /g, said product having a bulk density of from about 0.6-2 lb/ft³, a bulk compressibility of from about 0.04-0.4 kilo-newtons, a bulk resiliency of from about 40-75%, and cells having an average diameter of from about 0.5-5 mm.

2. The starch product of claim 1, said starch being selected from the group consisting of modified and unmodified wheat and corn starches.

3. The starch product of claim 2, said starch being selected from the group consisting of wheat and high amylose corn starches.

4. The starch product of claim 1, said agent being selected from the group consisting of silicon dioxide and amorphous silicas and mixtures thereof.

5. The starch product of claim 1, said agent being present at a level of from about 0.1-1% by weight.

6. The starch product of claim 1, said product being annular.

7. The starch product of claim 1, said product being generally C-shaped in cross-section.

8. The starch product of claim 1, said bulk density being from about 1.2-1.6 lb/ft³.

9. The starch product of claim 1, said compressibility being from about 0.13-0.36 kilo-newtons.

10. The starch product of claim 1, said resiliency being from about 45-70%.