Radiation-senstive, ethylenically unsaturated, copolymerizable compounds and their preparation
First Claim
1. An ethylenically unsaturated copolymerizable, radiation-sensitive organic compound of the formula (I) ##STR79## where R is aryl or a radical R1 andR1 is a radical ##STR80## where R2 and R6 are identical or different and each of the radicals can be H or one of the radicals ##STR81## R3 to R5 are identical or different and each is H, alkyl of 1 to 4 carbon atoms, phenyl, OCH3, OC2 H5, F, Cl, Br, CN, COOAlkyl where alkyl is 1 to 17 carbon atoms, COOAryl, CF3, N(Alkyl)2, N(Alkyl)-(Aryl), N(Aryl)2, N.sup.⊖
- (Alkyl)3 A.sup.⊖
or N.sup.⊕
H(Alkyl)2 A.sup.⊖
where alkyl is of 1 to 4 carbon atoms, and A.sup.⊖
is the anion of an acid, and one of the radicals ##STR82## where at least one of the radicals R2 to R6 is a radical ##STR83## where X is a divalent, unsubstituted or substituted alkylene radical--(CH2)m --or ##STR84## where m is from 1 to 10 and R'"'"' and R" are identical of different and each is H or alkyl, an oxaalkylene radical --(CH2)n --O--(CH2)p -- where n and p are each from 1 to 5, or a polyoxaalkylene radical having 2 to 20 oxygen atoms which are bonded to one another via at least one --CH2 -- or --CH2 -- CH(CH3)--group, or a radical --(CH2)m --O--CO--O--(CH2)n --, --CH2)n --NH--CO--O--(CH2)m --, --(CH2)m --CO--O--(CH2)n or --(CH2)m --O--CO--(CH2)n -- where m and n are each from 1 to 10, an unsubstituted or substituted cycloalkylene radical of 5 to 10 carbon atoms, a (bis)methylenecycloalkylene radical of 6 to 12 carbon atoms or an unsubstituted or substituted o-, m- or p-phenylene radical,Y is H, alkyl of 1 to 6 carbon atoms or phenyl andZ is O.
1 Assignment
0 Petitions
Accused Products
Abstract
Radiation-sensitive, ethylenically unsaturated compounds and a process for their preparation. The ethylenically unsaturated organic compounds are of the general formula ##STR1## where R is alkyl, aryl or a radical R1 and
R1 is a radical ##STR2## where R2 to R6 are each H, alkyl, OH, OAlkyl, SH, SAlkyl, halogen, N (Alkyl)2 or N (Alkyl) (Aryl) and at least one but not more than three of the radicals R2 to R6 is or are a radical ##STR3## where X is alkylene, cycloalkylene, oxaalkylene or arylene, Y is H or CH3 -- and Z is O or NY.
The novel radiation-sensitive ethylenically unsaturated compounds are suitable for the preparation of polymeric radiation-sensitive compounds.
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Citations
2 Claims
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1. An ethylenically unsaturated copolymerizable, radiation-sensitive organic compound of the formula (I) ##STR79## where R is aryl or a radical R1 and
R1 is a radical ##STR80## where R2 and R6 are identical or different and each of the radicals can be H or one of the radicals ##STR81## R3 to R5 are identical or different and each is H, alkyl of 1 to 4 carbon atoms, phenyl, OCH3, OC2 H5, F, Cl, Br, CN, COOAlkyl where alkyl is 1 to 17 carbon atoms, COOAryl, CF3, N(Alkyl)2, N(Alkyl)-(Aryl), N(Aryl)2, N.sup.⊖ - (Alkyl)3 A.sup.⊖
or N.sup.⊕
H(Alkyl)2 A.sup.⊖
where alkyl is of 1 to 4 carbon atoms, and A.sup.⊖
is the anion of an acid, and one of the radicals ##STR82## where at least one of the radicals R2 to R6 is a radical ##STR83## where X is a divalent, unsubstituted or substituted alkylene radical--(CH2)m --or ##STR84## where m is from 1 to 10 and R'"'"' and R" are identical of different and each is H or alkyl, an oxaalkylene radical --(CH2)n --O--(CH2)p -- where n and p are each from 1 to 5, or a polyoxaalkylene radical having 2 to 20 oxygen atoms which are bonded to one another via at least one --CH2 -- or --CH2 -- CH(CH3)--group, or a radical --(CH2)m --O--CO--O--(CH2)n --, --CH2)n --NH--CO--O--(CH2)m --, --(CH2)m --CO--O--(CH2)n or --(CH2)m --O--CO--(CH2)n -- where m and n are each from 1 to 10, an unsubstituted or substituted cycloalkylene radical of 5 to 10 carbon atoms, a (bis)methylenecycloalkylene radical of 6 to 12 carbon atoms or an unsubstituted or substituted o-, m- or p-phenylene radical,Y is H, alkyl of 1 to 6 carbon atoms or phenyl and Z is O.
- (Alkyl)3 A.sup.⊖
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2. The compound of the formula ##STR85##
Specification