Electrically conductive coating composition for providing a bend sensor

• US 5,250,227 A
• Filed: 05/03/1990
• Issued: 10/05/1993
• Est. Priority Date: 05/03/1990
• Status: Expired due to Term

• Current Assignee: National Starch and Chemical Investment Holding Corporation
• Original Assignee: National Starch and Chemical Investment Holding Corporation
• Inventors: Margolin, Keith J.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): SWOPE, BRADLEY
• Application Number:
  US07/518,343
• Time in Patent Office: 1,251 Days
• Field of Search: 252/511, 252/510, 252/503
• US Class Current: 252/511
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08L 61/04 Condensation polymers of aldehydes or ketones with phenols only
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: Y10S 428/901 Printed circuit
• CPC Class Codes: Y10T 428/24917 including metal layer
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A composition is disclosed which forms a bend sensor when coated on a flexible substrate. A bend sensor prepared from the composition is also disclosed. The composition contains a brittle binder which cracks under a stress, electrically conductive elements and a graphite additive which stabilizes the degree of cracking. The composition forms a bend sensor which upon a change in degree of flexing produces an electrical signal in the form of a change in resistance in circuits which include the sensor.

Claims

1. An electrically conductive composition for coating on a flexible polyester film substrate and providing a bend sensor in electronic circuits comprising

a) a polymeric binder system comprising phenolic resin that dries and/or cures to a brittle coating which cracks when bent around a mandrel;

b) an amount of discontinuous conductive carbon black ranging from about 3 to 20 wt. percent based on the weight of the binder effective to produce a desired electrical resistance in the composition;

c) graphite particles in an amount effective to stabilize the resistance profile of the composition after cracking on a mandrel and less than the amount that produces a composition having a resistance ratio (bent/straight) equal to 1;

1, and

d) a thermoplastic additive to improve adhesion of the composition to said polyester substrate, said additive comprising thermoplastic resin containing acrylic resin, vinyl resin and polyurethane, surfactant and organic solvent therefor.

2. The composition of claim 1 wherein the resistance ratio is greater than about 2:

1 and less than 10;

1.