Modified burn characteristic Saranex film

• US 5,250,350 A
• Filed: 12/03/1991
• Issued: 10/05/1993
• Est. Priority Date: 12/03/1991
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Tung, Harvey C.
• Primary Examiner(s): SLUBY, PATRICIA
• Application Number:
  US07/801,995
• Time in Patent Office: 672 Days
• Field of Search: 428/349, 428/516, 428/910, 428/216, 428/520, 428/920, 428/921
• US Class Current: 428/216
• CPC Class Codes: A41D 31/085 using layered materials
• CPC Class Codes: B32B 2307/3065 Flame resistant or retardant, fire resistant or retardant
• CPC Class Codes: B32B 2307/7242 Non-permeable
• CPC Class Codes: B32B 2323/046 LDPE, i.e. low density polyethylene
• CPC Class Codes: B32B 2571/02 defensive, e.g. armour plates or anti-ballistic clothing
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10S 428/92 Fire or heat protection feature
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

A coextruded film with both gas barrier and fire retardant properties as well as good physical properties is made up by melt coextrusion to form a four or five layer film product useful in making laminates for protective clothing or tarps. The five layer film has a Saran resin barrier core layer and LDPE skin layers on each face with intervening EVA glue layers. The four layer film has a Saran resin barrier core layer and a CPE skin layer on one face and an EVA skin layer on the other with an EVA glue layer between the barrier core layer and the CPE skin layer. Each skin layer and each glue layer contains about 8 to about 30 percent by weight of a polyhalogenated organic/antimony oxide fire retardant and a small amount of a slip agent.

Claims

1. A coextruded film having both gas barrier properties and modified burn characteristics, comprising:

a Saran resin barrier core layer having on both opposing faces a skin layer, at least one of the skin layers being predominantly a polyethylene selected from the group consisting of low density polyethylene and chlorinated polyethylene, blended with a fire retardant composition and a small amount of slip agent, the proportion of polyethylene being in the range of about 70 to 80 percent by weight, the proportion of fire retardant composition being in the range of about 8 to about 30 percent by weight, and the proportion of slip agent being in the range of about 2 to about 13 percent by weight;

up to one of the skin layers being predominantly ethylene/vinyl acetate copolymer blended with the fire retardant composition and a small amount of slip agent, the proportion of ethylene/vinyl acetate copolymer being in the range of about 70 to 90 percent by weight, the proportion of fire retardant composition being in the range of about 8 to about 30 percent by weight, and the proportion of slip agent being in the range of about 1 to about 6 percent by weight;

and wherein a skin layer is predominantly polyethylene, there being interposed between the skin layer and the barrier core layer a glue layer of predominantly ethylene/vinyl acetate copolymer blended with the fire retardant composition and a small amount of slip agent, the proportion of ethylene/vinyl acetate copolymer being in the range of about 70 to about 90 percent by weight, the proportion of fire retardant composition being in the range of about 8 to about 30 percent by weight, and the proportion of slip agent being in the range of about 1 to about 6 percent by weight;

the respective layers being in approximate sequential volumetric relation, in percent, 35;

10;

10;

10;

35 wherein both skin layers are of predominantly low density polyethylene, and 35;

10;

10;

10;

45 wherein one of the skin layers is predominantly of chlorinated polyethylene and represents about 45 percent of the thickness of the film, and the other skin layer is a glue layer that is not covered; and

the fire retardant composition being a polyhalogenated organic compound/antimony oxide blend in a low density polyethylene carrier.

2. The coextruded film of claim 1 wherein the barrier core layer comprises from about 92 to about 98 percent by weight Saran resin and the balance substantially ethylene/vinyl acetate copolymer.

3. The coextruded film of claim 1 wherein both skin layers comprise predominantly low density polyethlene and one of said glue layers is interposed between each skin layer and the barrier core layer and the coextruded film is composed of five layers.

4. The coextruded film of claim 3 having a total thickness of about 2 mils.

5. The coextruded film of claim 1 wherein one of the skin layers comprises predominantly chlorinated polyethylene, the film is composed of four layers, and the other skin layer is an ethylene/vinyl acetate copolymer glue layer that is not covered.

6. The coextruded film of claim 5 having a total thickness of about 4 mils.

7. The coextruded film of claim 1 containing up to about 3 percent by weight of fumed silica in replacement of a like amount of polyethylene to adjust drip/shrink behavior.

8. The coextruded film of claim 1 wherein the polyethylene content in each skin layer containing same is in the range of about 72 to about 78 percent by weight.

9. The coextruded film of claim 1 wherein the fire retardant composition content in each skin and glue layer is in the range of about 10 to about 20 percent by weight.

10. The coextruded film of claim 1 wherein the ethylene/vinyl acetate copolymer content of both glue layers is in the range of about 75 to about 85 percent by weight and the amount of slip agent is about 1 to about 5 percent by weight.

11. The coextruded film of claim 1 wherein the polyethylene is low density polyethylene, the low density polyethylene content of the skin layers is about 72 to about 78 percent by weight, the ethylene/vinyl acetate copolymer content of the glue layers is about 75 to about 85 percent by weight, and each of the skin and glue layers contains about 10 to about 20 percent by weight of the fire retardant composition.

12. The coextruded film of claim 11 containing up to about 3 percent of fumed silica in replacement of an equal weight of low density polyethylene in the skin layers.

13. The coextruded film of claim 1 wherein the polyethylene is chlorinated polyethylene, one skin layer contains chlorinated polyethylene in the range of about 72 to about 78 percent by weight, the other skin layer is a not-covered ethylene/vinyl acetate copolymer glue layer, and the glue layers contain about 75 to about 85 percent by weight ethylene/vinyl acetate copolymer and each of the skin and glue layers contains about 10 to about 20 percent by weight of the fire retardant composition.

14. The coextruded film of claim 13 containing up to about 3 percent by weight of fumed silica in the chlorinated polyethylene skin layer in replacement of an equal weight of chlorinated polyethylene.