Method and apparatus using oscillatory magnetic field to determine state of charge of an electrolytic storage cell

• US 5,250,903 A
• Filed: 03/13/1992
• Issued: 10/05/1993
• Est. Priority Date: 05/31/1989
• Status: Expired due to Term

• Current Assignee: Serveron Corporation (Fortive Corp.)
• Original Assignee: Amoco Corporation (BP PLC)
• Inventors: Limuti, Donald, Churchill, Thomas L., Ross, James M. Jr.
• Primary Examiner(s): Strecker, Gerard R.
• Application Number:
  US07/851,984
• Time in Patent Office: 571 Days
• Field of Search: 324/426, 324/427, 324/430, 324/432, 324/434, 324/436, 324/204, 324/222, 324/234, 324/236-238, 340/636
• US Class Current: 324/427
• CPC Class Codes: G01R 31/382 Arrangements for monitoring battery or accumulator variables, e.g. SoC
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/484 for measuring electrolyte level, electrolyte density or electrolyte conductivity
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Nonintrusive sensors capable of measuring various storage cell parameters such as voltage, state-of-charge, electrolyte level, internal resistance, and temperature are attached to a monitoring module which gathers and processes signals representative of information concerning the condition of electrolytic storage cells and transmits the information to a central computer for further processing. In response to commands issued by the central computer, appropriate maintenance and/or repair operations can be initiated. Alternatively, the system described can be used to automatically perform such maintenance tasks as checking and adding electrolyte levels, reducing the voltage in cells whose output voltage is too high, and leveling the state-of-charge of each cell in an array of electrolytic storage cells. The system can monitor other functions of the electrolytic storage cells, including the evolution of hydrogen gas and the accumulation of sediments in individual electrolytic storage cells.

Claims

1. A method of determining the state of charge of an electrolytic storage cell, comprising the steps of:

generating an oscillatory magnetic field from a circulating current that penetrates a predetermined volume

of a storage cell having a plurality of metallic electrodes immersed in electrolyte that vary their metallic volume in proportion to the state of charge of said storage cell;

adjusting the frequency of said oscillatory magnetic field to induce oscillatory currents in said electrolyte and in each of said plurality of electrodes of said storage cell; and

measuring the change of energy of said magnetic field within said predetermined volume due to the change in said induced oscillatory currents in said plurality of electrodes that is caused by the change in metallic volume of said plurality of metallic electrodes to determine the state of charge of said storage cell.

2. The method set forth in claim 1, wherein said step of generating comprises the step of circulating current through a path defined by a current-circulating conductor that has an inductance, and said step of measuring said change in magnetic field energy comprises the step of determining the change of inductance of said current-circulating conductor due to said change in metallic volume of said plurality of metallic electrodes.

3. The method set forth in claim 2 wherein said step of generating comprises generation of said magnetic field to penetrate substantially of all of the electrolyte of said storage cell within said predetermined volume of said magnetic field.

4. The method set forth in claim 3, wherein said step of adjusting the frequency of said oscillatory magnetic field comprises adjustment of the frequency of said magnetic field to cause said induced oscillatory currents to flow upon the surfaces of each of said plurality of electrodes of said storage cell by magnetic flux exclusion that penetrates each of said plurality of electrodes with said induced currents to a skin depth that is inversely proportional to the square root of the frequency of said magnetic field.

5. The method set forth in claim 4, wherein said step of adjusting the frequency of said magnetic field comprises adjustment of the frequency of said magnetic field to diffuse at least a portion of said generated magnetic field within a predetermined frequency range through a skin depth in said electrolyte that is at least as wide as half of the width of said storage cell.

6. The method set forth in claim 5, wherein said step of generating said magnetic field comprises generation of said magnetic field to be substantially incident upon the surfaces of said plurality of electrodes and said step of adjusting comprises adjustment of the frequency of said generated magnetic field into each of said plurality of electrodes to diffuse said magnetic field to a skin depth that is no more than approximately half of the thickness of each of said plurality of electrodes.

7. Apparatus for determining the state of charge of an electrolytic storage cell, comprising:

means for generating an oscillatory magnetic field from a circulating current that penetrates a predetermined volume of a storage cell having a plurality of metallic electrodes immersed in electrolyte that vary their metallic volume in proportion to the state of charge of said storage cell;

means for adjusting the frequency of said oscillatory magnetic field to induce oscillatory currents in said electrolyte and in each of said plurality of electrodes of said storage cell; and

means for measuring the change of energy of said magnetic field within said predetermined volume due to the change in said induced oscillatory currents in said plurality of electrodes that is caused by the change in metallic volume of said plurality of metallic electrodes to determine the state of charge of said storage cell.

8. The apparatus set forth in claim 7, wherein said means for generating comprises means for circulating current through a path defined by a current-circulating conductor that has an inductance, and said means for measuring said change in magnetic field energy comprises means for determining the change of inductance of said current-circulating conductor due to said change in metallic volume of said plurality of metallic electrodes.

9. The apparatus set forth in claim 8, wherein said means for generating generates said magnetic field to penetrate substantially of all of the electrolyte of said storage cell within said predetermined volume of said magnetic field.

10. The apparatus set forth in claim 9, wherein said means for generating induces said oscillatory currents to flow upon the surfaces of each of said plurality of electrodes of said storage cell by magnetic flux exclusion that penetrates each of said plurality of electrodes with said induced currents to a skin depth that is inversely proportional to the square root of the frequency of said magnetic field.

11. The apparatus set forth in claim 10, wherein said means for adjusting the frequency of said magnetic field adjusts the frequency of said magnetic field to diffuse at least a portion of said generated magnetic field within a predetermined frequency range through a skin depth in said electrolyte that is at least as wide as half of the width of said storage cell.

12. The apparatus set forth in claim 11, wherein said means for generating said magnetic field orients said magnetic field to be substantially parallel to and incident upon the surfaces of said plurality of electrodes and diffuses said generated magnetic field into each of said plurality of electrodes to a skin depth that is no more than approximately half of the thickness of each of said plurality of electrodes.

13. The apparatus set forth in claim 7, wherein said means for generating comprises an impulse-excited resonant circuit.

14. The apparatus set forth in claim 13, wherein said resonant circuit comprises an inductor and a capacitor.

15. The apparatus set forth in claim 14, wherein said resonant circuit is a parallel resonant circuit.

16. The apparatus set forth in claim 15, wherein said inductor encompasses the perimeter of said storage cell.

17. The apparatus set forth in claim 16, wherein said means for measuring comprises an impedance bridge.

18. The apparatus set forth in claim 16, wherein said means for measuring comprises a frequency meter.

19. The apparatus set forth in claim 7, wherein said means for generating comprises an oscillator having a tank circuit in its feedback path that comprises an inductor and a capacitor.

20. The apparatus set forth in claim 19, wherein said tank circuit is a parallel resonant circuit.

21. The apparatus set forth in claim 20, wherein said inductor encompasses the perimeter of said storage cell.

22. The apparatus set forth in claim 21, wherein said means for measuring comprises a frequency meter.

23. The apparatus set forth in claim 20, wherein said means for generating comprises an inductor that encompasses the perimeter of said storage cell.