Ammonia sensor

• US 5,252,292 A
• Filed: 05/17/1990
• Issued: 10/12/1993
• Est. Priority Date: 05/18/1989
• Status: Expired due to Fees

• Current Assignee: Nisshinbo Industries, Inc. (Kawasaki Heavy Industries Limited)
• Original Assignee: Nisshinbo Industries, Inc. (Kawasaki Heavy Industries Limited)
• Inventors: Takenishi, Soichiro, Yosomiya, Ryutoku, Hirata, Mitsutoshi
• Primary Examiner(s): Housel, James C.
• Assistant Examiner(s): Le, Long V.
• Application Number:
  US07/524,562
• Time in Patent Office: 1,244 Days
• Field of Search: 204/431, 204/400, 204/403, 204/298.02, 204/298.03, 252/500, 429/213, 436/113, 436/112, 436/111, 436/149, 422/98, 422/68.1, 422/83, 422/90
• US Class Current: 422/98
• CPC Class Codes: G01N 27/126 comprising organic polymers
• CPC Class Codes: G01N 33/0054 for ammonia
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y10T 436/173845 Amine and quaternary ammonium
• CPC Class Codes: Y10T 436/175383 Ammonia

Abstract

An ammonia sensor consisting of at least one pair of electrodes and an ammonia-sensing material comprising a polyaniline filling the space between the electrodes.

Claims

1. An ammonia sensor consisting of at least one pair of electrodes and an ammonia-sensing material filling the space between the electrodes wherein the ammonia-sensing material comprises a matrix of a conductive polymer having a conductivity of 10^-5 mho or higher and a polyaniline dispersed in the matrix.

2. An ammonia sensor according to claim 1, wherein the polyaniline is produced by electrolytic polymerization of aniline.

3. An ammonia sensor according to claim 1, wherein the electrodes are provided on an insulating substrate and are an interdigitated form.

4. An ammonia sensor according to claim 1, which is produced by coating a polyaniline solution on an insulating substrate having at least one pair of electrodes thereon, so as to fill at least the space between the electrodes.

5. An ammonia sensor according to claim 1, wherein the conductive polymer is selected from high-molecular electrolytes, their crosslinked products and mixtures of a polymer and an electrolyte.

6. An ammonia sensor according to claim 1, wherein the weight ratio of the polyaniline to the conductive polymer is 10/90 to 90/10.

7. An ammonia sensor according to claim 1, which is produced by forming a film having a thickness of 0.1 to 100 microns of a conductive polymer on an insulating substrate having at least one pair of electrodes thereon and then effecting electrolytic polymerization of aniline with said film of conductive polymer used as an anode.

12. A process for detecting the ammonia concentration of a gas containing ammonia which comprises contacting the ammonia sensor of claim 1 with an ammonia containing gas, measuring an electric resistance change of the ammonia-sensing material, and determining the concentration of ammonia from said change of electric resistance of the sensing material.

8. An ammonia sensor consisting of at least one pair of electrodes and an ammonia sensing material comprising a film matrix of a conductive polymer having a conductivity of 10^-5 mho or higher and a polyaniline dispersed in the matrix, wherein the weight ratio of the polyaniline to the conductive polymer is 10/90 to 90/10.

9. An ammonia sensor according to claim 8, wherein the electrodes are provided on an insulating substrate and are an interdigitated form.

10. An ammonia sensor according to claim 8 wherein the film matrix has a thickness of 1 to 20 microns.

11. An ammonia sensor according to claim 8 wherein the weight ratio of polyaniline to the conductive polymer is 20/80 to 85/15.

13. A process for detecting the ammonia concentration of a gas containing ammonia which comprises contacting the ammonia sensor of claim 8 with an ammonia containing gas, measuring an electric resistance change of the ammonia-sensing material, and determining the concentration of ammonia from said change of electric resistance of the sensing material.