Water-dispersible polyisocyanate mixtures, a process for their preparation and their use in two-component aqueous compositions

• US 5,252,696 A
• Filed: 11/04/1992
• Issued: 10/12/1993
• Est. Priority Date: 11/07/1991
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Halpaap, Reinhard, Noll, Klaus, Hassel, Tillmann, Kubitza, Werner, Laas, Hans J.
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/971,491
• Time in Patent Office: 342 Days
• Field of Search: 528/49, 528/76, 528/77
• US Class Current: 528/49
• CPC Class Codes: C08G 18/283 Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
• CPC Class Codes: C08G 18/6229 Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
• CPC Class Codes: C08G 18/706 the liquid medium being water
• CPC Class Codes: C08G 18/792 formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
• CPC Class Codes: C08G 18/798 containing urethdione groups

Abstract

The present invention relates to water-dispersible polyisocyanate mixtures which

a) have an average isocyanate functionality of 1.8 to 4.2,

b) contain 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups (calculated as NCO, molecular weight=42) and

c) contain 2 to 20% by weight of ethylene oxide units (calculated as C₂ H₄ O, molecular weight=44) arranged within polyether chains, the polyether chains containing an average of 5.0 to 9.9 ethylene oxide units.

The present invention also relates to the preparation of these polyisocyanate mixtures by reacting at an NCO/OH equivalent ratio of 4:1 to 120:1

A) a polyisocyanate component having an average isocyanate functionality of 2.1 to 4.4 and containing one or more polyisocyanates in which all the isocyanate groups are (cyclo)aliphatically bound with

B) a monovalent polyalkylene oxide polyether alcohol containing an average of 5.0 to 9.9 ethylene oxide units.

Finally, the present invention also relates to aqueous two-component compositions containing these polyisocyanate mixtures and aqueous resins having isocyanate-reactive groups.

Claims

1. A water-dispersible polyisocyanate mixture which

a) has an average isocyanate functionality of 1.8 to 4.2,

b) contains 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups (calculated as NCO, molecular weight=42),

c) contains 2 to 20% by weight of ethylene oxide units (calculated as C₂ H₄ O, molecular weight=44) arranged within polyether chains, the polyether chains containing, on average, 5.0 to 9.9 ethylene oxide units and

d) is not prepared from and does not contain 1,6-hexamethylene diisocyanate.

2. A process for the preparation of a polyisocyanate mixture which

a) has an average isocyanate functionality of 1.8 to 4.2,

b) contains 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups (calculated as NCO, molecular weight=42),

c) contains 2 to 20% by weight of ethylene oxide units (calculated as C₂ H₄ O, molecular weight=44) arranged within polyether chains, the polyether chains containing an average of 5.0 to 9.9 ethylene oxide units and

d) is not prepared from or does not contain 1,6-hexamethylene diisocyanate,

which comprises reacting at an NCO/OH equivalent ratio of 4:

1 to 120;

1

A) a polyisocyanate component having an average isocyanate functionality of 2.1 to 4.4 and containing one or more polyisocyanates other than 1,6-hexamethylene diisocyanate in which all of the isocyanate groups are (cyclo)aliphatically bound with

B) a monovalent polyalkylene oxide polyether alcohol containing an average of 5.0 to 9.9 ethylene oxide units.

3. The process of claim 2 wherein said polyether alcohol contains, on average, 6.0 to 8.0 ethylene oxide units.

4. A composition which comprises

I) a water-dispersible polyisocyanate mixture which

a) has an average isocyanate functionality of 1.8 to 4.27,

b) contains 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups (calculated as NCO, molecular weight=42),

c) contains 2 to 20% by weight of ethylene oxide units (calculated as C₂ H₄ O, molecular weight=44) arranged within polyether chains, the polyether chains containing, on average, 5.0 to 9.9 ethylene oxide units and

d) is not prepared from or does not contain 1,6-hexamethylene diisocyanate and

II) a water soluble or water-dispersible aqueous resin containing isocyanate reactive groups.

5. The composition of claim 4 wherein said isocyanate reactive groups comprise alcoholic hydroxyl groups.