Method and apparatus for recovery of ethylene and propylene from gas produced by the pyrolysis of hydrocarbons

• US 5,253,479 A
• Filed: 07/05/1991
• Issued: 10/19/1993
• Est. Priority Date: 07/06/1990
• Status: Expired due to Term

• Current Assignee: Technip Italy SPA (Technip Energies NV)
• Original Assignee: TPL Incorporated
• Inventors: Kaiser, Victor, Pocini, Carlo A., Picciotti, Marcello, Di Cintio, Roberto
• Primary Examiner(s): Bennet, Henry A.
• Assistant Examiner(s): Kilner, Christopher B.
• Application Number:
  US07/726,341
• Time in Patent Office: 837 Days
• Field of Search: 62/23, 62/24, 62/28, 62/31
• US Class Current: 62/631
• CPC Class Codes: C10G 70/041 by distillation
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2205/50 using absorption, i.e. with selective solvents or lean oil, heavier CnHm and including generally a regeneration step for the solvent or lean oil
• CPC Class Codes: F25J 2210/02 Multiple feed streams, e.g. originating from different sources
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2215/62 Ethane or ethylene
• CPC Class Codes: F25J 2245/02 Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/04 Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/60 Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
• CPC Class Codes: F25J 2290/40 Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more
• CPC Class Codes: F25J 3/0252 separation of hydrogen production of hydrogen containing gas in general C01B3/00, e.g. separation of hydrogen or hydrogen containing gases form gaseous mixtures at low temperatures C01B3/506
• CPC Class Codes: Y02P 30/40 Ethylene production

Abstract

A method and an apparatus for the largest recovery of ethylene and propylene from gas produced by the pyrolysis of hydrocarbons, wherein any liquid current produced by the fractional condensation of the raw gas up to a definite temperature is directly fed to an ethane fractionating column (deethanizer) the bottom product of which is the purified current containing almost all propylene, while any current condensed at lower temperature is fed to a methane separating column (demethanator) provided with a reboiler in which the partial condensation of the overhead vapor of the deethanizer occurs, and the bottom product of the demethanator contains all ethylene.

Claims

1. A method for recovery of ethylene and propylene from a raw gas produced by a pyrolysis or hydrocarbons and for splitting said gas into first and second depurated current flows, the first containing almost all ethylene and the second containing almost all propylene, comprising the steps of:

providing a fractional condensation of the raw gas from compression, caustic washing, and drying sections in a separation system with progressive plural cooling stages;

feeding a first condensate liquid of the first cooling stage and any mixture of liquid hydrocarbons from the compression section at a predetermined temperature to a deethanizer column to obtain as a bottom produce a depurated current containing almost all propylene;

feeding a second condensate liquid of the following cooling stages at lower temperatures to a demethanator column to obtain as a bottom produce a depurated current containing almost all the ethylene;

feeding a deethanizer overhead vapor stream to a heat exchanger employed as a demethanator reboiler, wherein said deethanizer overhead vapor stream is partially condensed;

supplying said partially condensed overhead vapour from the deethanizer to the demethanator.

2. The method of claim 1 wherein the temperature is reached and controlled by a separator/absorber in the first cooling stage.

3. The method of claim 1 wherein the temperature is reached and controlled by a pre-cooling pressurized feed gas.

5. The method of claim 1 wherein the bottom product of said demethanator containing almost all ethylene is also partially used as reflux to the deethanizer.

6. The method of claim 1 wherein the overhead vapour of the demethanator is depurated in a cryogenic apparatus so as to recover the ethylene from the residual gases.

7. The method of claim 1 wherein the raw gas is a pyrolysis gas from ethane or ethane/propane, and the overhead vapour of the demethanator is recycled to a gas compressor without cryogenic treatment.

8. The method of claim 1 wherein the column of the demethanator is placed on the column of the deethanizer, a condenser of which is partially formed by the reboiler of the demethanator.

4. The method of claim 11 wherein the temperature is reached and controlled by recycling to the separator/absorber of the first cooling stage, a portion of the bottom product of the demethanator containing almost all ethylene.