Solvent based fluorescent ink compositions for ink jet printing

• US 5,256,192 A
• Filed: 05/15/1992
• Issued: 10/26/1993
• Est. Priority Date: 05/15/1992
• Status: Expired due to Term

• Current Assignee: DataProducts
• Original Assignee: DataProducts
• Inventors: Liu, Clement, Hinton, Stephanie S.
• Primary Examiner(s): KLEMANSKI, HELENE G
• Application Number:
  US07/884,709
• Time in Patent Office: 529 Days
• Field of Search: 106/20 R, 106/20 B, 106/20 D, 106/21 A, 346/1.1
• US Class Current: 106/31.15
• CPC Class Codes: C09D 11/36 based on non-aqueous solvents
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks

Abstract

Fluorescent ink compositions and methods for using the ink co positions in drop-on-demand ink jet printers is provided. The fluorescent ink compositions are formulated with an aromatic alcohol, a glycol, a fatty acid, and at least one fluorescent pigment.

Claims

1. A fluorescent ink composition for use in impulse ink jet printers, comprising:

(a) from about 5-75% wt. of an aromatic alcohol having the general structure;

##STR4## where R₁ is hydroxyalkyl having from 1-5 carbon atoms and 1-2 oxygen atoms;

R₂ is H, OH, or hdyroxyalkyl having from 1-5 carbon atoms and 1-2 oxygen atoms;

(b) from about 10-90% wt. of a glycol component;

(c) a fatty acid in an amount up to about 15% wt.; and

(d) a fluorescent pigment in an amount up to about 25% wt.

2. The fluorescent ink composition of claim 1 wherein the aromatic alcohol has the general structure:

##STR5## where R₃ is an alkyl having 1-3 carbon atoms, and wherein the fatty acid is present in an amount of from about 0.05 to about 10% wt., and the fluorescent pigment is present in an amount of from about 0.25 to about 20% wt.

3. The fluorescent ink composition of claim 2 wherein the ink fluoresces upon exposure to ultraviolet light and emits light having a wavelength of from about 550-650 nanometers.

4. The fluorescent ink composition of claim 2 wherein the aromatic alcohol is present in an amount of from about 15-25% wt.

5. The fluorescent ink composition of claim 4 wherein the aromatic alcohol comprises benzyl alcohol.

6. The fluorescent ink composition of claim 5 wherein the glycol is present in an amount of from about 40-70% wt., and the fluorescent pigment is present in an amount of from 0.5-5% wt., and further comprising a brightener in an amount of from about 1 to about 20% wt.

7. The fluorescent ink composition of claim 6 wherein the fatty acid comprises oleic acid and the glycol comprises triethylene glycol.

8. The fluorescent ink composition of claim 2 wherein the glycol comprises one or more glycols selected from the group consisting of HO--R₄ --OH and HO--[R₄ --O]_n --H where R₄ is a straight chain or branched alkyl group having from about 1-20 carbon atoms, and n is from 1 to about 10, wherein the glycol or glycol mixture has a boiling point above about 100°

C.

9. The fluorescent ink composition of claim 8 wherein the glycol comprises triethylene glycol, and the glycol is present in an amount of from about 20-70% wt.

10. The fluorescent ink composition of claim 2 wherein the fatty acid comprises a saturated or unsaturated monocarboxylic acid having from 1 to about 40 carbon atoms and is present in an amount of from about 0.05-10% wt.

11. The fluorescent ink composition of claim 2 further comprising a brightener in an amount from about 1 to about 20% wt. and a corrosion inhibitor in an amount up to about 5% wt.

12. A method for recording fluorescent information on a substrate, comprising the steps of:

(a) providing a fluorescent ink composition which comprises;

(i) from about 5-75% wt. of an aromatic alcohol having the general structure;

##STR6## where R₁ is hydroxy alkyl having from 1-5 carbon atoms and 1-2 oxygen atoms;

R₂ is H, OH, or hdyroxy alkyl having from 1-5 carbon atoms and 1-2 oxygen atoms;

(ii) from about 10-90% wt. of a glycol component;

(iii) a fatty acid in an amount up to about 15% wt.; and

(iv) a fluorescent pigment in an amount up to about 25% wt.;

(b) ejecting one or more droplets of the fluorescent ink composition from an orifice by the selective application of pressure; and

(c) directing the droplets to a receiving surface on a substrate.

13. The method of claim 12 wherein the aromatic alcohol has the general structure:

##STR7## where R₃ is an alkyl having 1-3 carbon atoms, and wherein the fatty acid is present in an amount of from about 0.05 to about 10% wt., and the fluorescent pigment is present in an amount of from about 0.25 to about 20% wt.

14. The method of claim 13 wherein the aromatic alcohol comprises benzyl alcohol.

15. The method of claim 13 wherein the glycol comprises one or more glycols selected form the group consisting of HO--R₄ --OH and HO--[R₄ --O]_n --H where R₄ and is a straight chain or branched alkyl group having from about 1-20 carbon atoms, and n is from 1 to about 10, and wherein the glycol or glycol mixture has a boiling point above about 100°

C.

16. The method of claim 15 wherein the glycol comprises triethylene glycol in an amount of from about 20-70% wt.

17. The method of claim 13 wherein the fatty acid comprises a saturated or unsaturated monocarboxylic acid having from 1 to about 40 carbon atoms and is present in an amount of from about 0.05-10% wt.

18. The method claim 13 further comprising a brightener in an amount from about 1 to about 20% wt. and a corrosion inhibitor in an amount up to about 5% wt.

19. The method of claim 18 wherein the glycol is present in an amount of from about 40-70% wt., the fatty acid is present from about 0.25-4% wt., and the fluorescent pigment is present in an amount of from 0.5-5% wt.

20. The method of claim 19 wherein the fatty acid comprises oleic acid and the glycol comprises triethylene glycol.

21. The method of claim 13 wherein the receiving surface comprises paper, kraft paper, metal or corrugated cardboard.

22. The method of claim 13 wherein the information comprises alphanumeric text or bar codes.

23. The method of claim 13 wherein the ink fluoresces and emits light at wavelengths of from about 550-650 nanometers.