Process for the production of polycarbonate

• US 5,258,484 A
• Filed: 06/19/1992
• Issued: 11/02/1993
• Est. Priority Date: 06/27/1991
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Schomacker, Reinhard, Kirsch, Jurgen, Hucks, Uwe, Herrig, Wolfgang, Weymans, Gunther
• Primary Examiner(s): ANDERSON, HAROLD
• Application Number:
  US07/902,356
• Time in Patent Office: 501 Days
• Field of Search: 528/196, 528/198, 528/199, 526/64
• US Class Current: 528/196
• CPC Class Codes: C08G 64/24 and phenols

Abstract

A process for the continuous production of a thermoplastic aromatic polycarbonate is disclosed. Accordingly, in a reactor system which includes a tube reactor and a tank equipped with a stirrer, there are reacted a preheated dialkali diphenolate aqueous solution with gaseous phosgene in CH₂ Cl₂ and/or in chlorobenzene solution containing excess phosgene, in a mixer to form a mixed emulsion. The emulsion is then transported at least partly against the force of gravity into the tube reactor to facilitate a polycondensation reaction and in which after a residence time of at least 10 seconds and without dissipation of the heat of reaction there is added a chain terminator. The heat of reaction is dissipated in said tank and aqueous sodium hydroxide and catalyst are added to complete the reaction. The process according to the invention leads to high yields of phosgene.

Claims

1. A process for the continuous production of a thermoplastic aromatic polycarbonate in a reactor system which includes a tube reactor and a tank equipped with a stirrer, comprising

(i) preheating to at least 45°

C. a 25 to 30% by weight dialkali diphenolate solution in water

(ii) introducing gaseous phosgene in at least one member selected from the group consisting of CH₂ Cl₂ and chlorobenzlene, to form a phosgene solution containing 5 to 65 mol % excess based on the quantity of said dialkali diphenolate,

(iii) combining said phosgene solution with said dialkali diphenolate solution in a mixer to form a mixture and transporting said mixture at least partly against the force of gravity into said tube reactor to facilitate a polycondensation reaction and in which after a residence time of at least 10 seconds and without dissipation of the heat of reaction, adding a chain terminator, and establishing a pH value of 11 to 14 by adding an aqueous NaOH solution shortly before, at the same time as or shortly after the adding said chain terminator, and

(iv) dissipating said heat of reaction in said tank and

(v) adding aqueous sodium hydroxide and a catalyst selected from the group consisting of triethyl amine and N-ethyl piperidine to complete said reaction.

2. The process of claim 1 wherein said preheating is to a temperature of 45°

to 90°

C.

3. The process of claim 1 wherein said (ii) is under a pressure of 1 bar to 10 bar.

4. The process of claim 1 wherein said introducing of phosgene is with high-performance mixing units.

5. The process of claim 4 where said introducing is under pressure of up to 10 bar.

6. The process of claim 1 wherein said tank contains a circulation pipe for backmixing.

7. The process of claim 1 wherein after said residence time 5 to 35% dialkali diphenolate solution in water is introduced in said tube reactor to render a net phosgene excess of at most 10 mol- %, based on the total molar quantity of dialkali diphenolate.

8. The process of claim 1 wherein said dialkali diphenolate is disodium diphenolate of bisphenol-A.