Titanium lubricating material suitable for use in vacuum

• US 5,259,965 A
• Filed: 09/13/1991
• Issued: 11/09/1993
• Est. Priority Date: 09/21/1990
• Status: Expired due to Fees

• Current Assignee: Nissan Motor Co., Ltd.
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Yasuda, Yoshiteru, Kishi, Katsuhiro
• Primary Examiner(s): McAvoy, Ellen M.
• Application Number:
  US07/759,363
• Time in Patent Office: 788 Days
• Field of Search: 252/12, 252/12.2, 252/10, 252/11
• US Class Current: 508/108
• CPC Class Codes: C23C 8/80 After-treatment
• CPC Class Codes: F16C 33/043 Sliding surface consisting mainly of ceramics, cermets or hard carbon, e.g. diamond like carbon [DLC]
• CPC Class Codes: F16C 33/12 Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing

Abstract

To provide a lubricating material suitable for use in space or vacuum, light in weight, low in friction coefficient and long in life time, oxidation treatment is effected on the surface of titanium or titanium alloy substrate before a solid lubricating film is applied to the substrate. The formed oxide (Ti₂ O) can strengthen bonding force between the substrate (Ti) and the solid lubricating film (e.g. MoS₂).

Claims

1. A lubricating material used in space or vacuum, comprising:

a substrate made of titanium or titanium alloy;

a coating of an oxide of said titanium formed over the surface of said substrate to increase bonding force of a solid lubricating film applied thereover; and

a solid lubricating film formed over said oxide coating.

2. A lubricating material of claim 1, wherein a principal component of said oxide is Ti₂ O.

3. A lubricating material of claim 1, wherein the oxide coating is formed by cleaning said substrate in hydrofluoric acid and then heating said substrate at about 700°

C. for at least 10 hours.

4. A method of making a lubricating material usable in space or vacuum, comprising the steps of:

(a) providing a titanium or titanium alloy substrate;

(b) cleaning the substrate;

(c) heating the substrate at about 700°

C. for at least 10 hours to form a coating of titanium oxide; and

(d) applying a solid lubricating film onto the titanium oxide coating,

wherein said oxide increases bonding force of said lubricating film to said substrate.

5. The method of claim 4, wherein the titanium oxide is Ti₂ O.

6. The method of claim 4, wherein the substrate is a titanium alloy including 6 wt. % Al and 4 wt. % V.

7. The method of claim 4, wherein the substrate is cleaned by hydrofluoric acid.

8. The method of claim 4, wherein the solid lubricating film is a 1 μ

m-thick MoS₂ film.