Vacuum deposition and curing of liquid monomers

• US 5,260,095 A
• Filed: 08/21/1992
• Issued: 11/09/1993
• Est. Priority Date: 08/21/1992
• Status: Expired due to Term

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Affinito, John D.
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): DANG, VI
• Application Number:
  US07/933,447
• Time in Patent Office: 445 Days
• Field of Search: 427/124, 427/255.5, 427/255.6, 427/294, 427/428
• US Class Current: 427/124
• CPC Class Codes: B05D 3/0493 using vacuum
• CPC Class Codes: B05D 5/068 achieved by multilayers B05D5/066 takes precedence
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention is the formation of solid polymer layers under vacuum. More specifically, the present invention is the use of "standard" polymer layer-making equipment that is generally used in an atmospheric environment in a vacuum, and degassing the monomer material prior to injection into the vacuum. Additional layers of polymer or metal may be vacuum deposited onto solid polymer layers.

Formation of polymer layers under a vacuum improves material and surface characteristics, and subsequent quality of bonding to additional layers. Further advantages include use of less to no photoinitiator for curing, faster curing, fewer impurities in the polymer electrolyte, as well as improvement in material properties including no trapped gas resulting in greater density, and reduced monomer wetting angle that facilitates spreading of the monomer and provides a smoother finished surface.

Claims

1. A method of making a first solid polymer layer, comprising the steps of:

(a) placing a moving substrate into a vacuum chamber,

(b) placing a mechanical liquid-monomer spreading apparatus into the vacuum chamber;

(c) degassing a first liquid monomer,

(d) depositing a first thin layer of the degassed liquid monomer from said liquid-monomer spreading apparatus onto the moving substrate within the vacuum chamber, and

(e) curing said first thin layer.

2. A method as recited in claim 1, further comprising the step of:

(a) vacuum depositing metal onto said first solid polymer layer.

3. A method as recited in claim 1, further comprising the steps of:

(a) depositing a second thin layer of a second degassed liquid monomer onto said first solid polymer layer under vacuum,

(i) curing said second thin layer.

4. A method as recited in claim 2, further comprising the steps of:

(a) depositing a second thin layer of a second degassed liquid monomer onto said metal under vacuum,

(i) curing said second thin layer.

5. A method as recited in claim 1, wherein said first liquid monomer is a liquid monomer cathode material.

6. A method as recited in claim 5, wherein a layer of metal is deposited onto said moving substrate in advance of depositing said liquid monomer cathode material.