Low stress relaxation elastomeric nonwoven webs and fibers

• US 5,260,126 A
• Filed: 01/10/1990
• Issued: 11/09/1993
• Est. Priority Date: 01/10/1990
• Status: Expired due to Term

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Corporation
• Inventors: Stopper, Steven R., Collier, L. Warren IV
• Primary Examiner(s): Bell, James J.
• Application Number:
  US07/463,079
• Time in Patent Office: 1,399 Days
• Field of Search: 525/89, 525/98, 524/505, 428/230, 428/231, 428/394, 428/283, 428/288, 428/903, 428/224
• US Class Current: 442/329
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 53/025 modified
• CPC Class Codes: D04H 1/587 characterised by the bonding agents used
• CPC Class Codes: Y10S 428/903 Microfiber, less than 100 micron diameter
• CPC Class Codes: Y10T 442/602 Nonwoven fabric comprises an elastic strand or fiber material
• CPC Class Codes: Y10T 442/637 Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material

Abstract

An elastic nonwoven web is formed from elastic fibers composed of a blend of (1) a styrene-poly(ethylenepropylene)-styrene thermoplastic elastomeric block copolymer or a mixture of a styrene-poly(ethylenepropylene)-styrene elastomeric block copolymer and a styrene-poly(ethylene-butylene)-styrene elastomeric block copolymer, and (2) a tackifying resin in which the elastic nonwoven web has a stress relaxation of less than about 30 percent. The blend used to form the elastic nonwoven web and/or elastic fibers may also include a polyolefin and an extending oil.

Claims

1. An elastic nonwoven web comprising a coherent matrix of fibers formed from an extrudable blend, the blend comprising:

(A) an elastomeric polymer selected from the group consisting of styrene-poly(ethylene-propylene)-styrene elastomeric block copolymer and a mixture of styrene-poly(ethylene-polypropylene)-styrene and styrene-poly(ethylene-butylene)-styrene elastomeric block copolymers; and

(B) a tackifying resin, wherein said elastic nonwoven web has a stress relaxation of less than about 30 percent.

2. The elastic nonwoven web of claim 1, wherein said styrene-poly(ethylene-propylene)-styrene elastomeric block copolymer has the formula:

##STR3## wherein m is an integer from about 38 to 337; and

n is an integer from about 500 to 1860; and

R is a benzyl group.

3. The elastic nonwoven web of claim 2, wherein the styrene-poly(ethylene-propylene)-styrene block copolymer has an average molecular weight ratio of polystyrene endblocks to poly(ethylene-propylene) midblocks ranging from about 10:

90 to about 25;

75.

4. The elastic nonwoven web of claim 1 wherein the mixture of styrene-poly(ethylene-polypropylene)-styrene and styrene-poly(ethylene-butylene)-styrene elastomeric block copolymers contains at least about 40 parts by weight styrene-poly(ethylene-polypropylene)-styrene elastomeric block copolymer per 100 parts of elastomeric block copolymer.

5. The elastic nonwoven web of claim 1, wherein said tackifying resin is selected from the group including hydrogenated hydrocarbon resins and terpene hydrocarbon resins.

6. The elastic nonwoven web of claim 1, wherein the blend further includes a polyolefin.

7. The elastic nonwoven web of claim 6, wherein the polyolefin is selected from the group including polyethylene, polypropylene, polybutylene, polyethylene copolymers, polypropylene copolymers, polybutylene copolymers and mixtures thereof.

8. The elastic nonwoven web of claim 6, wherein the blend further includes an extending oil.

9. The elastic nonwoven web of claim 8, wherein the extending oil is a mineral oil.

10. The elastic nonwoven web of claim 8, wherein said blend comprises from about 50 to about 80 percent, by weight, of an elastomeric polymer, from about 15 to about 28 percent, by weight, of a tackifying resin, from about 3 to about 23 percent, by weight, of a polyolefin, and from about 0 to about 15 percent, by weight, of an extending oil.

11. The elastic nonwoven web of claim 1, wherein said fibers are meltblown fibers.

12. The elastic nonwoven web of claim 11, wherein said meltblown fibers include microfibers.

13. An elastic nonwoven web consisting essentially of a coherent matrix of fibers formed from an extrudable blend, the blend including:

(A) an elastomeric polymer selected form the group consisting of styrene-poly(ethylene-propylene)-styrene elastomeric block copolymer and a mixture of styrene-poly(ethylene-polypropylene)-styrene and styrene-poly(ethylene-butylene)-styrene elastomeric block copolymers;

(B) a polyolefin;

(C) a tackifying resin; and

(D) an extending oil,

wherein said elastic nonwoven web has a stress relaxation of less than about 30 percent.

14. A elastic nonwoven web comprising:

(A) a coherent matrix of elastic fibers formed from an extrudable blend, the blend comprising;

(i) an elastomeric polymer selected form the group consisting of styrene-poly(ethylene-propylene)-styrene elastomeric block copolymer and a mixture of a styrene-poly(ethylenepolypropylene)-styrene and a styrene-poly(ethylenebutylene)-styrene elastomeric block copolymer; and

(ii) a tackifying resin, and

(B) at least one other material selected form the group consisting of nonelastic fibers and particulates; and

wherein said web has a stress relaxation of less than about 30 percent.

15. The elastic nonwoven web of claim 14, wherein said styrene-poly(ethylene-propylene)-styrene elastomeric block copolymer has the formula:

##STR4## wherein m is an integer from about 38 to 337; and

n is an integer from about 500 to 1860; and

R is a benzyl group.

16. The elastic nonwoven web of claim 15, wherein the styrene-poly(ethylene-propylene)-styrene block copolymer has an average molecular weight ratio of polystyrene endblocks to poly(ethylene-propylene) midblocks ranging from about 10:

90 to about 25;

75.

17. The elastic nonwoven web of claim 14 wherein the mixture of styrene-poly(ethylene-polypropylene)-styrene and styrene-poly(ethylene-butylene)-styrene elastomeric block copolymers contains at least about 40 parts by weight styrene-poly(ethylene-polypropylene)-styrene elastomeric block copolymer per 100 parts of elastomeric block copolymer.

18. The elastic nonwoven web of claim 14, wherein said tackifying resin is selected from the group including hydrogenated hydrocarbon resins and terpene hydrocarbon resins.

19. The elastic nonwoven web of claim 14, wherein the blend further includes a polyolefin.

20. The elastic nonwoven web of claim 19, wherein the polyolefin is selected from the group including polyethylene, polypropylene, polybutylene, polyethylene copolymers, polypropylene copolymers, polybutylene copolymers and mixtures thereof.

21. The elastic nonwoven web of claim 19, wherein the blend further includes an extending oil.

22. The elastic nonwoven web of claim 21, wherein the extending oil is a mineral oil.

23. The elastic nonwoven web of claim 21, wherein said blend comprises from about 50 to about 80 percent, by weight, of the an elastomeric polymer, from about 15 to about 28 percent, by weight, of a tackifying resin, from about 3 to about 23 percent, by weight, of a polyolefin, and from about 0 to about 15 percent, by weight, of an extending oil.

24. The elastic nonwoven web of claim 14, wherein the elastic fibers are meltblown fibers.

25. The elastic nonwoven web of claim 24, wherein the meltblown fibers include microfibers.

26. The elastic nonwoven web of claim 14 comprising from about 20 percent, by weight, to about 99 percent, by weight, of the elastic fibers formed from a blend including a styrene-poly(ethylene-propylene)-styrene thermoplastic elastomeric block copolymer and from about 1 percent, by weight, to about 80 percent, by weight, of the other materials.

27. The elastic nonwoven web of claim 14 comprising from about 50 percent to about 99 percent, by weight, of the elastic fibers formed from a blend including a styrenepoly(ethylene-propylene)-styrene thermoplastic elastomeric block copolymer and from about 1 percent, by weight, to about 49 percent, by weight, of said nonelastic fibers and from about 1 percent, by weight, to about 49 percent, by weight, of said particulate materials.

28. The elastic nonwoven web of claim 14, wherein said nonelastic fibers are selected from the group consisting of polyester fibers, polyamide fibers, glass fibers, polyolefin fibers, cellulosic derived fibers, multi-component fibers, natural fibers, absorbent fibers, electrically conductive fibers or blends of two or more of said nonelastic fibers.

29. The elastic nonwoven web of claim 14, where said particulate materials are selected from the group consisting of activated charcoal and superabsorbents.

30. An elastic nonwoven web consisting essentially of:

(A) a coherent matrix of elastic fibers formed from an extrudable blend, the blend including;

(i) an elastomeric polymer selected from the group consisting of styrene-poly(ethylene-propylene)-styrene elastomeric block copolymer and a mixture of styrene-poly(ethylene-polypropylene)-styrene and styrene-poly(ethylene-butylene)-styrene elastomeric block a copolymers;

(ii) a polyolefin;

(iii) a tackifying resin; and

(iv) an extending oil, and

(B) at least one other material selected from the group consisting of nonelastic fibers and particulates; and

wherein said web has a stress relaxation of less than about 30 percent.