Hydrophilic foam pad for hair styling

• US 5,261,426 A
• Filed: 05/30/1991
• Issued: 11/16/1993
• Est. Priority Date: 05/30/1991
• Status: Expired due to Term

• Current Assignee: Creative Products Resource, Inc. (Henkel AG & Co KGaA)
• Original Assignee: Creative Products Resource Associates, Ltd.
• Inventors: Murphy, Betty J., Kellett, George W.
• Primary Examiner(s): Mancene, Gene
• Assistant Examiner(s): LaViola, Frank A.
• Application Number:
  US07/707,630
• Time in Patent Office: 901 Days
• Field of Search: 132/108, 132/110, 132/111, 132/202, 132/203, 132/204, 132/205, 132/208, 132/320, 521/52, 424/70, 424/73, 424/, 252/91, 252/106, 252/DIG. 3, 252/5, 252/7, 252/13, 15/104.93, 15/104.94
• US Class Current: 132/108
• CPC Class Codes: A45D 19/026 having brush or comb applicators A45D24/22 take precedence; brushes with reservoir or other means for applying substances A46B11/00
• CPC Class Codes: A45D 19/028 having applicators other than brushes or combs, e.g. rollers, balls or sponges
• CPC Class Codes: A45D 2/22 with means for applying liquids therethrough
• CPC Class Codes: A45D 24/22 Combs with dispensing devices for liquids, pastes or powders
• CPC Class Codes: A46B 11/001 with integral reservoirs A46B11/0003, A46B11/0006 take precedence
• CPC Class Codes: A46B 15/00 Other brushes; Brushes with additional arrangements
• CPC Class Codes: A46B 2200/104 Hair brush
• CPC Class Codes: A61K 8/0208 Tissues; Wipes; Patches
• CPC Class Codes: A61Q 5/006 Antidandruff preparations
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

A hair conditioning and styling pad is provided which comprises a shaped body of a resilient, open-celled, hydrophilic polyurethane foam matrix integrally incorporating an aqueous phase incorporating about 70-90% water, about 5-25% of a hair conditioning agent, and a nonionic surfactant. The pad is preferably affixed to the tines of a styling brush or comb to yield a composite brush or comb which is effective to condition and style hair.

Claims

1. A hair conditioning and styling pad consisting essentially of a resilient, open-celled, hydrophilic polyurethane foam matrix, wherein bound to said matrix is an aqueous phase incorporating about 70-90% water, about 5-25% of a polymeric organic film-forming hair conditioning agent and about 0.1-10% of a nonionic surfactant, wherein said aqueous phase does not include a significant amount of water-immiscible organic solvent.

2. The pad of claim 1 wherein the nonionic surfactant comprises a water-soluble polyoxyalkylene block copolymer.

3. The pad of claim 2 wherein the copolymer comprises a polyoxypropylene ether having a molecular weight of about 1750-2250 and a polyoxyethylene content which is about 40-60% of the copolymer by weight.

4. The pad of claim 3 wherein the surfactant further comprises about 0.25-5% of a silicone glycol copolymer.

5. The pad of claim 1 wherein the aqueous phase further comprises about 0.5-2.5% of an inorganic alkali metal or alkaline earth metal salt.

6. The pad of claim 1 wherein the hair conditioning agent comprises a cationic organic polymer.

7. The pad of claim 6 wherein the hair conditioning agent comprises collagen or a collagen derivative.

8. The pad of claim 6 wherein the hair conditioning agent comprises a cationic cellulosic polymer.

9. The pad of claim 6 wherein the hair conditioning agent comprises a vinylpyrrolidone-based polymer or copolymer.

10. The pad of claim 1 which further comprises a minor but effective amount of fragrance.

11. A hair conditioning and styling pad consisting essentially of a resilient, open-celled, hydrophilic polyurethane foam matrix, wherein bound to said matrix, is an aqueous phase incorporating about 75-85% water, about 10-20% of a polymeric organic film-forming, hair conditioning agent, about 0.25-5% of a nonionic surfactant, and an amount of an inorganic salt effective to substantially enhance the release of the aqueous phase from the foam matrix when the pad is pressed against the hair, wherein said aqueous phase does not include a significant amount of water-immiscible organic solvent.

12. The pad of claim 11 wherein the cells of said pad substantially vary in diameter.

13. The pad of claim 11 wherein a substantial number of said cells are about 1.0-5.0 mm in diameter.

14. The pad of claim 11 wherein the aqueous phase further comprises about 1-20% of a particulate soft mineral absorbent which is silane-coupled to the foam matrix.

15. The pad of claim 11 wherein the aqueous phase further comprises a minor but effective amount of a topically active insecticide or a minor but effective amount of an antidandruff agent.

16. The pad of claim 11 wherein the aqueous phase further comprises a minor but effective amount of fragrance.

17. The pad of claim 11 wherein the hair conditioning agent comprises hydrolyzed animal protein or a derivative thereof.

18. The pad of claim 11 wherein the hair conditioning agent comprises a cationic polymer.

19. The pad of claim 18 wherein the hair conditioning agent comprises a cationic cellulosic polymer.

20. A hair styling and conditioning pad formed by a process comprising:

(a) forming an aqueous reactant phase comprising a dispersion in about 70-90% water of about 5-25% of a polymeric organic film-forming hair conditioning agent and about 0.1-10% of a nonionic surfactant comprising a polyoxalkylene block copolymer of a mixture of a polyoxyalkoxylated lanolin and a polyoxyalkoxylated fatty alcohol, wherein said aqueous reactant phase does not include a significant amount of water-immiscible organic solvent; and

(b) mixing said aqueous reactant phase with a water-foamable prepolymer resin which contains at least 2 free isocyanate groups per resin molecule in a weight ratio of aqueous reactant phase to prepolymer resin of about 3.0-1.0;

1, thereby forming said resin into a hydrophilic, open-celled, highly reticulated polyurethane foam pad.

21. The pad of claim 20, wherein in step (b) the final mole ratio of water to total free resin isocyanate groups is about 20-150:

1.

22. The pad of claim 20 wherein the aqueous phase further comprises about 1-20% of a particulate mineral absorbent and about 0.1-5% by weight of said absorbent of a silane-coupling agent.

23. The pad of claim 20 wherein said hair conditioning agent comprises a cationic cellulosic polymer.

24. The pad of claim 20 wherein said hair conditioning agent comprises collagen or a collagen derivative.

25. The pad of claim 20 wherein said hair conditioning agent comprises a vinylpyrrolidone-based polymer or copolymer.

26. The pad of claim 20 wherein the aqueous reactant phase comprises 0.5-2.5% of an inorganic alkali metal or alkaline earth metal salt.

27. An assembly for treatment of hair or the like;

said assembly comprising;

(a) a base member; and

(b) a pad member mounted on said base member;

said pad member comprising a resilient, open-celled, hydrophilic polyurethane foam matrix, wherein bound to said matrix is an aqueous phase incorporating about 70-90% water, about 5-25% of a polymeric organic film-forming hair conditioning agent and about 0.1-10% of a nonionic surfactant, wherein said aqueous phase does not include a significant amount of water-immiscible organic solvent.

28. An assembly according to claim 27 including tine means projecting outwardly from said pad member.

29. An assembly according to claim 27 wherein:

(a) said base member comprises a brush having a plurality of tines projecting outwardly therefrom; and

,

(b) said pad member is impaled upon said plurality of tines.

30. An assembly according to claim 27 wherein said base member is a hair roller.

31. A kit for providing styling and conditioning of hair;

said kit including;

(a) at least one base member; and

(b) at least one pad member mountable on said base member;

said pad member comprising a resilient, open-celled, hydrophilic polyurethane foam matrix, wherein bound to said matrix is an aqueous phase incorporating about 70-90% water, about 5-25% of a polymeric organic film-forming hair conditioning agent and about 0.1-10% of a nonionic surfactant, wherein said aqueous phase does not include a significant amount of organic solvent.

32. A kit according to claim 31 wherein:

(a) said base member comprises a brush having a plurality of tines projecting outwardly therefrom; and

(b) said pad member is operably impalable on said plurality of tines.

33. The kit according to claim 31 wherein the base member comprises a hair roller.

34. A method of styling and conditioning hair;

said method comprising;

(a) providing an assembly comprising a base member with a pad member mounted thereon;

said pad member comprising a resilient, open-celled hydrophilic polyurethane foam matrix, wherein bound to said matrix is an aqueous phase incorporating about 70-90% water, about 5-25% of a polymeric organic film-forming hair conditioning agent and about 0.1-10% of a nonionic surfactant, wherein said aqueous phase does not include a significant amount of organic solvent; and

(b) manipulating said base member to bring said pad member into contact with hair to be styled and conditioned.

35. The method according to claim 34 including the steps of:

(a) providing tine means projecting outwardly from said pad member; and

(b) brushing said tine means through the hair to be styled and conditioned.

36. The method according to claim 34 wherein:

(a) said base member comprises a brush having a plurality of tines projecting outwardly therefrom; and

(b) said pad member is impaled upon said plurality of tines.

37. The method according to claim 34 wherein said base member comprises a hair roller.