Porous plastic film product, useful as a breathable wall covering or filters

• US 5,262,444 A
• Filed: 11/30/1992
• Issued: 11/16/1993
• Est. Priority Date: 11/30/1992
• Status: Expired due to Fees

• Current Assignee: Borden Inc. (Bakelite UK TopCo Ltd.)
• Original Assignee: Borden Inc. (Bakelite UK TopCo Ltd.)
• Inventors: Andrews, Richard C., Rusincovitch, George, Roe, Paul J.
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/985,376
• Time in Patent Office: 351 Days
• Field of Search: 521/50.5, 521/73, 521/79, 521/85, 521/88, 521/90, 522/33, 522/39, 522/42, 522/44, 522/915
• US Class Current: 521/50.5
• CPC Class Codes: B32B 2307/724 Permeability to gases, adsorption
• CPC Class Codes: B32B 2307/7265 Non-permeable
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/22 using plasticisers
• CPC Class Codes: C08J 9/141 Hydrocarbons
• CPC Class Codes: D06N 2205/026 Plastisol
• CPC Class Codes: D06N 2209/025 Insulating, sound absorber
• CPC Class Codes: D06N 2209/123 Breathable
• CPC Class Codes: D06N 2209/126 Permeability to liquids, absorption
• CPC Class Codes: D06N 2213/04 Perforated layer
• CPC Class Codes: D06N 3/0063 Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
• CPC Class Codes: D06N 3/0088 by directly applying the resin D06N3/0045 takes precedence
• CPC Class Codes: D06N 3/06 with polyvinylchloride or its copolymerisation products surface treatment or foaming for floor coverings D06N7/0007
• CPC Class Codes: D06N 7/0002 Wallpaper or wall covering on textile basis

Abstract

The invention relates to a breathable, plastic film, useful as a wall covering material. A low boiling additive, such as water, is added to a plastisol before extrusion. During extrusion and curing of the plastisol into a film or coating, the low boiling additive is volatilized and the resulting evolved gas perforates the forming film. In this manner a permeable plastic film, such as vinyl, is produced.

Claims

1. A permeable plastic film prepared by a process comprising:

(1) combining a curable plastic and a plasticizer to form a plastisol;

(2) combining with the plastisol an additive with a boiling point below the boiling point of the plastisol;

(3) extruding the mixture from step (2) to form a film;

(4) curing the film from step (3) under conditions whereby the additive volatilizes through the cured or curing film to thereby leave a multiplicity of holes in the resulting plastic film.

2. The plastic film of claim 1 wherein the curable plastic is selected from the group consisting of polyvinyl chloride, polyesters, polyethylene terephthalate, polyvinyl acetate, polyvinylidene chloride, polyvinylidene fluoride, and blends thereof and coextrusions thereof.

3. The plastic film of claim 1 wherein the curable plastic is selected from the group consisting of polyimides, polyamides, nylon, and polysulfone.

4. The plastic film of claim 1 wherein the curable plastic is selected from the group consisting of polyethylene, polypropylene, polystyrene, polymethylstyrene, polyisoprene, and styrene-acrylonitrile copolymer resins.

5. The plastic film of claim 1 wherein the curable plastic is selected from the group consisting of silicone resins, polycarbonates, styrene-butadiene copolymers, polycaprolactams, and natural rubber latex.

6. The plastic film of claim 1 wherein the curable plastic is selected from the group consisting of aliphatic urethane acrylate oligomers, polyacrylates, polymethacrylates, isobornyl acrylate, polymethylmethacrylates, and diol diacrylates.

7. The plastic film of claim 1 wherein the curable plastic comprises polyvinyl chloride.

8. The plastic film of claim 1 wherein the plasticizer is selected from the group consisting of phthalate esters, adipate esters, trimellitate esters, sebacate esters, azelates, glutamates, tallates, laurates, acetates, and aryl phosphate esters.

9. The plastic film of claim 1 wherein the plasticizer is selected from the group consisting of glycols, epoxidized soybean oil, polyethers, and amides.

10. The plastic film of claim 1 wherein the plasticizer comprises n-dioctyl phthalate.

11. The plastic film of claim 1 wherein the plasticizer is present in the plastisol at a level of from 1 to about 50 weight percent.

12. The plastic film of claim 1 wherein the additive is water and is present in the plastisol at 5% to 20% by weight.

13. The plastic film of claim 1 wherein the additive is present in the plastisol at a level of from about 1 to 30% by weight and is selected from the group consisting of water, C₁ -C₁₀ alcohols, C₁ -C₁₀ ethers, crown ethers, cyclic Si₄ -Si₈ siloxanes, linear Siloxanes, C₁ -C₁₀ aldehydes, C₁ -C₁₀ esters, C₁ -C₁₀ ketones, and mixtures thereof.

14. The plastic film of claim 1 wherein the additive is present in the plastisol at a level of from about 1 to 30% by weight and is selected from latent gas generators and hydrated silica gel.

15. The plastic film of claim 14 wherein the latent gas generator generates a gas selected from the group consisting of hydrogen, oxygen, nitrogen, carbon dioxide, carbon monoxide and water vapor.

16. The plastic film of claim 15 wherein the latent gas generator is selected from the group consisting of azodicarbonamide, p-toluene sulfonyl semicarbazide, and p,p-oxybis benzene sulfonyl hydrazide.

17. The plastic film of claim 1 wherein the boiling point of the additive is between 30°

and 120°

C.

18. The plastic film of claim 1 wherein the mixture in step (3) is extruded onto a substrate, and subsequently cured to form a composite article which exhibits a Perm value of from 1.0 to 20.0 by the Desiccant Method, or a Perm value of from 2.0 to about 18.0 by the Water Method.

19. The plastic film of claim 18 wherein the substrate is a fabric selected from the group consisting of cotton, polyester, cellulose, felt, fiberglass and polyolefin.

20. The plastic film of claim 18 wherein the substrate is paper.

21. The plastic film of claim 18 wherein the substrate is polyvinyl chloride.

22. The plastic film of claim 1 wherein the film is thermally curable and is cured in step (4) by exposure to thermal conditions sufficient to volatilize the additive and initiate crosslinking of the plastic comprising the film.

23. The plastic film of claim 1 wherein the plastic is ultraviolet radiation curable and wherein the composition further comprises a photoinitiator, and is cured in step (4) by exposure to sufficient ultraviolet radiation.

24. The plastic film of claim 23 wherein the photoinitiator is selected from the group consisting of hydroxycyclohexylphenyl ketone;

hydroxymethylphenylpropanone;

dimethoxyphenylacetophenone;

2-methyl-l-[4-(methylthio)phenyl]-2-morpholino-propanone-1;

1-(4-isopropylphenyl)-2-hydroxy-2-methylpropan-1-one;

1-(4-dodecylphenyl)-2-hydroxy-2-methylpropan-1-one;

4-(2-hydroxyethoxy)phenyl-(2-hydroxy-2-propyl)ketone;

diethoxyacetophenone;

2,2-di-sec-butoxyacetophenone;

diethoxyphenyl acetophenone; and

mixtures of these.

25. The plastic film of claim 1 wherein the plastic is electron beam radiation-curable and sufficient electron beam radiation is applied to cure the film and volatilize the additive to produce a porous film.

26. The porous plastic film of claim 11 wherein the plastic is polyvinyl chloride, the plasticizer is n-dioctyl phthalate, the additive is water, and wherein the plastic is present in the plastisol at from 30 to 50 weight percent, and the plasticizer is present in the plastisol at from 20 to 40 weight percent, and the additive is present in the plastisol at about fifteen weight percent, and wherein the substrate is paper, and the curing is achieved by exposing the coated substrate to a temperature range of from 120°

to 150°

C., and wherein the resulting cured film has holes up to 40 microns in diameter, and wherein the holes are present at a density of 1 to about 5,000 holes per square centimeter.

27. A process for preparing a permeable plastic film comprising the steps:

(1) combining a curable plastic and a plasticizer to form a plastisol;

(2) combining with the plastisol an additive with a boiling point below the boiling point of the plastisol;

(3) extruding the mixture from step (2) to form a film;

(4) curing the film from step (3) under conditions whereby the additive volatilizes through the cured or curing film to thereby leave a multiplicity of holes in the resulting plastic film.

28. The process of claim 27 wherein the plastic is selected from the group consisting of polyvinyl chloride, polyesters, polyethylene terephthalate, polyvinyl acetate, polyvinylidene chloride, polyvinylidene fluoride, and blends thereof and coextrusions thereof.

29. The process of claim 27 wherein the plastic is selected from the group consisting of polyimides, polyamides, nylon, and polysulfone.

30. The process of claim 27 wherein the plastic is selected from the group consisting of polyethylene, polypropylene, polystyrene, polymethylstyrene, polyisoprene, and styrene-acrylonitrile copolymer resins.

31. The process of claim 27 wherein the plastic is selected from the group consisting of silicone resins, polycarbonates, styrene-butadiene copolymers, polycaprolactams, and natural rubber latex.

32. The process of claim 27 wherein the plastic is selected from the group consisting of aliphatic urethane acrylate oligomers, polyacrylates, polymethacrylates, isobornyl acrylate, polymethylmethacrylates, and diol diacrylates.

33. The process of claim 27 wherein the plastic comprises polyvinyl chloride.

34. The process of claim 27 wherein the plasticizer is selected from the group consisting of phthalate esters, adipate esters, trimellitate esters, sebacate esters, glutamates, tallates, laurates, acetates, azelates, glutarates, and aryl phosphate esters.

35. The process of claim 27 wherein the plasticizer is selected from the group consisting of epoxidized soybean oil, amides, glycols, and polyethers.

36. The process of claim 27 wherein the plasticizer comprises n-dioctyl phthalate.

37. The process of claim 27 wherein the plasticizer is present in the plastisol at a level of 20 to 50 weight percent.

38. The process of claim 27 wherein, the additive is water and is present in the plastisol at a level of from about 5 to 20% by weight.

39. The process of claim 27 wherein the additive is selected from the group consisting of water, C₁ -C₁₀ alcohols, C₁ -C₁₀ ethers, crown ethers, cyclic Si₄ -Si₈ siloxanes, linear siloxanes, C₁ -C₁₀ aldehydes, C₁ -C₁₀ esters, esters, C₁ -C₁₀ ketones, hydrated silica gel, and mixtures thereof.

40. The process of claim 27 wherein the additive is a latent gas generator which generates a gas selected from the group consisting of hydrogen, oxygen, nitrogen, carbon dioxide, carbon monoxide and water vapor.

41. The process of claim 40 wherein the latent gas generator is selected from the group consisting of azodicarbomanide, p-toluene sulfonyl semicarbazide, and p,p-oxybis benzene sulfonyl hydrazide.

42. The process of claim 27 wherein the boiling point of the additive is between 30°

and 120°

C.

43. The process of claim 27 wherein the mixture in step (3) is extruded onto a substrate, and subsequently cured to produce in step (4) a substrate with a cured coating thereon.

44. The process of claim 43 wherein the substrate is a fabric selected from the group consisting of cotton, felt, polyester, cellulose, fiberglass and polyolefin.

45. The process of claim 43 wherein the substrate is paper.

46. The process of claim 43 wherein the substrate is polyvinylchloride.

47. The process of claim 27 wherein the plastic is thermally curable and is cured by exposure to thermal conditions sufficient to volatilize the additive and initiate crosslinking of the plastic comprising the film.

48. The process of claim 27 wherein the plastic is ultraviolet radiation curable, and wherein the composition further comprises a photoinitiator and is cured by exposure to sufficient ultraviolet radiation.

49. The process of claim 48 wherein the photoinitiator is selected from the group consisting of hydroxycyclohexylphenyl ketone;

hydroxymethylphenylpropanone;

dimethoxyphenylacetophenone;

2-methyl-l-[4-(methylthio)phenyl]-2-morpholino-propanone-1;

1-(4-isopropylphenyl)-2-hydroxy-2-methylpropan-1-one;

1-(4-dodecylphenyl)-2-hydroxy-2-methylpropan-1-one;

4-(2-hydroxyethoxy)phenyl-(2-hydroxy-2-propyl)ketone;

diethoxyacetophenone;

2,2-di-sec-butoxyacetophenone;

diethoxyphenyl acetophenone; and

mixtures of these.

50. The process of claim 27 wherein the plastic is electron beam radiation-curable and sufficient electron beam radiation is applied to cure the plastic and volatilize the additive to produce a porous plastic film.

51. The process of claim 43 wherein the plastic is polyvinyl chloride, the plasticizer is n-dioctyl phthalate, the additive is water, and wherein the plastic is present in the plastisol at 40 to 50 weight percent, and the plasticizer is present in the plastisol at 20 to 40 weight percent, and the additive is present in the plastisol at about fifteen weight percent, and wherein the substrate is paper, and the curing is achieved by exposing the coated substrate to a temperature between 270°

F. and 410°

F., and wherein the resulting plastic film has holes up to 40 microns in diameter, and wherein the holes are present at a density of 1 to about 5,000 holes per square centimeter.

52. The process of claim 27 wherein the cured plastic film has a Perm value of from 1.0 to 20.0 using the Desiccant Method or from 2.0 to 18.0 using the Water Method.

53. The process of claim 43 wherein the coated substrate has a Perm value of from 1.0 to 20.0 using the Desiccant Method or from 2.0 to 18.0 using the Water Method.

54. A filter comprising a permeable plastic film produced by a process comprising:

(1) combining a curable plastic and a plasticizer to form a plastisol;

(2) combining with the plastisol an additive with a boiling point below the boiling point of the plastisol;

(3) extruding the mixture from step (2) to form a film;

(4) curing the film from step (3) under conditions whereby the additive volatilizes through the cured or curing film to thereby leave a multiplicity of holes in the resulting plastic film.

55. A sound absorbing material comprising a permeable plastic film produced by a process comprising:

(1) combining a curable plastic and a plasticizer to form a plastisol;

(2) combining with the plastisol an additive with a boiling point below the boiling point of the plastisol;

(3) extruding the mixture from step (2) to form a film;

(4) curing the film from step (3) under conditions whereby the additive volatilizes through the cured or curing film to thereby leave a multiplicity of holes in the resulting plastic film;

which plastic film can reduce sound transmission better than a plastic film without the multiplicity of holes.

56. A process for reducing sound transmission from a room comprising:

(1) combining a curable plastic and a plasticizer to form a plastisol;

(2) combining with the plastisol an additive with a boiling point below the boiling point of the plastisol;

(3) extruding the mixture from step (2) to form a film;

(4) curing the film from step (3) under conditions whereby the additive volatilizes through the cured or curing film to thereby leave a multiplicity of holes in the resulting plastic film which plastic film can reduce sound transmission better than a plastic film without the multiplicity of holes; and

(5) applying at least one layer of said film to the walls of a room, whereby the sound transmission from the room through the wall is reduced.

57. A process for reducing mildew development within a wall comprising the steps:

(1) combining a curable plastic and a plasticizer to form a plastisol;

(2) combining with the plastisol an additive with a boiling point below the boiling point of the plastisol;

(3) coating the mixture from step (3) onto a substrate selected from the group consisting of paper, cotton, felt, polyester, cellulose, fiberglass and polyolefin;

(4) curing the coating under conditions whereby the additive volatilizes through the cured or curing film to thereby leave a multiplicity of holes in the resulting coated substrate;

(5) applying the coated substrate to a wall, whereby water vapor within the wall can permeate the coated substrate to reduce mildew development within the wall.