Hydrophilic compositions which are fog-resistant

• US 5,262,475 A
• Filed: 05/12/1992
• Issued: 11/16/1993
• Est. Priority Date: 05/12/1992
• Status: Expired due to Term

• Current Assignee: FSI Coating Technologies, Inc.
• Original Assignee: Film Specialties, Inc.
• Inventors: Creasy, Walter S.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): CLARK, WILLIAM R H
• Application Number:
  US07/882,458
• Time in Patent Office: 553 Days
• Field of Search: 525/58, 525/56, 525/57, 525/518, 525/203, 427/163, 427/164, 427/165, 428/46
• US Class Current: 525/58
• CPC Class Codes: C08J 2300/10 Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
• CPC Class Codes: C08J 3/246 Intercrosslinking of at least two polymers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08L 39/04 Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
• CPC Class Codes: C08L 61/20 Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen with aminophenols C08L61/04
• CPC Class Codes: Y10T 428/162 Transparent or translucent layer or section

Abstract

A polymer composition in the form of an alloy is disclosed, having hydrophilic and anti-fogging properties. The polymer alloy can be used as a coating, as an unsupported film or as a substrate having the desired anti-fogging properties.

The composition can be used where hydrophilic properties are desired. Surfaces coated with the composition described herein are more readily wetted by water or aqueous fluids, and may have a coefficient of friction of 0.10 or less when in contact with water.

The preferred composition contains a water-soluble polyvinyl alcohol and a water-soluble polyvinyl pyrollidone polymer in a weight ratio of about 4:1 to about 1:10.

A crosslinking agent comprised of a melamine, a mineral acid or a strong organic acid is included.

The composition is preferably applied to a substrate, such as a lens, and cured to form the coating.

Claims

1. A polymer composition which when cured exhibits anti-fogging properties consisting essentially of:

(a) a water-soluble polyvinyl alcohol polymer and a water-soluble polyvinyl pyrollidone polymer,

the polyvinyl alcohol polymer having a weight average molecular weight of about 20,000 to about 200,000 and the polyvinyl pyrollidone polymer having a weight average molecular weight of about 30,000 to about 400,000,

and (b) a crosslinking agent comprised of a melamine, a mineral acid or a strong organic acid,

said crosslinking agent being present in an amount up to about 50% by weight based upon the weight of the non-volatile components contained in the composition.

2. A polymer composition according to claim 1 wherein the water-soluble polyvinyl alcohol polymer and the water-soluble polyvinyl pyrollidone polymer form an alloy.

3. A polymer composition according to claim 1 wherein the weight ratio of the polyvinyl alcohol polymer to the polyvinyl pyrollidone polymer being in the range of from about 4:

1 to about 1;

10.

4. A polymer composition in accordance with claim 1 further comprised of a chain extender, crosslink density modifier or surfactant.

5. A polymer composition in accordance with claim 1 wherein the water-soluble polyvinyl pyrollidone polymer is a copolymer selected from the group consisting of vinylpyrollidone/vinyl acetate, vinylpyrollidone/vinylcaprolactam and vinylpyrollidone/N,N-dimethylacrylamide.

6. A polymer composition in accordance with claim 1 wherein the polyvinyl alcohol is a water soluble copolymer selected from the group consisting of vinyl alcohol/vinyl acetate, vinyl alcohol/vinyl acetate/vinyl acetal and vinyl alcohol/vinylpyrollidone.

7. A polymeric composition according to any one of the claims 1-6 in cured form.

10. A substrate coated with a polymer composition in accordance with claim 1.

11. A polymer composition according to claim 1 which has a coefficient of friction of 0.10 or less when wetted with water or an aqueous fluid.

12. An article coated with a polymer composition according to claim 1 having a coefficient of friction of 0.10 or less when wetted with water or an aqueous fluid.

13. An article according to claim 12 wherein the polymer composition is in cured form.

8. A method of treating a substrate to render it substantially fog-resistant comprising applying to the substrate a composition which consists essentially of (a) a water-soluble polyvinyl alcohol polymer and a water soluble polyvinyl pyrollidone polymer,

the polyvinyl alcohol polymer having a weight average molecular weight of about 20,000 to about 200,000 and the polyvinyl pyrollidone polymer having a weight average molecular weight of about 30,000 to about 400,000, and

(b) a crosslinking agent selected from the group consisting of a melamine, a mineral acid and a strong organic acid,

said crosslinking agent being present in an amount up to about 50% by weight based on the weight of the non-volatile components contained in the composition.

9. A method in accordance with claim 8 wherein the polyvinyl pyrollidone compound is selected from the group consisting of vinylpyrollidone/vinyl acetate, vinylpyrollidone/vinylcaprolactam, vinylpyrollidone/N,N-dimethylacrylamide and vinyl acetate/vinyl alcohol/vinyl acetal terpolymers.