Remote spectroscopy for raman and brillouin scattering

• US 5,262,644 A
• Filed: 12/16/1992
• Issued: 11/16/1993
• Est. Priority Date: 06/29/1990
• Status: Expired due to Term

• Current Assignee: Southwest Research Institute
• Original Assignee: Southwest Research Institute
• Inventors: Maguire, John F.
• Primary Examiner(s): FIELDS, CAROLYN
• Application Number:
  US07/993,446
• Time in Patent Office: 335 Days
• Field of Search: 356/301, 356/73, 356/43, 356/44, 356/337, 356/338, 356/339, 356/346, 250/338.1, 250/339
• US Class Current: 250/339.08
• CPC Class Codes: G01N 2021/638 Brillouin effect, e.g. stimulated Brillouin effect
• CPC Class Codes: G01N 2021/651 Cuvettes therefore
• CPC Class Codes: G01N 2021/656 Raman microprobe
• CPC Class Codes: G01N 21/65 Raman scattering

Abstract

An apparatus and method for performing Raman and Brillouin spectroscopy remotely. A near-infrared laser is used to irradiate a sample of material to be analyzed. Optical fibers transmit incident radiation from a near-infrared radiation source to the sample, and transmit Raman and Brillouin scattered radiation from the sample to the detecting equipment. The incident radiation is carefully determined so as to avoid fluorescence and to limit optic fiber losses. The invention provides useful information with the use of an interferometer.

Claims

1. An apparatus for remotely performing a spectroscopic analysis of Brillouin and Raman scattered radiation from a sample of material, comprising:

a near-infrared laser for providing incident radiation, wherein the wavelength of said incident radiation is within a range of wavelengths between a fluorescence limit and a fiber optics loss limit, such that said incident radiation has a wavelength sufficiently long to minimize fluorescence from a material to be analyzed and sufficiently short to minimize optical fiber losses;

an input optical fiber for transmitting said incident radiation to a sample of material to be analyzed, wherein said input fiber is made from a low loss optical fiber;

at least one collecting optical fiber for receiving Brillouin and Raman scattered radiation from said sample, wherein said at least one collecting fiber is made from low loss optical fiber, wherein said input optical fiber and said at least one collecting optical fiber are placed at a predetermined angle with respect to each other;

an interferometer for receiving said scattered radiation from said at least one collecting fiber and for generating a fringe pattern representative of said scattered radiation over time;

a solid state infrared detector for detecting said fringe pattern and for producing a time-domain electrical signal representing intensities of said fringe pattern; and

a processing means for transforming said time-domain electrical signal into a frequency-domain electrical signal representing intensities of said scattered radiation at different wavenumbers.

2. The apparatus of claim 1, wherein the wavelength emitted by said near-infrared laser is in the range of 1.0 micrometers to 2.0 micrometers.

3. The apparatus of claim 1, wherein said input optical fiber and said at least one collecting optical fiber are made from a heavy metal fluoride.

4. The apparatus of claim 1, wherein fibers are made from a fluoride material.

5. The apparatus of claim 1, wherein said angle is fixed by means of a probe head that secures the unclad ends of said optical fibers.

6. The apparatus of claim 1, wherein said interferometer is a Fabry-Perot interferometer.

7. The apparatus of claim 1, wherein said laser is a yttrium aluminum garnet laser.

8. The apparatus of claim 1, wherein said laser is a kryton ion laser.

10. The method of claim 8, wherein said transforming step is performed with a computer programmed to perform a Fourier transform of said time-domain electrical signal.

9. A Brillouin and Raman scattering method of analyzing materials, comprising the steps of:

radiating a sample of the material to be analyzed, using near infrared radiation transmitted through a low loss fiber optic input tube;

placing a receiving end of a low loss fiber optic output tube at a fixed and predetermined angle to said fiber optic input tube;

collecting Brillouin and Raman scattered radiation scattered by said material in response to said radiating step, using said low loss fiber optic output tube;

using an interferometer to generate a fringe pattern of said scattered radiation as a function of time;

using a detector to generate a time-domain electrical signal representative of said fringe pattern; and

transforming said time-domain electrical signal into a frequency-domain electrical signal representative of intensities of said scattered radiation at different wavenumbers.

11. The method of claim 9, further comprising the step of determining the width of the Rayleigh line at half height.

12. The method of claim 9, further comprising the step of determining the width of a Brillouin peak at half height.

13. The method of claim 9, further comprising the step of comparing the area of the Rayleigh peak to the area of a Brillouin peak.

14. The method of claim 9, further comprising the step of determining the distance between the zero shift from the wavelength of the incident radiation to the wavenumber corresponding to the maximum value of Brillouin peak.

15. The method of claim 9, wherein said material is part of a rotating device, and further comprising the step of placing stationary ends of said optic fiber input tube and said fiber optic output tube in proximity to ends of corresponding nonstationary fibers such that as the device rotates, the ends communicate with each other.

16. The method of claim 9, and further comprising the step of determining the temperature of said material by obtaining a spectrum of the scattered wavelengths and comparing the intensity of anti-Stokes and Stokes lines on a spectrum obtained by said detector.