Filler for degradable plastics and process for producing the same

• US 5,264,030 A
• Filed: 04/06/1992
• Issued: 11/23/1993
• Est. Priority Date: 04/16/1991
• Status: Expired due to Fees

• Current Assignee: Nittetsu Mining Company Limited
• Original Assignee: Nittetsu Mining Company Limited
• Inventors: Asaba, Seiji, Umebayashi, Masaharu, Ugomori, Atsushi, Tanabe, Katsuyuki
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): Hertzog, Scott L.
• Application Number:
  US07/863,931
• Time in Patent Office: 596 Days
• Field of Search: 106/463, 106/464, 106/465, 106/471, 106/467, 106/413, 106/416, 106/417, 106/437, 106/447, 106/456, 106/460, 106/469, 106/400, 106/401, 524/297
• US Class Current: 106/401
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C01P 2006/12 Surface area
• CPC Class Codes: C01P 2006/32 Thermal properties
• CPC Class Codes: C01P 2006/60 Optical properties, e.g. expressed in CIELAB-values
• CPC Class Codes: C01P 2006/90 Other properties not specified above
• CPC Class Codes: C08K 5/0033 Additives activating the degradation of the macromolecular compound
• CPC Class Codes: C08K 9/04 Ingredients treated with organic substances treated with macromolecular compounds C08K9/08
• CPC Class Codes: C08K 9/08 Ingredients agglomerated by treatment with a binding agent
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 27/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C09B 67/0004 Coated particulate pigments or dyes
• CPC Class Codes: C09C 1/021 Calcium carbonates
• CPC Class Codes: C09C 1/24 Oxides of iron
• CPC Class Codes: C09C 1/28 Compounds of silicon C09C1/0009, C09C1/0015, C09C1/0078 take precedence
• CPC Class Codes: C09C 1/3676 Treatment with macro-molecular organic compounds
• CPC Class Codes: C09C 1/405 containing combined silica, e.g. mica
• CPC Class Codes: C09C 1/42 Clays
• CPC Class Codes: C09C 3/08 Treatment with low-molecular-weight non-polymer organic compounds C09C3/006, C09C3/048 take precedence
• CPC Class Codes: C09C 3/10 Treatment with macromolecular organic compounds C09C3/006 takes precedence

Abstract

In order to provide a filler for degradable plastics which can simplify the stages for producing a degradable plastic, give effective plastic-degradability, and stabilize the quality of the plastic article, the filler is used as a carrier substance and effective biodegradable and/or photodegradable components are adsorbed on the surfaces of the filler particles via a surface treating agent.

Claims

1. A filler for degradable plastics comprising a filler used for plastics as a carrier substance, and biodegradable-and/or photodegradable-effective component(s) having been adsorbed on the surfaces of said filler particles via a surface treating agent.

2. The filler as claimed in claim 1, wherein said filler used for plastics comprises an inorganic substance represented by calcium carbonate, clay, talc, mica, titanium oxide, and iron oxide.

3. The filter as claimed in claim 1, wherein said filler used for plastics comprises an organic substance represented by phthalocyanine green.

4. The filler as claimed in claim 1, wherein said filler used for plastics consists essentially of a carbonate represented by calcium carbonate and basic magnesium carbonate and/or a hydroxide represented by aluminum hydroxide and magnesium hydroxide.

5. The filler as claimed in claim 1, wherein said biodegradable-effective component consists essentially of starch.

6. The filler as claimed in claim 5, wherein the biodegradable-effective component contains in an amount of 10-200% by weight based on the filler.

7. The filler as claimed in claim 1, wherein said photodegradable-effective component is one or more components selected from among ketone, quinone, transition metal salts, oxidation accelerators, and photosensitizers.

8. The filler as claimed in claim 1, which contains both the biodegradable and photodegradable effective components.

9. The filler as claimed in claim 1, wherein said surface treating agent is a surfactant.

10. A process for producing a filler for degradable plastics which comprises adding biodegradable-and/or photodegradable-effective component(s) to a filler before or during the surface treatment of the filler with a surface treating agent thereby adsorbing the component(s) on the surfaces of filler particles.

11. A process for producing a filler for degradable plastics characterized in that the biodegradable-and/or photodegradable-effective components are mixed with and dispersed in a surface treating agent, thereby surface-treating the filler with said surface treating agent and said biodegradable- and/or photodegradable-effective components.

12. A process for producing a filler for degradable plastics characterized in that biodegradable-and/or photodegradable-effective component(s) are added to a filler and adsorbed on the surfaces of the filler particles after the filler is surface-treated.

13. A process for producing a filler for degradable plastics characterized in that an biodegradable-effective component is mixed with and dispersed in a filler, followed by surface-treating.

14. A process for producing a filler for degradable plastics characterized in that an biodegradable-effective component is mixed with and dispersed in a filler, followed by adding a surface treating agent and an photodegradable-effective component.

15. A plasticizer for degradable plastics with biodegradable- and/or photodegradable-effective components mixed and dispersed therein.

16. A process for producing a plasticizer for degradable plastics comprising mixing with and dispersing in a plasticizer a biodegradable- and/or photodegradable-effective component.