Apparatus for the gas-phase polymerization of olefins in a fluidized-bed reactor

• US 5,266,276 A
• Filed: 03/09/1993
• Issued: 11/30/1993
• Est. Priority Date: 07/15/1988
• Status: Expired due to Term

• Current Assignee: Ineos Commercial Services UK Limited (Ineos Grangemouth Plc)
• Original Assignee: BP Chemicals Ltd. (BP PLC)
• Inventors: Dumain, Andre, Chinh, Jean-Claude
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): WEBER, THOMAS
• Application Number:
  US08/028,626
• Time in Patent Office: 266 Days
• Field of Search: 422/146, 422/235, 422/139, 422/132, 526/901
• US Class Current: 422/132
• CPC Class Codes: B01J 8/1827 the fluidising gas being a reactant
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 2/34 Polymerisation in gaseous state
• CPC Class Codes: Y10S 526/901 Monomer polymerized in vapor state in presence of transition metal containing catalyst

Abstract

The present invention relates to a process and apparatus for the gas-phase polymerization of olefins in a fluidized-bed reactor maintained at a temperature T1. A gaseous reaction mixture comprising the olefins to be polymerized passes through the reactor and is recycled to the reactor by means of a recycling line comprising successively a first heat transfer means, a compressor and a second heat transfer means. The present invention consists in introducing a readily volatile liquid hydrocarbon into the inlet of the first heat transfer means or into the recycling line, upstream and in the vicinity of the first heat transfer means. The first heat transfer means cools the gaseous reaction mixture to a temperature T2, below T1, while volatilizing the readily volatile hydrocarbon and without condensing a constituent of the gaseous reaction mixture. The second heat transfer means cools the gaseous reaction mixture to a temperature T3, below T2, for maintaining the fluidized-bed at the desired temperature T1.

Claims

1. Apparatus for the gas phase polymerisation of olefin(s) comprising a fluidised bed reactor with a fluidisation grid located at the lower part of said reactor and a gas recycling line external to said reactor connecting the top to the bottom part of said reactor below said fluidisation grid for returning into said bottom part of the reactor the gaseous reaction mixture comprising the olefin(s) to be polymerised leaving said top of the reactor, said gas recycling line being provided with (i) a gas compressor, (ii) a first heat transfer means arranged between said top of the reactor and the suction side of said gas compressor, (iii) a second heat transfer means arranged between the delivery side of said gas compressor and said bottom part of the reactor, and (iv) the inlet of a means for introducing a readily volatile liquid hydrocarbon arranged in the entering of said first heat transfer means or at a point between said top of the reactor and said first heat transfer means in the vicinity of the entering of said first heat transfer means.

2. Apparatus according to claim 1, wherein the inlet of the means for introducing a readily volatile liquid hydrocarbon is located at a distance from the entering of the first heat transfer means such that the readily volatile liquid hydrocarbon is partially in the liquid state in said entering.

3. Apparatus according to claim 1, wherein the inlet of the means for introducing a readily volatile liquid hydrocarbon is located at a distance from the entering of the first heat transfer means such that the means residence time of the readily liquid hydrocarbon introduced into the gas recycling line is leass than 1 second to reach said entering.

4. Apparatus according to claim 1, wherein the inlet of the means for introducing a readily volatile liquid hydrocarbon is located at a distance from the entering of the first head transfer means which is of 0 to 20 meters.

5. Apparatus according to claim 4, wherein the distance from the entering of the first heat transfer means is of 0 to 10 meters.

6. Apparatus according to claim 1, wherein the fluidised bed reactor is surmounted by a tranquillisation chamber.

7. Apparatus according to claim 1, wherein the means for introducing a readily volatile liquid hydrocarbon opens directly into the entering of the first heat transfer means or into the gas recycling line at a point between the top of the fluidized bed reactor and the first heat transfer means so that the readily volatile liquid hydrocarbon is partially in the liquid state in said entering.