Aqueous dispersions containing a synergistic dispersant combination

• US 5,266,622 A
• Filed: 11/02/1992
• Issued: 11/30/1993
• Est. Priority Date: 05/05/1988
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Mazanek, Jan, Link, Gunter, von Gizycki, Ulrich
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): SMITH, JEFFREY
• Application Number:
  US07/970,524
• Time in Patent Office: 393 Days
• Field of Search: 524/136, 524/137, 524/139, 524/599, 524/600, 524/131, 525/193
• US Class Current: 524/131
• CPC Class Codes: C09B 67/0085 Non common dispersing agents
• CPC Class Codes: C09D 17/001 in aqueous medium C09D17/003, C09D17/004 take precedence
• CPC Class Codes: C09K 23/017 Mixtures of compounds

Abstract

Aqueous dispersions of fillers and/or pigments contain a dispersant combination of the following composition:

A) 40 to 95 by weight of a water-soluble polymer,

B) 0 to 60 by weight of a non-ionic alkylene oxide adduct having an average molecular weight of 200 to 100,000,

C) 0 to 60% by weight of compounds of the formulae (I), (II) and/or (III) ##STR1## in which R₁ represents an optionally substituted aliphatic, aromatic or araliphatic radical having 1 to 50 C atoms,

z in each case independently of one another represents an integer from 1 to 10 and

x represents hydrogen, a monovalent metal ion or an optionally substituted ammonium ion and

D) 0 to 60% by weight of a compound of the formula (IV) ##STR2## in which Q represents hydrogen, ##STR3## in which Y in each case independently of one another represents hydrogen, a monovalent metal ion or an optionally substituted ammonium ion,

R₂ in each case independently of one another represents hydrogen, an optionally substituted alkyl radical having 1 to 12 C atoms or a radical of the type --CH₂ --COOR₃ or --CH₂ CH₂ COOR₃ and

R₃ in each case independently of one another represents hydrogen, Y or an optionally substituted alkyl radical having 1 to 25 C atoms,

where the sum A) +B) +C) +D) gives 100% by weight and at least one of the components B), C) and D) is different from zero.

Claims

1. Aqueous dispersions of fillers and/or pigments, which contain a synergistic dispersant combination of the following compositions:

A) 50 to 80% by weight of a water-soluble polymer selected from the group consisting of cellulose derivatives, sulphonated polyesters and hydrolysates of polyacrylonitrile, including carboxymethylcellulose, homopolymers and copolymers of methacrylic and/or acrylic acid and their salts with molecular weights in the range from 800 to 40,000,

B) 10 to 40% by weight of a non-ionic alkylene oxide adduct of the formula ##STR11## in which R₄ denotes an optionally stubstituted aliphatic, aromatic or araliphatic radical having 1 to 40 carbon atoms,

R₅ denotes hydrogen, phenyl or alkyl radical having 1 to 12 C atoms and

n denotes a number from 2 to 300.

n preferably denotes 4 to 100, and

D) 10 to 30% by weight of a compound of the formula ##STR12## in which R⁷ is hydrogen, a monovalent metal ion or an optionally substituted ammonium ion and

Y is hydrogen, a monovalent metal ion or an optionally substituted ammonium ion,

where the sum A) +B) +D) gives 100% by weight.

2. Dispersions of claim 1, in which the dispersion contains the dispersant combination in an amount from 0.02 to 10% by weight, relative to the solids present in the dispersion.

3. Dispersions of claim 1, which contain calcium carbonate, silicates, silica, glass beads, aluminium titanate, silicon carbide, silicon nitride, other powders for ceramic production, zinc oxide, titanium dioxide, iron oxides, organic pigments, metal oxides, metal powders, metal fibres, alumina, Al(OH)₃, carbon black, graphite, coal, ground minerals, monybdenum sulphide and/or calcium sulphate.

4. Dispersions of claim 1, which contain 5 to 95% by weight of solids.

5. Dispersions of claim 1, which contain further customary additives.

6. Dispersions of claim 1, in which the dispersion contains a dispersant combination, wherein the component (A) is sodium polyacrylate.

7. Dispersions of claim 1, in which the dispersion contains a dispersant combination, wherein the component (B) is the reaction product of nonylphenol with -ethylenoxide groups.

8. Dispersions of claim 1, in which the dispersion contains a dispersant combination, wherein the component (D) is the tetra-sodium salt of 2-phosphonobutan-1,2,4-tricarboxylic acid of the formula ##STR13##