Nitrogen adsorption with highly Li exchanged X-zeolites with low Si/Al ratio

• US 5,268,023 A
• Filed: 10/05/1992
• Issued: 12/07/1993
• Est. Priority Date: 10/05/1992
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Kirner, John F.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US07/957,532
• Time in Patent Office: 428 Days
• Field of Search: 55/25, 55/26, 55/58, 55/62, 55/68, 55/75, 55/389
• US Class Current: 95/103
• CPC Class Codes: B01D 2253/1085 characterized by a silicon-aluminium ratio
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2256/12 Oxygen
• CPC Class Codes: B01D 2257/102 Nitrogen
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/0476 Vacuum pressure swing adsorption
• CPC Class Codes: B01J 20/186 Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity

Abstract

Low silica X (LSX) zeolites having a framework Si/Al ratio equal to 1.0 with lithium exchange levels greater than a threshold level of 70% exhibit unexpectedly higher capacity for nitrogen adsorption compared to LSX-zeolite with lower lithium exchange levels. These materials provide high performance adsorbents for PSA air separation processes at a lower cost for the adsorbent because of the lower threshold lithium exchange levels compared to highly exchanged lithium X-zeolite known in the prior art.

Claims

1. A process for adsorbing nitrogen from a gas containing nitrogen which comprises contacting the gas with an adsorbent which is selective for the adsorption of nitrogen, comprising a crystalline X-zeolite having a zeolitic Si/Al ratio less than 1.25 and a lithium ion exchange level of the exchangeable ion content greater than 70% and less than 88%.

2. The process of claim 1 wherein said zeolite is ion exchanged with lithium to a level greater than (72×

(Si/Al ratio)-2)%.

3. The process of claim 1 wherein said zeolite is ion exchanged with lithium to a level greater than 77%, but less than 88%.

4. The process of claim 3 wherein said zeolite is ion exchanged with lithium to a level of approximately 85%.

5. The process of claim 1 wherein said Si/Al ratio is less than 1.1

6. The process of claim 5 wherein said Si/Al ratio is approximately 1.

7. The process of claim 1 wherein said gas contains nitrogen and oxygen.

8. The process of claim 7 wherein said gas is air.

9. The process of claim 1 wherein an oxygen and nitrogen containing gas contacts a zone of said adsorbent, the nitrogen is selectively adsorbed and the oxygen passes through said zone and is recovered as an oxygen enriched product.

10. The process of claim 9 wherein said oxygen enriched product has a purity of at least approximately 90% oxygen.

11. The process of claim 9 wherein the adsorption is conducted at an average bed temperature in the range of approximately 55°

to 135°

F.

12. The process of claim 9 wherein said zone is operated through a series of steps comprising:

adsorption, during which said gas contacts said adsorbent, nitrogen is selectively adsorbed and oxygen passes through said zone as product;

depressurization, during which said gas contact is discontinued and said zone is reduced in pressure to desorb the nitrogen; and

repressurization with oxygen product to adsorption pressure.

13. The process of claim 1 wherein the adsorption pressure is in the range of approximately 35 to 65 psia.

14. The process of claim 1 wherein the depressurization is conducted down to a level in the range of approximately 14.7 to 16.7 psia.

15. The process of claim 1 wherein said zone is operated through a series of steps comprising:

adsorption, during which said gas contacts said adsorbent, nitrogen is selectively adsorbed and oxygen passes through said zone as product;

depressurization, during which said gas contact is discontinued and said zone is reduced in pressure to desorb the nitrogen;

evacuation to further desorb the nitrogen to below ambient pressure; and

repressurization with oxygen product to the adsorption pressure.

16. The process of claim 15 wherein the adsorption pressure is in the range of approximately 900 to 1600 torr.

17. The process of claim 15 wherein the evacuation is conducted down to a level in the range of approximately 80 to 400 torr.