Self reinforced thermoplastic composite laminate

• US 5,268,225 A
• Filed: 12/02/1991
• Issued: 12/07/1993
• Est. Priority Date: 08/16/1990
• Status: Expired due to Term

• Current Assignee: University of Akron
• Original Assignee: University of Akron
• Inventors: Isayev, Avraam
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): WEISBERGER, RICHARD C
• Application Number:
  US07/801,429
• Time in Patent Office: 736 Days
• Field of Search: 525/444, 525/425, 525/436, 428/224, 428/245, 428/294, 264/108
• US Class Current: 428/300.7
• CPC Class Codes: B32B 2307/306 Resistant to heat
• CPC Class Codes: B32B 2307/51 Elastic
• CPC Class Codes: B32B 2307/54 Yield strength; Tensile strength
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C09K 19/00 Liquid crystal materials
• CPC Class Codes: Y10T 428/24995 Two or more layers

Abstract

Composite laminates are prepared from thin sheets of thermotropic liquid crystal polymer blends. A preferred blend contains 2 thermotropic liquid crystal polymers, i.e., a first liquid crystal polymer in LCP-1, and a second liquid crystal polymer (LCP-2), the second liquid crystal polymer having a higher melting point than the first. The second liquid crystal polymer is molecularly oriented and is preferably at least partially in the form of microscopic fibers in a matrix of the first liquid crystal polymer. The two liquid crystal polymers are phase separated in the solid phase and have overlapping melt processing temperatures.

Claims

1. A self reinforced composite laminate formed from a plurality of layers of a blend of thermotropic liquid crystal polymers having overlapping processing temperature ranges, said liquid crystal polymers including a first liquid crystal polymer and a second liquid crystal polymer which are incompatible in the solid state, each layer comprising fibers of said second liquid crystal polymer in a matrix of said first liquid crystal polymer, wherein the second liquid crystal polymer has a higher minimum processing temperature than the first liquid crystal polymer and wherein the said blend contains from about 2% to about 98% by weight each of said first and second liquid crystal polymers, based on the total liquid crystal polymer weight in said blend.

2. A composite laminate according to claim 1 wherein said first liquid crystal polymer and said second liquid crystal polymer each have melting point, the melting points of said second liquid crystal polymer being higher than that of the first liquid crystal polymer.

3. A composite laminate according to claim 1 wherein at least said first liquid crystal polymer is a wholly aromatic co-polyester.

4. A composite laminate according to claim 1 wherein said blend contains from about 20% to about 80% each of said first and second liquid crystal polymers, based on total liquid crystal polymer weight.

5. A composite laminate according to claim 1 wherein said blend consists essentially of said first liquid crystal polymer and said second liquid crystal polymer.

6. A composite according to claim 1, said laminate being formed from individual sheets of said blend at a lamination temperature which is equal to or above the minimum processing temperature of the first liquid crystal polymer but below that of the second liquid crystal polymer.

7. A shaped article formed from a laminate of claim 1.

8. A composite laminate according to claim 1 in which the direction of fiber orientation is different in different layers, whereby said laminate is essentially isotropic.

9. A composite laminate according to claim 1 in which the direction of fiber orientation in all layers is essentially the same, whereby said laminate is anisotropic.