Process for removal of inert gases from liquid chlorine and system therefor

• US 5,269,834 A
• Filed: 10/13/1992
• Issued: 12/14/1993
• Est. Priority Date: 10/13/1992
• Status: Expired due to Fees

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Loftis, Harry J., Steely, Robert K., Dotson, Ronald L.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US07/960,075
• Time in Patent Office: 427 Days
• Field of Search: 55/36, 55/47, 55/58, 55/75, 55/189, 55/208, 55/274, 55/389, 210/662, 210/673, 210/681, 210/275, 210/283, 423/500, 423/501, 423/503
• US Class Current: 95/104
• CPC Class Codes: B01D 19/0031 by filtration
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/308 Pore size
• CPC Class Codes: B01D 2257/2025 Chlorine
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0407 Constructional details of adsorbing systems

Abstract

A method and system for treating liquid chlorine to remove inert gases therefrom. Liquid chlorine is treated by passing it through a molecular sieve having a molecular pore diameter greater than the molecular diameter of the inert gases and smaller than the molecular diameter of chlorine so that the inert gases are adsorbed by the sieve while the liquid chlorine passes therethrough. The sieve may be regenerated by heating the sieve and evacuating by vacuum, followed by a purging with a gas and then a further vacuum evacuation.

Claims

1. A process for treating liquid chlorine to remove inert gases therefrom comprising:

providing a column containing a molecular sieve which has a molecular pore diameter greater than the molecular diameter of the inert gases to be removed, and smaller than the molecular diameter of the liquid chlorine, and;

passing the liquid chlorine through the sieve whereby at least some of the inert gases is adsorbed by the molecular sieve while the liquid chlorine passes therethrough.

2. The method of claim 1 wherein said molecular sieve is periodically regenerated by heating the molecular sieve and vacuum evacuating the column in which the sieve is contained and purging the molecular sieve with a gas to flush out impurities.

3. The method of claim 1 wherein said molecular sieve is periodically regenerated by heating the molecular sieve and vacuum-evacuating the container in which the sieve is contained and thereafter passing gaseous chlorine at an elevated temperature through the molecular sieve, and then again vacuum-evacuating the container.

4. The method of claim 3 wherein the gaseous chlorine for regeneration is at temperature of from about 90°

to about 100°

C.

5. A system for treating liquid chlorine to remove inert gases therefrom comprising:

a column containing a molecular sieve,

said molecular sieve having a molecular pore diameter greater than the molecular diameter of the inert gases to be removed and smaller than the molecular diameter of the liquid chlorine;

a source of liquid chlorine under pressure; and

means for passing said chlorine from said source to said column to permit said chlorine to pass through the molecular sieve to remove at least a portion of the inert gases.

6. The system of claim 5 further including means for controlling the rate of flow of said chlorine through said system.

7. The system of claim 6 further including a flow meter for determining the flow of chlorine to said molecular sieve column.

8. The system of claim 5 further including means for regenerating said molecular sieve.

9. The system of claim 8 wherein said means for regenerating includes a vacuum pump attached to one end of the column for applying a vacuum to said column, and heating means for heating the molecular sieve, and means for purging the system with a gas to flush out impurities.

10. The system of claim 9 wherein said means for regenerating further includes a source of gaseous chlorine, and means for passing said gaseous chlorine through said molecular sieve column after said molecular sieve column has been vacuum-evacuated.

11. The system of claim 10 wherein said system includes a means for heating said gaseous chlorine to an elevated temperature.

12. The system of claim 5 further including means for purging said system with nitrogen, said purging means including a source of nitrogen, means for shutting off the flow of chlorine into said system, and means for feeding nitrogen to said system and therefrom.

13. The system of claim 5 further including means for bleeding a portion of said liquid chlorine after it has been purified for the purpose of taking a sample.

14. The system of claim 5 wherein said column includes an intermediate section and upper and lower sections attached thereto at opposite ends thereof, and means for retaining said molecular sieve within said intermediate portion.

15. The system of claim 14 wherein said means for retaining said molecular sieve includes a foraminous disk member having a pliable cloth extending thereover on the side of said disk facing the interior of the intermediate portion.

16. The system of claim 14 wherein said upper and lower sections have a flange at one end thereof and said intermediate section has a flange at each end thereon connected to a respective flange on said upper and lower section, a recess in each end of said intermediate section, and said means for retaining said molecular sieve being positioned in each of said recesses.