Calcium aluminate composition and process for making same

• US 5,269,845 A
• Filed: 02/27/1992
• Issued: 12/14/1993
• Est. Priority Date: 02/27/1992
• Status: Expired due to Fees

• Current Assignee: Cer-Con, Inc.
• Original Assignee: Cer-Con, Inc.
• Inventors: Grunau, Klaus F., Hamilton, William W.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US07/842,883
• Time in Patent Office: 656 Days
• Field of Search: 106/692, 106/695, 106/696, 106/38.27, 106/38.35, 264/309, 427/421, 427/427
• US Class Current: 106/692
• CPC Class Codes: C04B 14/043 Alkaline-earth metal silicates, e.g. wollastonite
• CPC Class Codes: C04B 14/062 Microsilica, e.g. colloïdal silica preparing microsilica slurries or suspensions C04B18/148
• CPC Class Codes: C04B 14/303 Alumina
• CPC Class Codes: C04B 14/306 Zirconium oxide zircon C04B14/046
• CPC Class Codes: C04B 14/324 Silicon carbide
• CPC Class Codes: C04B 20/008 Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder colloidal silica C04B14/062 ; silica fume C04B18/146
• CPC Class Codes: C04B 2103/40 Surface-active agents, dispersants
• CPC Class Codes: C04B 2103/408 Dispersants
• CPC Class Codes: C04B 2103/445 Gelling agents
• CPC Class Codes: C04B 2111/00155 Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
• CPC Class Codes: C04B 2111/00939 for the fabrication of moulds or cores
• CPC Class Codes: C04B 22/062 of the alkali or alkaline-earth metals
• CPC Class Codes: C04B 24/003 Phosphorus-containing compounds
• CPC Class Codes: C04B 24/085 Higher fatty acids
• CPC Class Codes: C04B 24/122 Hydroxy amines
• CPC Class Codes: C04B 24/18 Lignin sulfonic acid or derivatives thereof, e.g. sulfite lye
• CPC Class Codes: C04B 24/226 Sulfonated naphtalene-formaldehyde condensation products
• CPC Class Codes: C04B 24/26 obtained by reactions only involving carbon-to-carbon unsaturated bonds C04B24/243 takes precedence
• CPC Class Codes: C04B 24/2641 Polyacrylates; Polymethacrylates
• CPC Class Codes: C04B 28/06 Aluminous cements monolithic refractories or refractory mortars C04B35/66
• CPC Class Codes: C04B 38/10 : by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: C04B 40/0028 : Aspects relating to the mixing step of the mortar preparation

Abstract

A novel cementitious composition based on calcium aluminate and suitable for use in molds is provided. The composition comprises a calcium aluminate powder base, at least one particulate inorganic filler, a latex binding agent chemically compatible with said calcium aluminate powder, at least one dispersing agent, an initiator which initiates the binding of said calcium aluminate powder to said inorganic filler at pH values between 6.5 and 8.0, at least one surface hardness agent comprising an alkyl-aryl sulfonate compound or salt thereof or an aryl sulfonate compound or salt thereof, a polymer salt surface gloss agent, and at least one metal or non-metal oxide wetting agent. A process for producing the composition and a process of applying the composition to form it into a desired shape are also provided.

Claims

1. A cementitious composition particularly useful in the construction of molds, said composition comprising:

(a) 30-40 percent by weight of a calcium aluminate powder base;

(b) 30-40 percent by weight of at least one particulate inorganic filler;

(c) 25-35 percent by weight of a latex binding agent chemically compatible with said calcium aluminate powder;

(d) 0.0005-0.005 percent by weight of at least one dispersing agent;

(e) 0.0005-0.005 percent by weight of an initiator which initiates the binding of said calcium aluminate powder to said inorganic filler at pH values between 6.5 and 8.0;

(f) 0.05-0.5 percent by weight of at least one surface hardness agent comprising an alkyl-aryl sulfonate compound or salt thereof or an aryl sulfonate compound or salt thereof;

(g) 0.05-0.5 percent by weight of a polymer salt surface gloss agent; and

(h) 1.14 2 percent by weight of at least one metal or non-metal oxide wetting agent.

2. A composition according to claim 1 wherein said particulate inorganic filler is selected from the group consisting of amorphous silica, silicon carbide, calcium metasilicate, and aluminum oxide.

3. A composition according to claim 1 wherein said latex binding agent comprises an emulsion of particulate polymer having a solids content of between about 45 and 55 percent.

4. A composition according to claim 1 wherein said initiator comprises lithium hydroxide.

5. A composition according to claim 1 wherein said alkyl-aryl sulfonate compound or salt thereof or aryl sulfonate compound or salt thereof surface hardness agent comprises a mixture of sulfonated naphthalene condensate and calcium lignosulfonate.

6. A composition according to claim 1 wherein said polymer salt surface gloss agent comprises sodium polyacrylate.

7. A composition according to claim 1 wherein said metal or non-metal oxide wetting agent is selected from the group consisting of fumed silica, and colloidal zirconia.

8. A composition according to claim 7 wherein said metal or non-metal oxide is a combination of fumed silica, and colloidal zirconia.

9. A composition according to claim 1 which further comprises an air entraining agent.

10. A composition according to claim 9 wherein said air entraining agent comprises a sodium aryl-fatty acid salt.

11. A composition according to claim 1 which further comprises a gelling agent.

12. A composition according to claim 11 wherein said gelling agent comprises triethanolamine.

13. A composition according to claim 1 which further comprises a foaming agent.

14. A composition according to claim 13 wherein said foaming agent comprises tri-n-butylphosphate.

15. A composition according to claim 2 wherein said inorganic filler comprises a mixture of aluminum oxide, calcium metasilicate, and silicon carbide.

19. A process of making an article from the composition of claim 1 comprising spraying the composition while avoiding the entraining of air into the composition onto an object configured to form the composition into a desired shape.

20. A process according to claim 19 wherein the object for forming the composition comprises a male model, and wherein the desired shape is a female mold conforming to the male model.

21. An article formed by the process of claim 19.

22. An article according to claim 21, wherein the article formed is a female mold.

16. A process for producing a cementitious composition comprising the steps of:

(a) soaking 1-2 percent by weight of at least one metal or non-metal oxide wetting agent in water, thereby forming a thick gel;

(b) mixing the gel with 25-30 percent by weight of a latex binding agent chemically compatible with calcium aluminate powder, 0.0005-0.005 percent by weight of at least one dispersing agent, 0.0005-0.005 percent of an initiator which initiates the binding of said calcium aluminate powder to said inorganic filler at pH values between 6.5 and 8.0, 0.05-0.5 percent by weight of at least one surface hardness agent comprising an alkyl-aryl sulfonate compound or salt thereof or an aryl sulfonate compound or salt thereof, and 0.05-0.5 percent by weight of a polymer salt surface gloss agent to form a slurry; and

(c) combining the slurry with 30-40 percent by weight of a calcium aluminate powder base and 30-40 percent by weight of at least one particulate inorganic filler, thereby forming a cementitious composition.

17. A process according to claim 16, wherein the metal or non-metal oxide wetting agent is at least one selected from the group consisting of fumed silica, and colloidal zirconia.

18. A process according to claim 16, wherein the metal or non-metal oxide wetting agent is a mixture of fumed silica, and colloidal zirconia.