Process for reducing nitrogen oxides from exhaust gas

• US 5,270,024 A
• Filed: 08/31/1990
• Issued: 12/14/1993
• Est. Priority Date: 08/31/1989
• Status: Expired due to Term

• Current Assignee: Tosoh Corporation, Kabushiki Kaisha Toyota Chuo Kenkyusho (Toyota Motor Corporation), Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Tosoh Corporation, Kabushiki Kaisha Toyota Chuo Kenkyusho (Toyota Motor Corporation), Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: Suzuki, Tadashi, Igawa, Kazushige, Kamiyama, Katsumi, Takeshima, Shinichi, Nakano, Masao, Yokota, Koji, Fukui, Masayuki, Matsumoto, Shinichi, Ishibashi, Kazunobu, Kondoh, Shiroh, Kasahara, Senshi
• Primary Examiner(s): 1
• Assistant Examiner(s): DEES, CARL
• Application Number:
  US07/575,621
• Time in Patent Office: 1,201 Days
• Field of Search: 502/77, 502/78, 502/79, 502/73, 423/213.2, 423/239, 423/247, 423/213.5
• US Class Current: 423/213.2
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 29/072 Iron group metals or copper
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

A catalyst for reducing nitrogen oxides from an exhaust gas containing the same in an oxygen rich atmosphere comprising (i) a zeolite having a molar ratio of SiO₂ /Al₂ O₃ of at least 10, (ii) copper, and (iii) a rare earth ion, an alkaline earth metal and/or a valence variable metal.

Claims

1. A method of purifying an exhaust gas containing an excess amount of oxygen, which comprises bringing a catalyst into contact with the exhaust gas to remove nitrogen oxides, carbon monoxide and hydrocarbons from the exhaust gas, the catalyst comprising:

(i) a zeolite having a molar ratio of SiO₂ /Al₂ O₃ of at least 10; and

(ii) at least one copper ion and at least one kind of rare earth ion loaded thereon.

2. The method as claimed in claim 1, wherein said rare earth ion is selected from the group consisting of La, Ce, Pr, Nd, Pm, and Sm.

3. The method as claimed in claim 1, wherein the amount of the copper ion is 0.01 to 1 in terms of a Cu/Al atomic ratio.

4. The method as claimed in claim 1, wherein the amount of the rare earth ion is at least 0.01 in terms of a rare earth ion/Al atomic ratio.

9. The method as claimed in claim 2, wherein the catalyst further comprises at least one kind of rare earth ion loaded on the zeolite.

10. The method as claimed in claim 9, wherein the amounts of the copper ion, the alkaline earth metal, and the rare earth ion are 5% to 80%, in terms of atomic ratio, based upon the aluminum atom in the zeolite, 0.05% to 2% by weight based upon the weight of the zeolite, and 0.1% to 10% by weight based upon the weight of the zeolite, respectively.

12. The method as claimed in claim 2, wherein said valence variable metal is at least one kind of metal selected from the group consisting of Fe, Co, Ni, V, Mn, W, Mo, Cr, Ti, and Nb.

13. The method as claimed in claim 12, wherein the amounts of the copper ion and the valence variable metal are 5% to 80%, in terms of atomic ratio, based upon the aluminum atom in the zeolite and 0.01% to 3% by weight based upon the weight of the zeolite.

5. A method of purifying an exhaust gas containing an excess amount of oxygen, which comprises bringing a catalyst into contact with the exhaust gas in the presence of an organic compound to remove nitrogen oxides, carbon monoxide and hydrocarbons from the exhaust gas, the catalyst comprising:

(i) a zeolite having a molar ratio of SiO₂ /Al₂ O₃ of at least 10; and

(ii) at least one copper ion and at least one kind of alkaline earth metal loaded thereon.

6. The method as claimed in claim 5, wherein said alkaline earth metal is at least one kind of metal selected from the group consisting of magnesium, calcium, strontium, and barium.

7. The method as claimed in claim 5, wherein the amount of the copper ion is 5% to 80%, in terms of atomic ratio, based upon the atom of Al in the zeolite.

8. The method as claimed in claim 5, wherein the amount of the alkaline earth metal is 0.1% to 10% by weight based upon the weight of the zeolite.

11. A method of purifying an exhaust gas containing an excess amount of oxygen, which comprises bringing a catalyst into contact with the exhaust gas in the presence of an organic compound to remove nitrogen oxides, carbon monoxide and hydrocarbons from an exhaust gas, the catalyst comprising:

(i) a zeolite having a molar ratio of SiO₂ /Al₂ O₃ of at least 10; and

(ii) at least one copper ion and at least one kind of valence variable metal loaded thereon.