Method for fabricating an electrically heatable coated transparency

• US 5,270,517 A
• Filed: 03/28/1991
• Issued: 12/14/1993
• Est. Priority Date: 12/29/1986
• Status: Expired due to Fees

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Finley, James J.
• Primary Examiner(s): Reynolds, Bruce A.
• Assistant Examiner(s): SWITZER, MICHAEL
• Application Number:
  US07/676,619
• Time in Patent Office: 992 Days
• Field of Search: 219/547, 219/522, 219/543, 219/203, 52/171
• US Class Current: 219/203
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10348 comprising an obscuration band
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3673 specially adapted for use in heating devices for rear window of vehicles
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 17/3689 one oxide layer being obtained by oxidation of a metallic layer
• CPC Class Codes: C03C 2217/73 Anti-reflective coatings with specific characteristics

Abstract

A method for fabricating an electrically heatable coated transparency, particularly useful as a vehicle windshield, is disclosed. The method involves sputtering on a substrate surface layers of metal oxide, metal-containing primer, infrared reflective metal, metal-containing primer and metal oxide to produce an electroconductive coating, and applying first and second bus bars to the substrate in contact with the coating.

Claims

1. A method for fabricating an electrically heatable coated transparency comprising the steps of:

a. sputtering a metal cathode target comprising zinc and tin in a reactive atmosphere comprising oxygen thereby depositing a first transparent antireflective zinc/tin oxide film on a surface of a transparent substrate;

b. sputtering a metal-containing primer layer on said antireflective zinc/tin oxide film;

c. sputtering an infrared reflective electroconductive metallic film over said metal-containing primary layer;

d. sputtering a metal-containing primer layer over said infrared reflective electroconductive metallic film;

e. sputtering a second metal oxide film over said metal-containing primer layer to produce an electroconductive multilayer coating; and

f. applying first and second bus bars to said substrate in contact with said coating.

2. A method according to claim 1, wherein said substrate is glass.

3. A method according to claim 1, further comprising the step of depositing a protective metal-containing overcoat deposited over said second metal oxide film.

4. The method according to claim 1, comprising the further step of subjecting the multiple-layer coated article to high temperature processing whereby the transmittance of the coating increases.

5. A method for fabricating an electrically heatable coated laminated transparency comprising the steps of:

a. placing a transparent nonmetallic substrate in a sputtering chamber;

b. sputtering zinc and tin in a reactive atmosphere comprising oxygen to deposit a first transparent metal alloy oxide film on a surface of said substrate;

c. sputtering titanium in an oxidizing atmosphere to deposit titanium oxide and then sputtering titanium in an inert atmosphere to deposit titanium to form a primer layer on said oxide film;

d. sputtering a silver cathode target in an inert atmosphere to deposit a transparent silver film on said primer layer;

e. sputtering titanium to deposit a second titanium-containing primer layer on said silver film;

f. sputtering zinc and tin in a reactive atmosphere comprising oxygen to deposit a second metal alloy oxide film on said second titanium-containing primer layer to produce an electroconductive multilayer coating;

g. applying first and second bus bars to said substrate in contact with said coating; and

h. laminating the coated transparent substrate with a second transparent substrate.

6. The method according to claim 5, wherein the transparent nonmetallic substrate is glass.

7. The method according to claim 6, wherein the second transparent substrate is plastic.

8. The method according to claim 6, further comprising the step of depositing a metal-containing protective coating over said second metal alloy oxide film.