Optical fiber sensor and method of manufacture

• US 5,271,073 A
• Filed: 08/10/1990
• Issued: 12/14/1993
• Est. Priority Date: 08/10/1990
• Status: Expired due to Fees

• Current Assignee: Puritan Bennett Corp. (Medtronic Plc)
• Original Assignee: Puritan Bennett Corp. (Medtronic Plc)
• Inventors: Lumsden, Terry J., Hui, Henry K.
• Primary Examiner(s): Ullah, Akm E.
• Application Number:
  US07/565,639
• Time in Patent Office: 1,222 Days
• Field of Search: 350/96.29, 350/96.30, 350/96.31, 350/96.33, 350/96.34, 427/163, 385/12, 385/13
• US Class Current: 385/12
• CPC Class Codes: G01N 2021/772 Tip coated light guide
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B

Abstract

The optical fiber sensor is formed from an optical fiber having a light conducting optical fiber core, and a coating of cladding material, with a length of a sensing material matrix applied to the distal portion of the optical fiber core. The method involves removing a length of the cladding material from the distal portion of the optical fiber to expose a distal tip of the optical fiber core, applying a sensing material matrix to the exposed distal portion of the optical fiber core, and applying a coating of reflective material over the sensing material matrix.

Claims

1. A method of making an optical fiber sensor from an optical fiber having proximal and distal portions, a light conducting optical fiber core with a side portion and a coating of cladding material over said side portion, the steps of the method comprising:

removing a length of said cladding material from the distal portion of the side portion of the optical fiber to expose a distal side portion of the optical fiber core;

applying a polymeric, semipermeable sensing material matrix containing a dye indicator material to the exposed distal portion of the optical fiber core; and

applying a coating of reflective material over the sensing material matrix.

2. The method of claim 1, wherein said cladding material is removed by electrical discharge.

3. The method of claim 1, wherein the length of cladding material removed ranges from approximately 10 microns of 100 mm.

4. The method of claim 1, wherein said optical fiber core is made of glass, and said step of removing a length of said cladding material further comprises cleaning the surface of the exposed distal portion of the optical fiber core and treating the surface with sulfuric acid to improve wettability of the exposed optical fiber core.

5. The method of claim 4, wherein said step of applying said sensing material matrix includes chemically treating the surface of the exposed distal portion with a primer to improve adhesion between the surface and the polymeric, semipermeable sensing material matrix.

6. The method of claim 5, wherein said primer comprises vinyltrichlorosilane.

7. The method of claim 1, wherein the sensing material matrix comprises a polymeric silicone.

8. The method of claim 1, wherein said matrix comprises cross-linked polydimethylsiloxane.

11. The method of claim 1, wherein the applied thickness of said sensing material matrix ranges approximately from 1 to 20 microns along the sides of the optical fiber core and ranges approximately from 5 to 100 microns at the extreme distal tip of the optical fiber core.

9. The method of claim 9, wherein said step of applying the sensing material matrix comprises dipping the exposed distal portion of the optical fiber core into an uncured liquid form of the sensing material matrix.

10. The method of claim 9, wherein said step of applying the sensing material matrix comprises controlling the thickness of the sensing material matrix by controlling the viscosity of the uncured liquid form of the sensing material matrix.

12. The method of claim 9, further comprising the step of curing said uncured liquid form of the sensing material matrix.

13. An optical fiber sensor apparatus comprising:

an optical fiber having proximal and distal portions, a light conducting optical fiber core with a side portion having a coating of cladding material over the proximal portion of the side portion of said optical fiber core and with said coating of cladding material having been removed from the distal portion of the side portion of said optical fiber core; and

a length of a polymeric, semipermeable sensing material matrix containing a dye indicator material applied to the uncladded distal portion of the optical fiber core.

14. The apparatus of claim 13, further including a coating of reflective material applied over the sensing material matrix.

15. The apparatus of claim 13, wherein the sensing material matrix is a polymeric silicone matrix.

16. The apparatus of claim 13, wherein said matrix comprises cross-linked polydimethylsiloxane.

17. The apparatus of claim 13, wherein the applied thickness of said sensing material matrix ranges approximately from 1 to 20 microns along the sides of the optical fiber core and ranges approximately from 5 to 100 microns at the extreme distal tip of the optical fiber core.

18. A method of making an optical fiber sensor from an optical fiber having an optical fiber core and a side surface coated with a cladding material, the steps of the method comprising:

removing a portion of said cladding material from the side surface of the optical fiber to expose a portion of the side surface of the optical fiber core;

applying a polymeric, semipermeable sensing material matrix containing a dye indicator material to the exposed portion of the optical fiber core; and

applying a coating of reflective material over the sensing material matrix.

19. The method of claim 18, wherein said optical fiber core is made of glass, the optical fiber core has a distal surface portion which is exposed by said removal of cladding material, and said step of removing said cladding material further comprises cleaning the exposed distal surface portion of the optical fiber core and treating the surface with acid to improve wettability of the exposed optical fiber core.

20. The method of claim 18, wherein said polymeric, semipermeable sensing matrix is applied in an uncured liquid form, and said step of applying the sensing material matrix comprises controlling the thickness of the sensing material matrix by controlling the viscosity of the uncured liquid form of the sensing material matrix.

21. An optical fiber sensor apparatus comprising:

a optical fiber having a light conducting optical fiber core with a side surface substantially coated with a cladding material and a portion of said side surface having said cladding material removed therefrom to provide an uncladded side surface portion of said optical fiber; and

a polymeric, semipermeable sensing material matrix containing a dye indicator material applied to the uncladded side surface portion of the optical fiber core.

22. The apparatus of claim 21, further including a coating of reflective material applied over the polymeric, semipermeable sensing material matrix.

23. The apparatus of claim 21, wherein the polymeric, semipermeable sensing material matrix comprises a polymeric silicone matrix.

24. The apparatus of claim 21, wherein said matrix comprises cross-linked polydimethylsiloxane.

25. A method of making an optical fiber sensor from an optical fiber having proximal and distal portions, a glass light conducting optical fiber core with a side portion and a coating of cladding material over said side portion, the steps of the method comprising:

removing a length of said cladding material from the distal portion of the side portion of the optical fiber to expose a distal side portion of the optical fiber core;

cleaning the surface of the exposed distal portion of the optical fiber core and treating the surface with sulfuric acid to improve wettability of the exposed optical fiber core; and

applying a polymeric, semipermeable sensing material matrix containing a dye indicator material to the exposed distal potion of the optical fiber core.

26. The method of claim 25, wherein said step of applying said sensing matrix includes chemically treating the surface of the exposed distal portion with a primer to improve adhesion between the surface and the polymeric, semipermeable sensing material matrix.

27. The method of claim 26, wherein said primer comprises vinyltrichlorosilane.

28. A method of making an optical fiber sensor from an optical fiber having proximal and distal portions, a light conducting optical fiber core with a side portion and a coating of cladding material over said side portion, the steps of the method comprising:

removing a length of said cladding material from the distal portion of the side portion of the optical fiber to expose a distal side portion of the optical fiber core; and

applying a polymeric, semipermeable sensing material matrix containing a dye indicator material to the exposed distal portion of the optical fiber core by dipping the exposed distal portion of the optical fiber core into an uncured liquid form of the sensing material matrix, and controlling the thickness of the sensing material matrix by controlling the viscosity of the uncured liquid form of the sensing material matrix.