Structural body for vehicle

• US 5,271,612 A
• Filed: 05/13/1992
• Issued: 12/21/1993
• Est. Priority Date: 05/13/1991
• Status: Expired due to Fees

• Current Assignee: Nippon Zeon Co., Ltd., Zeon Kasei (Changshu) Co. Ltd. (ZEON Corporation)
• Original Assignee: Nippon Zeon Co., Ltd., Zeon Kasei (Changshu) Co. Ltd. (ZEON Corporation)
• Inventors: Yada, Seiki, Hino, Noboru, Mikuni, Takamitsu, Nagase, Toshio, Kagoshima, Yutaka
• Primary Examiner(s): Graham, Matthew C.
• Application Number:
  US07/882,680
• Time in Patent Office: 587 Days
• Field of Search: 267/148, 267/149, 267/158, 267/151, 267/152, 267/136, 267/140.3, 296/146 C, 428/246, 428/283, 428/138, 156/330, 156/338
• US Class Current: 267/158
• CPC Class Codes: B32B 2305/022 Foam
• CPC Class Codes: B32B 2307/56 Damping, energy absorption
• CPC Class Codes: B32B 25/045 of foam
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: B62D 29/00 Superstructures, understructures, or sub-units thereof, characterised by the material thereof B62D33/044, B62D33/048 take precedence
• CPC Class Codes: B62D 29/04 predominantly of synthetic material working of plastics or substances in a plastic state B29
• CPC Class Codes: F16F 1/37 of foam-like material , i.e. microcellular material, e.g. sponge rubber padded linings for vehicle interiors B60R21/04
• CPC Class Codes: Y10T 428/24331 including nonapertured component

Abstract

A vibration-damping structural body for a vehicle, which comprises a sublayer sheet composed of a foamed thermoset resin and fusion-bonded onto a vehicle part, and at least one layer, which is fusion-bonded onto the sublayer and is selected from a damping intermediate sheet (2) comprised of a viscoelastic material and restraining sheet (3). The sublayer sheet (1) is formed from a semi-gelled sheet made by heating a forming and thermosetting resin composition comprising (A) an epoxy resin, (B) a coreacting curing agent, (C) a foaming agent, (D) a surface active agent and (E) a rubber-like elastic material or a powdery thermoplastic resin not containing halogen, which is insoluble in the epoxy resin at room temperature, but is miscible with and dispersible in the epoxy resin at 80° to 150° C.

Claims

1. A structural body for a vehicle with a two or three layer structure, which comprises a sublayer sheet comprised of a foamed thermoset resin fusion-bonded onto a vehicle part, and at least one layer fusion-bonded onto the sublayer sheet and selected from the group consisting of the following:

a vibration-damping intermediate sheet comprised of a viscoelastic material selected from the group consisting of rubber and asphalt, and

a restraining sheet fusion-bonded onto one of the sublayer and the vibration-damping intermediate sheet;

wherein said sublayer sheet is formed from a semi-gelled sheet made by heating a foaming and thermosetting resin composition comprising;

(A) 100 parts by weight of an epoxy resin having at least two epoxy groups in the molecule,

(B) 0.5 to 20 parts by weight of a coreacting curing agent for the epoxy resin,

(C) 0.5 to 20 parts by weight of a foaming agent having a decomposition temperature of 100°

to 220°

C.,

(D) 0.05 to 5 parts by weight of a surface active agent, and

(E) 10 to 200 parts by weight of at least one material which is insoluble in the epoxy resin at room temperature, but is miscible with and dispersible in the epoxy resin at a temperature of 80°

to 150°

C., and which is selected from the group consisting of a rubber-like elastic material, and a powdery thermoplastic resin which does not contain a halogen and has an average particle diameter of not larger than 150 μ

m;

said heating of the foaming and thermosetting resin composition being carried out at a temperature lower than the decomposition temperature of the foaming agent (C).

2. A structural body for a vehicle according to claim 1 which has a three layer structure comprising the sublayer sheet adapted to be fusion-bonded onto a vehicle part, the vibration-damping intermediate sheet fusion-bonded onto the sublayer sheet, and the restraining sheet fusion-bonded onto the vibration-damping intermediate sheet.

3. A structural body for a vehicle according to claim 1 wherein the epoxy resin (A) has an epoxy equivalent of 100 to 300.

4. A structural body for a vehicle according to claim 1 wherein the coreacting curing agent exhibits an exotherm peak temperature of 100°

to 200°

C. as used in combination with the particular epoxy resin.

5. A structural body for a vehicle according to claim 1 wherein said foaming and thermosetting resin composition further comprises a curing promoter.

6. A structural body for a vehicle according to claim 1 wherein the foaming agent (C) is an organic foaming agent.

7. A structural body for a vehicle according to claim 1 wherein the foaming agent is a powder having a particle diameter of smaller than 20 μ

m.

8. A structural body for a vehicle according to claim 1 wherein said foaming and thermosetting resin composition further comprises a foaming promoter.

9. A structural body for a vehicle according to claim 1 wherein the powdery thermoplastic resin has a particle diameter of not larger than 150 μ

m.

10. A structural body for a vehicle according to claim 1 wherein the rubber-like elastic material and the powdery thermoplastic resin (E) are capable of being molten to form a uniform dispersion in the epoxy resin (A) when the foaming and thermosetting resin composition is heated to a temperature of at least 150°

C.

11. A structural body for a vehicle according to claim 10 wherein the rubber-like elastic material and the powdery thermoplastic resin (E) are not completely compatible with but are dispersible in the epoxy resin (A) in a molten state.

12. A structural body for a vehicle according to claim 1 wherein said foaming and thermosetting resin composition further comprises a diluent for the epoxy resin (A).

13. A structural body for a vehicle according to claim 1 wherein said foaming and thermosetting resin composition exhibits a melt viscosity of 2.5×

10³ to 5×

10⁴ dPa.s when the foaming agent is heated to a decomposed gas-evolving temperature.

14. A structural body for a vehicle according to claim 1 wherein the sublayer sheet is formed by heating the semi-gelled sheet at an expansion ratio of 2 to 30 and has a thickness of 1 to 50 mm.

15. A structural body for a vehicle according to claim 1 wherein the vibration-damping intermediate sheet is made of butyl rubber and has a thickness of not larger than 10 mm.

16. A structural body for a vehicle according to claim 1 wherein the restraining sheet is made of a thermoplastic resin having incorporated therein a material selected from the group consisting of a tackifier, and a thermosetting plastic material predominately comprised of rubber, and has a thickness of 0.5 to 3 mm.

17. A structural body for a vehicle according to claim 1 wherein the vibration-damping intermediate sheet is made of asphalt and has a thickness of not larger than 10 mm.