Method of making a trivalent chromium plated engine valve

• US 5,271,823 A
• Filed: 06/17/1992
• Issued: 12/21/1993
• Est. Priority Date: 06/17/1992
• Status: Expired due to Fees

• Current Assignee: Eaton Corp. (Wisconsin) (Eaton Corporation PLC.)
• Original Assignee: Eaton Corp. (Wisconsin) (Eaton Corporation PLC.)
• Inventors: Bujalski, Paul A., Narasimhan, Sundaram L., Schachameyer, Steven R.
• Primary Examiner(s): GORGOS, KATHRYN L
• Application Number:
  US07/899,966
• Time in Patent Office: 552 Days
• Field of Search: 205/287, 205/288, 205/289, 205/224, 205/50, 205/229, 205/319
• US Class Current: 205/224
• CPC Class Codes: C25D 3/06 from solutions of trivalent chromium
• CPC Class Codes: C25D 5/50 by heat-treatment
• CPC Class Codes: F01L 3/04 Coated valve members or valve-seats
• CPC Class Codes: F02B 3/06 with compression ignition compression ignition engines using air or gas for blowing fuel into compressed air in cylinder F02B13/02

Abstract

An internal combustion engine valve (100) is provided having a stem (4) onto which a plating or coating of trivalent chromium is electrodeposited and which is then heated at a temperature of at least about 150° F. for at least about 3 hours to provide a wear resistant surface that is superior to coatings of hexavalent chromium heretofor used for such purpose.

Claims

1. A method for providing a wear resistant chromium coating on a metallic internal combustion engine valve stem, said method including the steps of:

(a) electro-depositing a coating made solely from trivalent chromium ions and devoid of hexavalent chromium ions on the valve stem and,

(b) heating the coating of step (a) to a temperature of at least about 150°

F. for at least about 30 minutes.

2. The method of claim 1 wherein the chromium is electrodeposited as a coating on the valve in a aqueous solution containing trivalent chromium and boric acid.

3. The method of claim 2 wherein the solution has a pH of about 2.0 to about 3.0.

4. The method of claim 2 wherein the solution further includes at least one stabilizer.

5. The method of claim 2 or 4 wherein the solution further includes at least one regulator.

6. The method of claim 1 wherein the chromium is electrodeposited as a coating on the valve in an aqueous solution containing trivalent chromium, boric acid, at least one regulator, and at least one stabilizer, while the solution is at a temperature of about 110°

F. to about 120°

F. and has a pH of about 2.3 to about 2.7.

7. The method of claim 2 or 6 wherein the chromium is electrodeposited on the valve at an electrical current density of about 100 to about 150 amps per square foot of valve stem surface immersed in the solution.

8. A metallic engine valve having a stem having a wear resistant coating of chromium thereon, said chromium having been electro-deposited solely as trivalent chromium ions and devoid of hexavalent chromium ions thereon and then heated at a temperature of at least about 150°

F. for at least 30 minutes.