Biodegradable expanded foam material

• US 5,272,181 A
• Filed: 11/18/1992
• Issued: 12/21/1993
• Est. Priority Date: 11/18/1992
• Status: Expired due to Fees

• Current Assignee: Clean Green Packing Co. (Environmental Technologies USA, Inc.)
• Original Assignee: EverGreen Solutions, Inc. (District of Columbia) (Environmental Technologies USA, Inc.)
• Inventors: Boehmer, Edward W., Hanlon, Daniel L.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/978,112
• Time in Patent Office: 398 Days
• Field of Search: 521/84.1, 521/109.1, 521/149, 521/313, 106/122
• US Class Current: 521/84.1
• CPC Class Codes: C08J 2303/02 Starch; Degradation products thereof, e.g. dextrin
• CPC Class Codes: C08J 2451/00 Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08J2455/02; Derivatives of such polymers
• CPC Class Codes: C08J 9/0061 characterized by the use of several polymeric components
• CPC Class Codes: C08J 9/125 Water, e.g. hydrated salts

Abstract

Expanded foam materials having a high degree of biodegradability are prepared by combining a starch-graft copolymer (SGC) with grain based starch containing materials and 15-25% water and expanding the mixture either with or without blowing agents. The mixture of SGC and grain based material is directly expanded at elevated temperature with an extruder or other expansion means. The product may be customized for particular applications by manipulating the particular grafted monomer, manipulating the ratio of SGC to grain based material and/or by the addition of nucleators, blowing agents, plasticizers or other additives, and/or by varying moisture content and the conditions of expansion.

Claims

1. A method for preparing a foamed material, comprising:

combining a starch-graft copolymer having at least 15% of a monomeric resin grafted to a first starch with a second starch to make a mixture, said starch graft copolymer having a glass transition temperature below about 390 degrees F;

adding liquid and/or vaporous water to bring the water content of the mixture to between 10 and 50 percent;

conditioning the wetted mixture at elevated temperature; and

expanding the mixture.

2. The method of claim 1, wherein said first and second starch are unpredestructurized.

3. The method of claim 1, wherein said starch-graft copolymer comprises 36-65 percent add-on polymer.

4. The method of claim 1, wherein said second starch is derived from one or more of corn, wheat, rice, potatoes and tapioca.

5. The method of claim 1, wherein the starch-graft copolymer comprises a starch grafted with a methyl acrylate to produce a copolymer containing up to 65 percent add-on methyl acrylate.

6. The method of claim 1, wherein the mixture is expanded by passage through a single-screw extruder and die(s).