Non-fogging sheet and its production

• US 5,273,812 A
• Filed: 12/24/1991
• Issued: 12/28/1993
• Est. Priority Date: 02/27/1990
• Status: Expired due to Fees

• Current Assignee: Dai Nippon Printing Company Limited
• Original Assignee: Dai Nippon Printing Company Limited
• Inventors: Ueda, Kenji, Yamamoto, Masahiro, Oguchi, Kiyoshi, Takekoh, Osamu, Doi, Tomio
• Primary Examiner(s): Ryan, Patrick J.
• Assistant Examiner(s): JEWIK, PATRICK
• Application Number:
  US07/773,664
• Time in Patent Office: 735 Days
• Field of Search: 427/44, 427/54.1, 427/155, 427/365, 427/366, 427/428, 156/273.7, 156/275.5, 156/324, 156/247, 156/327, 156/344, 428/409, 428/411.1, 428/336, 428/220, 428/913, 428/40
• US Class Current: 428/220
• CPC Class Codes: B05D 1/40 Distributing applied liquids or other fluent materials by members moving relatively to surface
• CPC Class Codes: B05D 2201/00 Polymeric substrate or laminate
• CPC Class Codes: B05D 2252/02 of indefinite length
• CPC Class Codes: B05D 2320/10 Detergents
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 3/068 using ionising radiations (gamma, X, electrons)
• CPC Class Codes: B05D 5/04 to obtain a surface receptive to ink or other liquid B05D5/02, B41M5/52 take precedence
• CPC Class Codes: B29C 35/0866 using particle radiation
• CPC Class Codes: B29C 35/10 for articles of indefinite length
• CPC Class Codes: B29D 7/01 Films or sheets
• CPC Class Codes: B32B 2305/72 Cured, e.g. vulcanised, cross-linked
• CPC Class Codes: B32B 2310/0881 using ion-radiation, e.g. alpha-rays
• CPC Class Codes: B32B 37/24 with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate B32B37/15 takes precedence
• CPC Class Codes: Y10T 428/31 Surface property or characteristic of web, sheet or block
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

A method for producing a thick film type of non-fogging sheets having a thickness of 30 μm or more comprises the steps of: preparing a solvent-free composition comprising (a) a polymer, (b) a hydrophilic monomer and (c) a surface active agent and having a viscosity of 50,000 cP or less, applying this composition as a coating on the surface of a backing film without recourse to any solvent, and crosslinking the thus coated composition by exposure thereof to ionizing radiation, thereby forming a hydrophilic film having a thickness of 30 μm or more.

Claims

1. A method for producing a non-fogging sheets having a thickness of 30 μ

m or more, comprising the steps of;

preparing a solvent-free composition comprising, as essential components, (a) a polymer, (b) a hydrophilic monomer and (c) a surface active agent and having a viscosity of up to 50,000 cP, the proportion of said hydrophilic monomer to said polymer being at most 50 mole percent, the weight ratio of said hydrophilic monomer to said polymer being 5-400;

100, the weight ratio of said surface active agent to said polymer being <

200;

100, said polymer comprising a functional polymer, the number of functional groups being one per molecular weight of 300 to 10,000.

placing a baking film and a laminating film having a centerline-average surface roughness of 0.1 μ

m or less, one superimposed upon the other, between a pair of rolls,

feeding and introducing said solvent-free composition under pressure in between said two films, thereby forming a layer of said composition between said films while forcing out a surplus amount of the composition fed with the force with which both the films are pressed together between said rolls to create a composition plenum on the interface of said two films at a roll nip entrance, thereby preventing gases from being entrained in the composition layer formed between the said two films,

exposing the obtained laminate composed of said backing film/composition/laminating film combination to ionizing radiation to crosslink the composition in said laminate, thereby forming a hydrophilic film having a thickness of not less than 30 μ

m, and

removing said laminating film from said laminate, leaving said hydrophilic film on said backing film.

2. A method as claimed in claim 1, wherein said composition further contains a crosslinkable monomer.

3. A method as claimed in claim 1, wherein said composition comprises a crosslinkable monomer.

4. A method as claimed in claim 1, wherein said ionizing radiation is by an electron beam or ultraviolet rays.

5. A non-fogging sheet obtained by the method as claimed in claim 1.

6. A non-fogging sheet as claimed in claim 5, characterized in that said centerline-average surface roughness is 0.1 μ

m or less.

7. A method as claimed in claim 1, wherein the polymer comprises a functional polymer, the number of functional groups being one per molecular weight of 300 to 10,000.

8. A method as claimed in claim 1, wherein the polymer has a weight-average molecular weight of 1,000 to 300,000.

9. A method as claimed in claim 1, wherein the polymer has a weight-average molecular weight of 1,000 to 300,000.

10. A method as claimed in claim 1, wherein the weight ratio of the hydrophilic monomer to the polymer is 5-400:

100.