Solid electrolyte fuel cells

• US 5,273,837 A
• Filed: 12/23/1992
• Issued: 12/28/1993
• Est. Priority Date: 12/23/1992
• Status: Expired due to Term

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: St. Julien, Dell J., Ketcham, Thomas D., Aitken, Bruce G., Faber, Margaret K.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US07/996,140
• Time in Patent Office: 370 Days
• Field of Search: 429/30-33, 429/34, 429/193, 204/410, 204/421, 501/104, 501/105, 501/102
• US Class Current: 429/496
• CPC Class Codes: H01M 8/0271 Sealing or supporting means around electrodes, matrices or membranes
• CPC Class Codes: H01M 8/1231 with both reactants being gaseous or vaporised
• CPC Class Codes: H01M 8/2432 Grouping of unit cells of planar configuration
• CPC Class Codes: H01M 8/2435 with monolithic core structure, e.g. honeycombs
• CPC Class Codes: H01M 8/2485 Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Thermal-shock-resistant fuel cell designs comprising flat and corrugated ceramic sheets combined to form channeled structures, the sheets being provided as thin, flexible ceramics and being particularly effective when used as components of compliant electrolyte substructures incorporating the flexible ceramics with fuel cell electrodes and/or current conductors bonded thereto, are described.

Claims

1. A solid electrolyte fuel cell comprising an oxidant reservoir, a fuel reservoir, and an electrolyte structure interposed between the oxidant and fuel reservoirs, wherein the electrolyte structure includes an oxygen-ion-conductive electrolyte comprising a thin, flexible, pre-sintered, polycrystalline ceramic sheet.

2. A fuel cell in accordance with claim 1 wherein the electrolyte is formed of a pre-sintered oxide ceramic of high oxygen ion conductivity.

3. A fuel cell in accordance with claim 2 wherein the major component of the pre-sintered oxide ceramic sheet is zirconium oxide.

4. A fuel cell in accordance with claim 1 which further comprises a gas channeling component for controlling fuel or oxidant flow in the cell, and wherein the gas channeling component is formed of a second flexible pre-sintered polycrystalline ceramic sheet.

5. A fuel cell in accordance with claim 4 wherein the electrolyte and/or the gas channeling component have thicknesses not exceeding about 45 micrometers.

6. A fuel cell in accordance with claim I wherein the pre-sintered polycrystalline ceramic sheet is directly bonded to an electrode or current conductor.

7. A thermal-shock-resistant fuel cell comprised of a combination of flat or curved and corrugated ceramic sheets forming a channeled fuel cell structure, wherein at least one of the sheets is a flexible pre-sintered ceramic sheet.

8. A thermal-shock-resistant fuel cell in accordance with claim 7 rein the flexible pre-sintered ceramic sheet is a flat or curved electrolyte sheet composed of an oxygen-ion-conducting ceramic oxide.

9. A thermal-shock-resistant fuel cell in accordance with claim 8 wherein the electrolyte sheet is provided as a component of a compliant electrolyte substructure, and wherein the substructure further comprises at least one additional fuel cell circuit component selected from the group consisting of fuel cell electrodes and fuel cell current conductors bonded directly to the electrolyte sheet.

10. A thermal-shock-resistant fuel cell in accordance with claim 9 wherein the circuit component is selected from the group consisting of a porous anode layer, a porous cathode layer, and a metallic, ceramic, or cermet current collector.

11. A thermal-shock-resistant fuel cell in accordance with claim 9 wherein the compliant electrolyte substructure comprises a porous anode layer bonded to a first surface of the electrolyte sheet and a porous cathode layer bonded to a second surface of the electrolyte, and wherein the thickness of the electrolyte substructure does not exceed about 150 micrometers.

12. A thermal-shock-resistant fuel cell in accordance with claim 11 wherein the corrugated sheets comprise flexible pre-sintered polycrystalline ceramic sheets.

13. A thermal-shock-resistant fuel cell in accordance with claim 7 wherein the flat sheets and/or the corrugated sheets are bonded to adjoining fuel cell components by means of a thermally crystallizable rare earth-alkali/alkaline earth-silicate sealing glass.

14. A thermal-shock-resistant fuel cell in accordance with claim 13 wherein the sealing glass comprises, in mole percent, about 0-35% R₂ O, wherein R₂ O consists of alkali metal oxides, 0-40% RO, wherein RO is selected from the alkaline earth metal oxides and ZnO, 7-40% total of R₂ O+RO, 3-18% Ln₂ O₃, wherein Ln₂ O₃ consists of rare earth metal oxides selected from the lanthanide series of rare earth metals and yttrium, 0-5% Al₂ O₂, and 53-75% SiO₂.