Production of ultrafine suspensions of bisphenol, sodium hydroxide and water

• US 5,275,758 A
• Filed: 09/01/1992
• Issued: 01/04/1994
• Est. Priority Date: 09/05/1991
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Schomacker, Reinhard, Heuser, Jurgen, Kadelka, Jurgen, Wulff, Claus, Weymans, Gunther, Hable, Konrad
• Primary Examiner(s): Lovering, Richard D.
• Application Number:
  US07/940,254
• Time in Patent Office: 490 Days
• Field of Search: 252/183.13, 252/311, 252/314
• US Class Current: 516/77
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/235 Metal derivatives of a hydroxy group bound to a six-membered aromatic ring
• CPC Class Codes: C08G 64/24 and phenols
• CPC Class Codes: Y10S 516/926 Phase change, e.g. melting

Abstract

The invention relates to ultrafine suspensions of bisphenol, sodium hydroxide and water for the production of polycarbonates by the two-phase interfacial process. According to the invention, these suspensions are prepared by cooling bisphenolate concentrations near the solubility limit in aqueous sodium hydroxide with intensive mixing at relatively high temperatures and precipitating bisphenolate or more bisphenolate in the form of fine droplets during the cooling process. The ultrafine suspensions provide for a high volume/time yield in the interfacial reaction.

Claims

1. A process for the production of ultrafine suspensions based on 2,2-bis- )-propane (=bisphenol A, "BPA"), sodium hydyroxide and water, characterized in that

a) a melt of bisphenol A is combined with sodium hydroxide and water with intensive mixing (mixing energy 0.5 watt/liter),

b) a temperature of at least 60°

C. and at most 90°

C. being established in at most 1 minute after mixing, optionally by cooling, and

c) the ratios of bisphenol A to NaOH are selected so that between 1.5 and 2.2 mol NaOH are used per mol bisphenol A and 15 parts by weight to 40 parts by weight of the sum of BPA and NaOH are present per 100 parts by weight water and

d) at most 50% of the BPA used, optionally in the form of its alkali metal salt, are precipitated at those temperatures and

e) the aqueous solution is subsequently cooled with further vigorous mixing (mixing energy>

0.5 watt/liter) to temperatures of 10 to 35°

C. in times of 1 second to 30 minutes, an opaque ultrafine suspension being formed.