Curable silicone composition and cured product thereof

• US 5,276,087 A
• Filed: 01/23/1992
• Issued: 01/04/1994
• Est. Priority Date: 01/24/1991
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Fujiki, Hironao, Ikeno, Masayuki
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): Dean, Karen A.
• Application Number:
  US07/824,304
• Time in Patent Office: 712 Days
• Field of Search: 524/847, 524/786, 524/862, 524/861, 524/860, 524/863, 523/223, 523/220
• US Class Current: 524/786
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 7/18 inorganic
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C10M 111/04 at least one of them being a macromolecular organic compound
• CPC Class Codes: C10M 2201/0623 used as base material
• CPC Class Codes: C10M 2201/1053 used as base material
• CPC Class Codes: C10M 2229/0435 used as base material
• CPC Class Codes: C10M 2229/0445 used as base material
• CPC Class Codes: C10N 2010/06 Groups 3 or 13
• CPC Class Codes: C10N 2010/14 Group 7
• CPC Class Codes: C10N 2030/02 Pour-point; Viscosity index
• CPC Class Codes: C10N 2040/14 Electric or magnetic purposes

Abstract

A curable silicone composition which can cure using hydrosilylation, comprising an aluminum oxide powder and/or silica powder, the powders each consisting of substantially spherical particles with an average particle diameter of 50 μm or below and an elongation of from 1.0 to 1.4 and being such that the respective amounts of alkali metal ions and halogen ions are extracted with 50 ml of water from 5 g of the powder at 121° C. for 20 hours are not more than 10 ppm, wherein the amount of the component (D) is from 25 to 90% by weight based on the composition, and the ratio of the amount of hydrosilyl groups contained in the components (A) and (B) to the amount of alkenyl groups contained in the components (A) and (B) is in the range from 0.5/1 to 1.5/1. When the composition is used as a protective material or encapsulating material for devices such as ICs, generated heat can be dissipated efficiently and the devices are not be broken by abrasion. There are no fears of causing corrosion of the devices.

Claims

1. A curable silicone composition comprising:

(A) an alkenyl-containing organopolysiloxane which contains an average of 0.5 or more alkenyl groups in its molecule,

(B) an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms in its molecule,

(C) a platinum group metal catalyst, and

(D) a corrosion resistant effective amount of aluminum oxide powder consisting of substantially spherical particles with an average particle diameter of 50 μ

m or below and an elongation of from 1.0 to 1.4 and being such that the respective amounts of alkali metal ions and halogen ions which are extracted with 50 ml of water from 5 g of the powder at 121°

C. for 20 hours is not more than 10 ppm, wherein the amount of the component (D) is from 25 to 90% by weight based on the composition, and the ratio of the amount of hydrosilyl groups contained in the components (A) and (B) to the amount of alkenyl groups contained in the components (A) and (B) is in the range from 0.5/1 to 1.5/1.

2. The composition according to claim 1, wherein the alkenyl-containing organopolysiloxane (A) is represented by the general composition formula (1):

space="preserve" listing-type="equation">R.sub.a SiO.sub.(4-a) /2 (1)

wherein R is a hydrogen atom or an unsubstituted or substituted monovalent hydrocarbon group of from 1 to 20 carbon atoms and a is a number in the range from 1.9 to 2.4.

3. The composition according to claim 2, wherein R consists of the vinyl group and the methyl group.

4. The composition according to claim 1, wherein the organohydrogenpolysiloxane (B) is contained such that the silicon-bonded hydrogen atoms therein are present in an amount of from 0.5 to 1.5 equivalents per equivalent of the alkenyl groups contained in the component (A), and the component (C) is contained in an amount of 0.1 to 500 ppm based on the component (A).

5. A cured product obtained by curing the curable silicone composition as defined in claim 1.