Alk-1-enyloxy carbonates

• US 5,276,174 A
• Filed: 03/09/1990
• Issued: 01/04/1994
• Est. Priority Date: 03/09/1990
• Status: Expired due to Fees

• Current Assignee: ISP Investments, Inc. (Ashland Global Holdings, Inc.)
• Original Assignee: ISP Investments, Inc. (Ashland Global Holdings, Inc.)
• Inventors: Narayanan, Kolazi S., Taylor, Paul D., Plotkin, Jeffrey S.
• Primary Examiner(s): Dees, Josee G.
• Assistant Examiner(s): Conrad, Joseph M.
• Application Number:
  US07/491,362
• Time in Patent Office: 1,397 Days
• Field of Search: 558/266, 558/265, 558/268, 558/275, 558/276
• US Class Current: 558/266
• CPC Class Codes: C07C 43/23 containing hydroxy or O-metal groups
• CPC Class Codes: C07C 69/96 Esters of carbonic or haloformic acids

Abstract

This invention relates to radiation curable alk-1-enyloxy carbonate reaction products of a polyhydroxylated compound having the formula ROH and a dialk-1-enyloxy carbonate having the formula ##STR1## wherein R is a C₃ to C₅₀ saturated or unsaturated, linear, branched or cyclic polyhydroxylated hydrocarbon radical optionally substituted with halo, alkoxy, lower alkyl, cyano or nitro;

R'"'"' is hydrogen or lower alkyl

B is a linear, branched or cyclic divalent radical having from 2 to 12 carbon atoms and is selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, lower alkyl, cyano, nitro or alkoxy and m has a value of from 1 to 10. The products of this invention are defined by the formula: ##STR2## wherein R" is the same as R except that it contains at least one less hydroxy group; (b) has a value of at least 1 up to the number of hydroxy groups in ROH and (n) represents the number of hydroxy groups in ROH.

Claims

1. A compound having the formula ##STR9## wherein R" is a C₃ to C₅₀ saturated or unsaturated, linear, branched or cyclic hydrocarbon radical optionally substituted with halo, alkoxy, lower alkyl, cyano or nitro;

R'"'"' is hydrogen or lower alkyl

B is a linear, branched or cyclic divalent radical having from 2 to 12 carbon atoms and is selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, lower alkyl, cyano, nitro or alkoxy;

(m) has a value of from 1 to 10;

(b) has a value of from at least one up to 10 and (n-b) has a value of from 0 to 9.

2. A composition containing a mixture of compounds of claim 1.

3. The composition of claim 2 which also contains an oligomer of a compound at least one of said compounds in said mixture.

4. The compound of claim 1 wherein R'"'"' is hydrogen (m) is one.

5. The compound of claim 4 wherein B is butylene.

6. The compound of claim 4 wherein B is --CH₂ --C₆ H₁₀ --CH₂ --.