Impact-resistant compatibilized polymer blends of olefin polymers and polyamides

• US 5,278,231 A
• Filed: 09/16/1992
• Issued: 01/11/1994
• Est. Priority Date: 05/24/1990
• Status: Expired due to Term

• Current Assignee: Ferro Corporation (Vibrantz Technologies, Inc.)
• Original Assignee: Ferro Corporation (Vibrantz Technologies, Inc.)
• Inventors: Chundury, Deenadayalu
• Primary Examiner(s): WOODWARD, ANA LUCRECIA
• Application Number:
  US07/945,511
• Time in Patent Office: 482 Days
• Field of Search: 525/92, 525/66
• US Class Current: 525/66
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

Blended polymer compositions are described which comprise

(I) from about 1% to about 97% by weight of at least one alpha-olefin polymer;

(II) from about 1% to about 97% by weight of at least one polyamide;

(III) from about 1% to about 97% by weight of at least one polymer of a vinyl aromatic hydrocarbon; and

(IV) an effective amount of a mixture of two or more compatibilizing agents selected from the group consisting of

(IVa) at least one selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene;

(IVb) at least one selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene to which has been grafted, an alpha,beta-olefinically unsaturated monocarboxylic or dicarboxylic acid reagent; and

(IVc) at least one terpolymer of an alpha-olefin, at least one acrylic ester, and an alpha,beta-olefinically unsaturated dicarboxylic acid reagent, or a glycidyl acrylate.

The polymer blends of the present invention have improved impact-resistance.

Claims

1. A blended polymer composition comprising

(I) from about 60% to about 90% by weight of at least one alpha-olefin polymer selected from the group consisting of polypropylene and copolymers of ethylene and propylene;

(II) from about 5% to about 25% by weight of at least one polyamide;

(III) from about 5% to about 25% by weight of at least one copolymer of a vinyl aromatic hydrocarbon and an unsaturated mono-or dicarboxylic acid reagent, wherein the copolymer is other than a graft copolymer; and

(IV) from about 1% up to about 25% by weight of a mixture of two or more compatibilizing agents selected from the group consisting of

(IVa) at least one selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene;

(IVb) at least one selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene to which has been grafted, an alpha, beta-olefinically unsaturated monocarboxylic or dicarboxylic acid reagent; and

(IVc) at least one terpolymer of an alpha-olefin, at least one acrylic ester, and an alpha, beta-olefinically unsaturated dicarboxylic acid reagent, or a glycidyl acrylate, wherein (IV) comprises mixtures of (IVa) and (IVb), (IVa) and (IVc), (IVb) and (IVc), or (IVa), (IVb), and (IVc).

2. The polymer composition of claim 1 wherein said composition further comprises a scrap material comprising the same composition obtained from a preceding molding operation using the polymer composition of claim 1.

3. The polymer composition of claim 1 wherein the polyamide (II) is selected from the group consisting of polyhexamethylene adipamide, polyhexamethylene sebacamide, polycaprolactam, polyhexamethylene isophthalamide, polyhexamethylene tere-co-isophthalamide, polytetramethylene adipamide and mixtures thereof.

4. The polymer composition of claim 1 wherein the copolymer (III) is a copolymer of a styrene and a maleic anhydride or an N-hydrocarbyl-substituted maleimide.

5. The polymer composition of claim 1 comprising from about 1% to about 25% by weight of the compatibilizing agents (IV).

6. The polymer composition of claim 1 wherein the compatibilizing agent mixture is a mixture of (IVa) and (IVc).

7. The polymer composition of claim 1 wherein the block copolymers of (IVa) and (IVb) prior to hydrogenation, are each independently styrene-butadiene-styrene block copolymers.

8. The polymer composition of claim 1 wherein the carboxylic acid reagent in (IVb) is a dicarboxylic acid, anhydride, imide, half ester, metal salt, or mixtures thereof.

9. The polymer composition of claim 8 wherein the dicarboxylic acid compound is maleic acid.

10. The polymer composition of claim 1 wherein the terpolymer (IVc) comprises from about 60% to about 94% by weight of the olefin, from about 5% to about 40% by weight of the acrylic ester and from about 1% to about 10% by weight of the dicarboxylic acid reagent or the glycidyl acrylate.

11. The polymer composition of claim 1 also containing

(V) at least one filler, fiber or mixture thereof.

12. The polymer composition of claim 11 wherein the filler is talc or calcium carbonate, and the fiber is a glass fiber.

13. A blended polymer composition comprising

(I) from about 70% to about 90% by weight of at least one alpha-olefin polymer selected from the group consisting of polyethylene, and polypropylene,

(II) from about 5% to about 25% by weight of at least one polyamide having a number average molecular weight of at least about 5000;

(III) from about 5% to about 25% by weight of a copolymer of styrene and maleic anhydride; and

(IV) from about 1% to about 25% by weight of a mixture of two or more compatibilizing agents selected from the group consisting of

(IVa) at least one selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and an aliphatic conjugated diene;

(IVb) at least one selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and an aliphatic conjugated diene to which has been grafted an alpha, beta-olefinically unsaturated monocarboxylic or dicarboxylic acid reagent; and

(IVc) at least one terpolymer of ethylene or propylene, an acrylic ester and maleic acid, maleic anhydride, or a glycidyl acrylate.

14. The polymer composition of claim 13 also containing

(V) at least one filler to mixtures thereof.

15. The polymer composition of claim 14 wherein the filler is talc or calcium carbonate, and the fiber is a glass fiber.

16. The polymer composition of claim 13 wherein the polyamide (II) is selected from the group consisting of polyhexamethylene adipamide, polyhexamethylene sebacamide, polyhexamethylene tere-co-isophthalamide, polytetramethylene adipamide and mixtures thereof.

17. The polymer composition of claim 13 wherein the mixture of (IV) is a mixture of (IVa) and (IVb).

18. The polymer composition of claim 13 wherein the mixture of (IV) is a mixture of (IVa) and (IVc).

19. The polymer composition of claim 13 wherein the block copolymer of (IVa) and (IVb) prior to hydrogenation, are each independently styrene-butadien-e-styrene block copolymers.

20. The polymer composition of claim 13 wherein the carboxylic acid reagent in (IVb) is a dicarboxylic acid, anhydride, imide, half ester or metal salt, or mixtures thereof.

21. The polymer composition of claim 13 wherein the terpolymer (IVc) comprises from about 60% to about 94% by weight of ethylene, propylene or a mixture thereof, from about 5% to about 40% by weight of the acrylic ester and from about 1% to about 5% by weight of maleic acid or maleic anhydride.