Anionically polymerized polymers coupled with fullerenes

• US 5,278,239 A
• Filed: 06/30/1993
• Issued: 01/11/1994
• Est. Priority Date: 10/05/1992
• Status: Expired due to Fees

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Hoxmeier, Ronald J.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): Delaney, Patrick R.
• Application Number:
  US08/085,227
• Time in Patent Office: 195 Days
• Field of Search: 525/232, 525/314, 525/332.5, 525/333.2, 525/333.3
• US Class Current: 525/232
• CPC Class Codes: C08F 297/044 using a coupling agent
• CPC Class Codes: C08G 81/022 containing sequences of polymers of conjugated dienes and of polymers of alkenyl aromatic compounds
• CPC Class Codes: Y10S 977/753 with polymeric or organic binder
• CPC Class Codes: Y10S 977/842 for carbon nanotubes or fullerenes

Abstract

A process is described for producing a coupled polymer by anionically polymerizing monomers selected from the group consisting of a vinyl aromatic hydrocarbon, a conjugated diene or both with an organo alkali metal compound to produce living polymer arms which are then contacted with a fullerene which reacts with the living polymer arms to form a coupled polymer. The coupled polymer has a novel composition and novel characteristics.

Claims

1. An anionically polymerized polymer comprised of conjugated diene arms coupled with a fullerene.

3. The polymer of claim 1 wherein the polymer also contains arms comprised of a conjugated diene and a vinyl aromatic hydrocarbon which are also coupled with the fullerene.

2. An anionically polymerized polymer comprised of vinyl aromatic hydrocarbon arms coupled with a fullerene.

4. An anionically polymerized polymer comprised of arms comprised of a conjugated diene and a vinyl aromatic hydrocarbon coupled with a fullerene.

5. An anionically polymerized coupled polymer produced by the process which comprises:

(a) anionically polymerizing monomers selected from the group consisting of a vinyl aromatic hydrocarbon, a conjugated diene or both with an organo alkali metal compound to produce living polymer arms,

(b) contacting the living polymer arms with a fullerene which reacts with the living polymer arms, thereby forming a coupled polymer, and

(c) terminating the polymerization.

6. The product of claim 5 wherein the coupling reaction of step (b) is carried out at a temperature of from about 0°

C. to about 150°

C.

7. The product of claim 5 wherein the living polymer arms made in step (a) comprise blocks of at least two different monomers.

8. The product of claim 5 wherein after step (a) but before step (b), anionically polymerizing monomers different from those of step (a) and selected from the group consisting of a vinyl aromatic hydrocarbon, a conjugated diene or both with an organo alkali metal compound to produce a second set of living polymer arms, wherein the polymer arms from step (a) and the second set of polymer arms are coupled in step (b) to produce an asymmetric polymer.

9. The product of claim 5 wherein the following additional steps are added after step (c):

(d) anionically polymerizing monomers different from those of step (a) and selected from the group consisting of a vinyl aromatic hydrocarbon, a conjugated diene or both with an organo alkali metal compound to produce living polymer arms,

(e) contacting the living polymer arms of step (d) with the coupled and terminated polymer of step (c) wherein the living polymer arms of step (d) react with the fullerene and form an asymmetric coupled polymer, and

(f) terminating the polymerization.

10. The product of claim 5 wherein the organo alkali metal compound is a hydrocarbon lithium compound.

11. The product of claim 10 wherein the hydrocarbon lithium compound is sec-butyl lithium.

12. The product of claim 5 wherein the coupled polymer is hydrogenated.

13. The product of claim 8 wherein the coupled polymer is hydrogenated.

14. The product of claim 5 wherein the coupled polymer is hydrogenated.