Method for replicating holographic optical elements

• US 5,279,689 A
• Filed: 02/14/1992
• Issued: 01/18/1994
• Est. Priority Date: 06/30/1989
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Shvartsman, Felix P.
• Primary Examiner(s): Simmons, David A.
• Assistant Examiner(s): Barry, Chester T.
• Application Number:
  US07/839,665
• Time in Patent Office: 704 Days
• Field of Search: 156/220, 156/219, 156/209, 156/212, 156/273.7, 156/289, 156/230, 156/235, 156/238, 156/247, 156/332, 156/275.5, 264/106, 264/107, 264/2.7, 264/1.1, 264/1.3, 264/1.4, 369/284, 369/286, 428/64, 428/908, 350/3.7, 350/3.21, 350/3.71, 350/3.72, 350/162.2, 350/162.17, 204/5, 522/103, 522/170
• US Class Current: 156/220
• CPC Class Codes: B29C 2035/0833 using actinic light
• CPC Class Codes: B29C 33/60 Releasing, lubricating or separating agents in general C10M
• CPC Class Codes: B29C 33/62 based on polymers or oligomers
• CPC Class Codes: B29C 35/08 by wave energy or particle radiation B29C64/00, B29C71/04 take precedence
• CPC Class Codes: B29C 59/026 of layered or coated substantially flat surfaces
• CPC Class Codes: B29K 2105/0002 monomers or prepolymers
• CPC Class Codes: B29L 2031/7224 Holograms
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: G03F 7/0002 Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
• CPC Class Codes: G03F 7/001 Phase modulating patterns, e.g. refractive index patterns
• CPC Class Codes: G03F 7/20 Exposure; Apparatus therefor photographic printing apparatus for making copies G03B27/00
• CPC Class Codes: G03H 1/028 by embossing
• CPC Class Codes: G11B 7/26 Apparatus or processes specially adapted for the manufacture of record carriers
• CPC Class Codes: Y10T 156/1041 Subsequent to lamination

Abstract

A method for making an optical image element having a high aspect ratio relief hologram comprising the sequential steps of

(a) applying a dry photohardenable film to a surface of a transparent dimensionally stable substrate;

(b) embossing the exposed surface of the photohardenable film with the holographic image by applying thereto under pressure a stamper containing a reverse relief image of the hologram having an aspect ratio of at least 3:1;

(c) passing actinic radiation through the transparent substrate and the photohardenable film to effect hardening of the photohardenable film while it is in contact with the stamper; and

(d) separating the stamper die from the embossed photohardened film.

Claims

1. A method for replicating an optical element having a surface relief hologram comprising the sequential steps of:

(a) laminating a dry photohardenable film to a surface of a dimensionally stable optically transparent substrate, the film capable of being embossed at room temperature to form a relief holographic image having an aspect ratio of at least 10;

1;

(b) embossing a relief holographic image in the photohardenable film at room temperature by applying thereto under pressure a stamper containing a reverse relief image of the hologram having an aspect ratio of at least 10;

1;

(c) passing actinic radiation through the transparent substrate and the unheated photohardenable film to effect hardening of the photohardenable film while maintaining embedded contact between the stamper and the photohardenable film; and

(d) separating the stamper from the photohardened film containing the surface relief hologram having an aspect ratio of at least 10;

1.

2. The method of claim 1 in which a polymeric protective layer is applied to the surface of the embossed photohardened film subsequent to the embossing step.

3. The method of claim 1 in which the substrate is formed into a disc prior to lamination.

4. The method of claim 1 in which the substrate is in sheet form prior to lamination and is formed into a disc following lamination.

5. The method of claim 1 in which the substrate is made from a material selected from the group consisting of polycarbonate, poly(methylmethacrylate) or glass.

6. The method of claim 1 in which the photohardenable film has a creep viscosity of at least 20 megapoise.

7. The method of claim 1 in which the stamper is made by the sequential steps of:

(e) applying a second dry photohardenable film to a surface of a dimensionally stable substrate;

(f) embossing the exposed surface of the second photohardenable film with the surface of a relief hologram;

(g) passing actinic radiation through the second photohardenable film to effect hardening of the second photohardenable film while it is in contact with the stamper; and

(h) separating the photohardened film from the relief hologram.

8. The method of claim 7 in which a release layer is applied to the second photohardened film after step (h).

9. The method of claim 8 in which the release layer is either Al or Cr.

10. The method of claim 8 in which the release layer is a low surface energy solid organic polymer.

11. The method of claim 10 in which the low surface energy solid organic polymer is a fluoropolymer.

12. A method for replicating an optical element having a surface relief hologram, comprising:

(a) embossing a relief holographic image having an aspect ratio of at least 10;

1 in a dry photohardenable film at room temperature by applying thereto under pressure a stamper containing a reverse relief image of the relief image having an aspect ratio of at least 10;

1, wherein the dry photohardenable film is supported by a dimensionally stable, optically transparent substrate;

(b) passing actinic radiation through the transparent substrate and the embossed dry photohardenable film while maintaining embedded contacted between the stamper and the photohardenable film; and

(c) separating the stamper from the film containing the surface relief hologram having the aspect ratio of at least 10;

1,

wherein the dry photohardenable film consists essentially of an admixture of 5-50% liquid ethylenically unsaturated monomer or monomers, 0.1-10% initiator system, 25-75% solid polymeric binder or binders, 0-25% plasticizer or plasticizers, and 0-5% other ingredients, wherein the percentages are percents by weight.

13. The method of claim 12, wherein at least one of the monomers contains more than one ethylenically unsaturated group.

14. The method of claim 12, wherein at least one of the monomers contains three ethylenically unsaturated groups.

15. The method of claim 12, wherein at least one of the monomers is a triacrylate or a trimethacrylate of trimethylolpropane or ethoxylated trimethylolpropane.

16. The method of claim 12, wherein the admixture includes:

at least one monomer from the group consisting of trimethylolpropane trimethacrylate and triacrylate ester of ethoxylated trimethylolpropane; and

at least one binder form the group consisting of poly(methyl methacrylate) and poly(vinyl acetate).

17. The method of claim 12, wherein the dry photohardenable film comprises an admixture of:

poly(methyl methacrylate);

poly(vinyl acetate);

trimethylolpropane trimethacrylate;

triacrylate ester of ethoxylated trimethylolpropane;

1,1'"'"'-biimidazole, 2,2'"'"'-bis[o-chloro-phenyl]-4,4'"'"',5,5'"'"'-tetraphenyl-;

2-mercapto benzoxazole;

2-(stibyl-4")-(naphto-1'"'"',2'"'"',4,5)-1,2,3-triazol-2"-sulfonic acid phenyl ester;

3-phenyl-7-[2'"'"'-(4'"'"'-N,N-diethylamino-6'"'"'-chloro-1'"'"',3'"'"',5'"'"'-triazinylamino]-coumarin;

(2-hydroxy-4-methoxyphenyl) (2-hydroxyphenyl) methanone;

polyoxyethylene (4) lauryl ether;

hydroquinone; and

1,4,4-trimethyl-2,3-diazobicyclo-(3.2.2-)-non-2-ene-2,3-dioxide.