Phosphonic acid based ion exchange resins

• US 5,281,631 A
• Filed: 12/20/1991
• Issued: 01/25/1994
• Est. Priority Date: 12/20/1991
• Status: Expired due to Term

• Current Assignee: ARCH Development Corporation (University of Chicago), The University Of Tennessee Research Corporation (University of Tennessee)
• Original Assignee: ARCH Development Corporation (University of Chicago)
• Inventors: Horwitz, E. Philip, Alexandratos, Spiro D., Gatrone, Ralph C., Chiarizia, Ronato
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Zitomer, Fred
• Application Number:
  US07/811,098
• Time in Patent Office: 767 Days
• Field of Search: 526/278, 521/38, 521/33, 521/25
• US Class Current: 521/38
• CPC Class Codes: B01J 39/12 Compounds containing phosphorus
• CPC Class Codes: B01J 39/20 obtained by reactions only involving unsaturated carbon-to-carbon bonds

Abstract

An ion exchange resin for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene disphosphonic acid with styrene, acrylonitrile and divinylbenzene.

Claims

1. A polymeric ion exchange resin for extracting metal ions from a liquid waste stream, including:

(a) a first polymerizable component selected from the group consisting of vinylidene diphosphonic acid and alkyl/aryl esters of said diphosponic acid;

(b) a second polymerizable component selected from the group consisting of an acrylamide and a styrene;

(c) a third polymerizable component of a monomer selected from the group consisting of acrylonitrile, methyl acrylate and methyl methacrylate; and

(d) a fourth polymerizable component of a copolymer selected from the group consisting of a divinylic and a trivinylic cross linking agent.

2. The ion exchange resin as defined in claim 1 wherein said second component comprises a styrene.

3. The ion exchange resin as defined in claim 1 wherein said fourth component comprises a divinylbenzene.

4. The ion exchange resin as defined in claim 1 wherein said polymer is sulfonated.

5. A polymeric ion exchange resin for extracting metal ions from a liquid waste stream, comprising a copolymer prepared by copolymerizing components including:

(a) a first polymerizable component selected from the group consisting of vinylidene diphosphonic acid and alkyl/aryl esters thereof of from about 5-95 weight percent;

(b) a second polymerizable component consisting essentially of styrene from about 1-95 weight percent;

(c) a third polymerizable component selected from the group consisting essentially of acrylonitrile of about 10-95 weight percent; and

(d) a fourth polymerizable component selected from the group consisting of divinylbenzene of about 5-50 weight percent and 2-ethylhexanol.

6. The ion exchange resin as defined in claim 5 wherein the components are polymerized by reactants selected from the group consisting of ionic and free-radical initiators.

7. The ion exchange resin as defined in claim 5 wherein said polymer is sulfonated.

8. The ion exchange resin as defined in claim 5 wherein said resin has a phosphorous capacity of about 1-5 mequiv/g. per dry resin.

9. The ion exchange resin for extracting metal ions from a liquid waste stream, comprising a copolymer having copolymerized components including:

(a) a first polymerizable component selected from the group consisting of vinylidene diphosphonic acid and alkyl/aryl esters of said diphosphonic acid;

(b) a second polymerizable component of an acrylamide; and

(c) a third polymerizable component consisting essentially of acrylonitrile.

10. The ion exchange resin as defined in claim 9 wherein said resin is sulfonated.

11. The ion exchange resin as defined in claim 9 wherein said acrylamide comprises a mixture of N,N'"'"'-methylenebisacrylamide and acrylamide.

12. The ion exchange resin as defined in claim 9 further including a fourth polymerizable component as a cross linking agent, said cross linking agent selected from the group consisting of divinylbenzene, trivinylbenzene, and diethylene glycoldiacrylate.

13. The ion exchange resin as defined in claim 12 wherein said cross linking agent consists essentially of divinylbenzene.

14. The ion exchange resin as defined in claim 9 wherein the components are polymerized by reactants selected from the group consisting of ionic and free-radical initiators, said components polymerized in the presence of a porogen.

15. The ion exchange resin as defined in claim 9 wherein said first component ranges from about 5-95 weight percent, said second component ranges from about 1-95 weight percent, said third component ranges from about 10-95 weight percent and said fourth component ranges from about 5-50 weight percent.