Supercritical fluid contamination monitor

• US 5,282,381 A
• Filed: 09/08/1992
• Issued: 02/01/1994
• Est. Priority Date: 09/08/1992
• Status: Expired due to Term

• Current Assignee: Raytheon Company (Rtx Corporation)
• Original Assignee: Hughes Aircraft Company (Rtx Corporation)
• Inventors: Krone-Schmidt, Wilfried
• Primary Examiner(s): Warden, Robert J.
• Assistant Examiner(s): CRAWFORD, LESLIE
• Application Number:
  US07/942,017
• Time in Patent Office: 511 Days
• Field of Search: 73/61.41, 73/64.56, 324/663, 324/693, 210/96.1, 210/662, 210/746
• US Class Current: 73/61.41
• CPC Class Codes: G01N 27/12 of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid , for detecting components in the fluid
• CPC Class Codes: G01N 27/221 by investigating the dielectric properties using microwaves G01N22/00; measuring loss factors or dielectric constants per se G01R27/26

Abstract

A system and method for detecting the presence of contaminants in supercritical fluid. The system is based upon the use of an absorbent module comprising an absorbent which selectively absorbs the contaminant being measured and wherein the electrical properties (i.e. conductance and/or capacitance) of the absorbent varies depending upon the amount of contaminant absorbed. A sample stream of the supercritical fluid is contacted with the absorbent material. By measuring the electrical properties of the absorbent, contaminant levels are measured and monitored.

Claims

1. A system for detecting the presence of contaminants in a supercritical fluid, said system comprising:

a conduit containing supercritical fluid;

sampling means connected to said conduit for removing supercritical fluid from said conduit to provide a sample stream;

a vessel having walls defining a contaminant measurement zone;

means for introducing said sample stream from said sampling means into said measurement zone;

an absorbent module comprising an absorbent material located within said measurement zone wherein said absorbent material comprises zeolite and is capable of selectively absorbing contaminants from said sample stream, said absorbent module having an electrical property which varies depending upon the amount of contaminant which is absorbed therein; and

electrical property measurement means for measuring the electrical property through said absorbent module to thereby provide for detection of contaminants present in said sample stream of supercritical fluid.

2. A system for detecting the presence of contaminants in a supercritical fluid according to claim 1 wherein said zeolite is selected from the group consisting of chabazite, gmelinite, erionite and sodalite.

3. A system for detecting the presence of contaminants in a supercritical fluid according to claim 1 wherein said zeolite has pore sizes of between about 0.5 to 130 angstroms.

4. A system for detecting the presence of contaminants in a supercritical fluid according to claim 1 wherein said absorbent module is in the shape of a rod having two ends wherein an electrode is located at each of said rod ends.

5. A system for detecting the presence of contaminants in a supercritical fluid according to claim 4 wherein said zeolite is selected from the group consisting of chabazite, gmelinite, erionite and sodalite.

6. A system for detecting the presence of contaminants in a supercritical fluid according to claim 4 wherein said zeolite has pore sizes of between about 0.5 and 130 angstroms.

7. A system for detecting the presence of contaminants in a supercritical fluid according to claim 1 wherein a plurality of said vessels are provided having walls defining a plurality of contaminant measurement zones and wherein means are provided for selectively introducing said sample stream into said plurality of measurement zones, wherein each of said measurement zones includes at least one of said absorbent modules located therein, and wherein electrical property measurement means are provided for individually measuring the electrical properties through each of said absorbent modules.

8. A system for detecting the presence of contaminants in a supercritical fluid according to claim 1 wherein a plurality of said absorbent materials are provided to selectively absorb different types of contaminants.

9. A method for detecting the presence of contaminants in supercritical fluid comprising the steps of:

providing a supercritical fluid;

contacting a portion of said supercritical fluid with an absorbent material comprising zeolite wherein the absorbent material has an electrical property and wherein the electrical property of said absorbent material varies depending upon the amount of said contaminants absorbed therein; and

measuring the electrical property of said absorbent material to thereby provide for detection of said contaminants in said supercritical fluid.

10. A method for detecting the presence of contaminants in supercritical fluid according to claim 9 wherein said zeolite is selected from the group consisting of chabazite, gmelinite, erionite and sodalites.

11. A method for detecting the presence of contaminants in supercritical fluid according to claim 9 wherein said zeolite has pore sizes of between about 0.5 to 130 angstroms.