Electrodialytic process for producing an alkali solution

• US 5,282,935 A
• Filed: 04/13/1992
• Issued: 02/01/1994
• Est. Priority Date: 04/13/1992
• Status: Expired due to Fees

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Kaczur, Jerry J., Cawlfield, David W.
• Primary Examiner(s): Niebling, John
• Assistant Examiner(s): Phasge, Arun S.
• Application Number:
  US07/867,557
• Time in Patent Office: 659 Days
• Field of Search: 204/98, 204/182.4, 204/182.5, 204/96, 204/129
• US Class Current: 205/511
• CPC Class Codes: B01D 61/445 with bipolar membranes; Water splitting
• CPC Class Codes: B01D 61/52 Accessories; Auxiliary operation
• CPC Class Codes: C01D 1/40 by electrolysis

Abstract

A bipolar water ionizing electrode and a process employing such an electrode in an electrodialytic cell are disclosed. The cell has a plurality of ion exchange compartments separated by cation permselective membranes and the bipolar water ionizing electrode. The bipolar electrode is permeable to gas and electric current and impervious to liquid.

Claims

1. An electrodialytic process for producing an alkali solution from a salt comprising the steps of:

a. separating at least one central ion exchange compartment from a first adjacent ion exchange compartment by a bipolar water ionizing electrode on the side of the central ion exchange compartment closer to a cathode and from a second adjacent ion exchange compartment by a first cation permselective membrane positioned on the side of said central ion exchange compartment closer to an anode;

(b) separating a second adjacent ion exchange compartment and an anode compartment by a second cation permselective membrane;

(c) separating a first adjacent ion exchange compartment and a cathode compartment by a third cation permselective membrane;

(d) feeding a sodium carbonate solution to the first adjacent ion exchange compartment and the second adjacent ion exchange compartment;

(e) feeding an anolyte solution into the anode compartment;

(f) feeding a catholyte solution to the cathode compartment;

(g) generating hydrogen ions in the anode compartment and transporting those hydrogen ions through said second cation permselective membrane to said second adjacent ion exchange compartment to produce carbon dioxide;

(h) transporting sodium ions through the first cation permselective membrane from said second adjacent ion exchange compartment to the central ion exchange compartment;

(i) reducing water in the central ion exchange compartment with the bipolar water ionizing electrode; and

(j) combining the transported sodium ions with hydroxyl ions produced in the central ion exchange compartment to form sodium hydroxide.

2. The process according to claim 1 further comprising transporting sodium ions in a first ion exchange compartment to the cathode compartment to combine with the catholyte solution to form sodium hydroxide.

3. The process according to claim 2 further comprising using an anolyte solution selected one from the group consisting of aqueous solutions of brine, sodium sulfate and an acid.

4. The process according to claim 3 further comprising sulfuric acid as the anolyte solution.

5. The process according to claim 2 further comprising selecting the catholyte solution from one from the group consisting of aqueous solutions of brine, sodium sulfate and a base.

6. The process according to claim 5 further comprising using sodium hydroxide as the base.

7. The process according to claim 1 further comprising filling the first ion exchange compartment and the second ion exchange compartment with ion exchange resin.