Method for the preparation of electrostatographic toner of controlled shape by evaporative limited coalescence

• US 5,283,151 A
• Filed: 05/28/1992
• Issued: 02/01/1994
• Est. Priority Date: 05/28/1992
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Santilli, Domenic
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US07/890,060
• Time in Patent Office: 614 Days
• Field of Search: 430/106, 430/106.6, 430/109, 430/110, 430/137
• US Class Current: 430/137.14
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/0812 Pretreatment of components
• CPC Class Codes: G03G 9/08782 Waxes
• CPC Class Codes: G03G 9/09 Colouring agents for toner particles

Abstract

A method is described for the preparation of electrostatographic toner particles which involves the use of carnauba wax for treating the surface of a pigment employed The method involves recrystallizing carnauba wax from its natural state by dissolution in ethyl acetate and cooling to precipitate needle like structures The structures so obtained are then added to a mixture comprising a pigment, a polymer material, a solvent and optionally a charge control agent which mixture serves as the organic phase in a limited coalescence process. The toner particles produced in accordance with this method are non spherical in nature and evidence excellent fluidity and anti-blocking properties.

Claims

1. A method for the preparation of electrostatographic toner comprising the steps of:

(a) mixing carnauba wax in a first solvent heated to a temperature sufficient to dissolve the wax and cooling the resultant solution, so resulting in the precipitation of the wax in the form of fine needle-like structures;

(b) mixing the wax needles with a polymer material, a pigment, a second solvent and optionally a charge control agent to form an organic phase;

(c) dispersing the organic phase in an aqueous phase comprising a promoter and a particulate stabilizer and homogenizing the resultant mixture; and

(d) evaporating the second solvent and washing and drying the resultant product.

2. The method of claim 1 wherein the first solvent and the second solvent are the same.

3. The method of claim 1 wherein the first and second solvents are ethyl acetate.

4. The method of claim 1 wherein the pigment to wax ratio ranges from 1:

1 to 1;

0.05.

6. The method of claim 1 wherein the polymer material is butyl acrylate-styrene copolymer.

7. The method of claim 1 wherein the pigment employed comprises from 2.0 to 30.0%, by weight, of total solids present including wax.

8. The method of claim 1 wherein the pigment employed comprises carbon black.

9. The method of claim 1 wherein the pigment employed comprises bridged aluminum phthalocyanine.

16. Electrostatographic toner prepared in accordance with the method of claim 1.

18. Electrostatographic toner in accordance with claims 16 or 17 comprising carbon black and being non-spherical in shape.

5. The method of claim I wherein the particulate stabilizer is selected from the group consisting of highly cross-linked latex particles and SiO₂.

10. In a method for preparing electrostatographic toner by dispersing an organic phase in an aqueous phase to yield a layer of particulate stabilizer on the surface of a polymer, the improvement which comprises adding carnauba wax in a solvent to a polymer material, a pigment and optionally a charge control agent to form an organic phase for dispersing in the aqueous phase.

11. The method of claim 10 wherein the solvent is ethyl acetate.

12. The method of claim 10 wherein the polymer is butyl acrylate-styrene copolymer.

13. The method of claim 10 wherein the pigment to carnauba wax ration ranges from about 1:

1 to 1;

0.05.

14. The method of claim 10 wherein the pigment employed comprises carbon black.

15. The method of claim 10 wherein the pigment employed comprises bridged aluminum phthalocyanine.

17. Electrostatographic toner prepared in accordance with the method of claim 10.