All-optical modulation in crystalline organic semiconductor waveguides

• US 5,287,421 A
• Filed: 01/11/1993
• Issued: 02/15/1994
• Est. Priority Date: 01/11/1993
• Status: Expired due to Term

• Current Assignee: University of Southern California
• Original Assignee: University of Southern California
• Inventors: Zang, De Yu, Forrest, Stephen R.
• Primary Examiner(s): Ullah, Akm E.
• Application Number:
  US08/003,021
• Time in Patent Office: 400 Days
• Field of Search: 385/2, 385/3, 385/4, 385/5, 385/9, 385/13, 385/28, 385/129, 385/130, 385/132, 385/147, 385/146
• US Class Current: 385/5
• CPC Class Codes: G02F 1/065 in an optical waveguide structure
• CPC Class Codes: G02F 1/3515 All-optical modulation, gating, switching, e.g. control of a light beam by another light beam G02F1/353, G02F1/37, G02F1/39 take precedence
• CPC Class Codes: G02F 1/361 Organic materials
• CPC Class Codes: G02F 1/365 in an optical waveguide structure G02F1/377, G02F1/395 take precedence

Abstract

All-optical modulation occurs in crystalline organic semiconductor waveguides (10a) grown by the ultrahigh vacuum process of organic molecular-beam deposition onto substrates (10b). Two light beams with wavelengths of 1.06 and 0.514 μm from a first source (12) and a second source (34), respectively, may be used as the guided and the pump light sources, respectively. A resonant non-linear coefficient at room temperature of 5.4×10^-5 cm² /W at 1.06 μoccurs at a pump intensity of 1.0 W/cm². This large non-linear effect is attributed to free electron-hole pairs produced by the dissociation of excitons generated by the short wavelength beam. A carrier lifetime of (17±1) us, which determines the modulator switching time, is in good agreement with theoretical predictions. This appears to be the first observation of free-carrier-induced index modulation in crystalline organic waveguides.

Claims

1. An improved method of modulating light in at least one waveguide, comprising:

(a) providing said at least one waveguide;

(b) introducing light from a first source into said waveguide;

(c) introducing light from a second source at an angle to said waveguide to cause modulation of said light from said first source,

wherein the improvement comprises fabricating said waveguide from a crystalline organic aromatic semiconductor compound having a resonant non-linear coefficient of at least 10^-6 cm^-2 /W at room temperature and grown in a quasi-epitaxial structure.

2. The method of claim 1 wherein said crystalline organic aromatic semiconductor compound comprises a polyacene compound having at least two fused benzene rings.

3. The method of claim 2 wherein said crystalline organic aromatic semiconductor compound is planar.

4. The method of claim 3 wherein said crystalline organic aromatic semiconductor compound comprises 3,4,9,10-perylenetetracarboxylic dianhydride.

5. The method of claim 1 wherein said light from said first source has a wavelength of about 1.06 μ

m.

6. The method of claim 1 wherein said light from said source has a wavelength of about 0.514 μ

m.

7. The method of claim 1 wherein said waveguide is formed in the shape of a strip having a substantially rectangular cross-section and having faceted ends suitable for waveguiding light, with light from said first source introduced into one of said faceted ends and with light from said second source introduced orthogonal thereto.

8. The method of claim 7 wherein light from said second source is introduced onto the top of said waveguide.

9. The method of claim 1 wherein light is modulated in a directional coupler switch comprising two waveguides supported on a substrate, said directional coupler comprising (a) a coupled region in which said two waveguides are separated by a first distance and (b) two guiding regions on either side of said coupled region in which said two waveguides are separated by a second distance, said second distance greater than said first distance, said first distance having a value to permit switching of light from one waveguide to the other.

10. The method of claim 9 wherein light from said first source is introduced into a first of said waveguides and light from said second source is introduced onto the top of at least said first waveguide, with light from said second source causing light in said first waveguide to switch into the other waveguide.

11. The method of claim 1 wherein said organic semiconductor compound has a carrier lifetime that is reduced by forming said compound in a multiple-quantum-well structure.

12. The method of claim 1 wherein said organic semiconductor compound has a carrier lifetime that is reduced by electrically injecting holes therein from a contact, and then sweeping them out using an applied electric field.

13. An improved method of modulating light in at least one waveguide, comprising:

(a) providing said at least one waveguide;

(b) introducing light from a first source into said waveguide;

(c) introducing light from a second source at an angle to said waveguide to cause modulation of said light from said first source,

wherein the improvement comprises fabricating said waveguide from a planar stacking crystalline organic aromatic semiconductor compound having a resonant non-linear coefficient of at least 10^-5 cm² /W at room temperature and grown in a quasi-epitaxial structure.

14. The method of claim 13 wherein said crystalline organic aromatic semiconductor compound comprises a polyacene compound having four fused benzene rings.

15. The method of claim 14 wherein said crystalline organic aromatic semiconductor compound comprises 3,4,9,10-perylenetetracarboxylic dianhydride.

16. The method of claim 13 wherein said light from said first source has a wavelength of about 1.06 μ

m.

17. The method of claim 13 wherein said light from said second source has a wavelength of about 0.514 μ

m.