Electroless plating catalyst

• US 5,288,313 A
• Filed: 05/31/1990
• Issued: 02/22/1994
• Est. Priority Date: 05/31/1990
• Status: Expired due to Term

• Current Assignee: Shipley Company, Inc.
• Original Assignee: Shipley Company, Inc.
• Inventors: Portner, J. Claude
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): EINSMANN, MARGARET V
• Application Number:
  US07/531,156
• Time in Patent Office: 1,363 Days
• Field of Search: 106/1.11-1.28
• US Class Current: 106/1.11
• CPC Class Codes: C23C 18/30 Activating or accelerating or sensitising with palladium or other noble metal
• CPC Class Codes: H05K 9/0084 comprising a single continuous metallic layer on an electrically insulating supporting structure, e.g. metal foil, film, plating coating, electro-deposition, vapour-deposition

Abstract

The invention discloses a new electroless plating catalyst and a process of using the same for selective plating. The catalyst and process are especially adapted for formation of EMI shielding for electronic components. The electroless plating catalyst comprises catalytic particulates dispersed in a liquid film forming composition.

Claims

1. An electroless plating catalyst solution comprising a polymer solution having a mixture of catalytic particles homogeneously dispersed therein, said mixture of catalytic particles comprising first catalytic particles of a reduced platinum family metal absorbed into an inert particulate carrier and second catalytic particles of reduced silver adsorbed onto an inert particulate carrier, said particles having a metals content whereby the weight ratio of silver to the platinum family metal varies between about 100:

1 and 1;

1.

2. The catalyst solution of claim 1 where the particle size of the inert particulate carrier particles range between 1 and 100 microns.

3. The catalyst solution of claim 1 where the liquid film forming coating composition is a varnish.

4. The catalyst solution of claim 1 where the liquid film forming coating composition contains a polymer selected from the group consisting of phenolics, epoxies, alkyds, polyesters, acrylics, polyurethanes and polyamides.

5. The catalyst solution of claim 1 where the concentration of said platinum family metal in the electroless plating catalyst varies from about 0.1 to 100 grams per liter of solution.

6. The catalyst solution of claim 5 where the concentration of said platinum family metal varies from about 1.0 to 10.0 grams per liter of solution.

7. The catalyst solution of claim 1 where the concentration of silver in the electroless plating catalyst varies from about 1.0 to 100 grams per liter of solution.

8. The catalyst solution of claim 7 where the concentration varies from about 3.0 to 20.0 grams per liter of solution.

9. The catalyst solution of claim 1 wherein the concentration of said platinum family metal varies from about 1.0 to 10 grams per liter of solution, the concentration of silver varies from about 3.0 to 20 grams per liter of solution and the weight ratio of silver to the platinum family metal varies between about 50:

1 and 2;

1.

10. The catalyst solution of claim 9 where the weight ratio of silver to the platinum family metal varies between from about 20:

1 and 5;

1.

11. The catalyst solution of claim 9 where the weight ratio of catalytic metal to inert particulate carrier varies between about 1:

50 and 1;

3.

12. The catalyst solution of claim 9 where the total of the platinum family metal and the silver in the electroless plating catalyst varies between 0.1 and 50 grams per liter.

13. The catalyst solution of claim 12 where the total of the platinum family metal and the silver varies between 10.0 and 25 grams per liter.

14. The catalyst solution of claim 1 where the weight ratio of the catalytic particles to the polymer content of the solution varies between 2:

1 and 50;

1.

15. The catalyst solution of claim 1 where the weight ratio of the catalytic particles to the polymer content of the solution varies between 3:

1 and 25;

1.

16. The catalyst solution of claim 1 where the platinum family metal is palladium.

17. The catalyst solution of claim 1 where the inert particulate carrier is chosen from the group of irregularly shaped particles selected from the group of carbon, glass, titania or silica.

18. The catalyst solution of claim 17 where the inert particulate carrier is silica.

19. An electroless plating catalyst solution consisting essentially of a polymer solution having a mixture of catalytic particles homogeneously dispersed therein, said mixture of catalytic particles consisting essentially of first catalytic particles of reduced palladium absorbed onto an inert particulate silica carrier and second catalytic particles of reduced silver adsorbed onto an inert particulate carrier, said particles having a metal content whereby the weight ratio of silver to palladium varies between about 100:

1 and 1;

1.

20. The catalyst solution of claim 19 where the particle size of the silica particles range between 1 and 100 microns.

21. The catalyst solution of claim 20 where the particle size of the particles range between 1 and 25 microns.

22. The catalyst solution of claim 19 where the palladium absorbed onto the inert particulate carrier is the reaction product of palladium ions and stannous tin and the silver adsorbed onto the inert particulate carrier is the reaction product of a silver compound and stannous tin.

23. The catalyst solution of claim 22 where the polymer solution is a solution of a polymer selected from the group consisting of phenolics, epoxies, alkyds, polyesters, acrylics, polyurethanes and polyamides.

24. The catalyst solution of claim 22 where the concentration of palladium in the electroless plating catalyst varies from about 0.1 to 100 grams per liter of solution.

25. The catalyst solution of claim 24 where the concentration of palladium varies from about 1.0 to 10.0 grams per liter of solution.

26. The catalyst solution of claim 22 where the concentration of silver in the electroless plating catalyst varies from about 1.0 to 100 grams per liter of solution.

27. The catalyst solution of claim 26 where the concentration of silver varies from about 3.0 to 20.0 grams per liter of solution.

28. The catalyst solution of claim 22 where the concentration of palladium in the electroless plating catalyst varies from about 0.1 to 10 grams per liter of solution, the concentration of silver varies from about 3.0 to 20 grams per liter of solution and the weight ratio of silver to palladium varies between about 50:

1 and 2;

1.

29. The catalyst solution of claim 28 where the weight ratio of catalytic metal to inert particulate carrier varies between about 1:

50 and 1;

3.

30. The catalyst solution of claim 29 where the weight ratio of the catalytic particles to the polymer content of the solution varies between 2:

1 and 50;

1.

31. The catalyst solution of claim 30 where the weight ratio of the catalytic particles to the polymer content of the solution varies between 3:

1 and 25;

1.