Cellulose acetate and starch based biodegradable injection molded plastics compositions and methods of manufacture

• US 5,288,318 A
• Filed: 07/01/1993
• Issued: 02/22/1994
• Est. Priority Date: 07/01/1993
• Status: Expired due to Fees

• Current Assignee: United States Of America As Represented By The Secretary Of The Army (Government of the United States of America), The United States of America As Represented By The Secretary of Agriculture
• Original Assignee: The United States Of America As Represented By The Secretary Of The Army
• Inventors: Mayer, Jean M., Elion, Glenn R.
• Primary Examiner(s): Group, Karl
• Assistant Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/088,961
• Time in Patent Office: 236 Days
• Field of Search: 106/196, 106/210, 106/211, 106/213, 106/214, 106/203, 106/204, 264/211.12, 264/211, 536/69, 536/102
• US Class Current: 106/126.3
• CPC Class Codes: C08L 1/12 Cellulose acetate
• CPC Class Codes: C08L 2201/06 Biodegradable
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 3/02 Starch; Degradation products thereof, e.g. dextrin

Abstract

A method and composition are provided for making biodegradable injection ded parts from 30% to 70% cellulose acetate, 10% to 60% unmodified raw (whole) starch and 5% to 35% plasticizer including glycerols and glycerol acetates. Other ingredients that can be used include: starch, flour and paper acetates; gelatin; boric acid; and agricultural fillers. The solid ingredients are combined and fed to an extruder used to make pellets or to feed injection molding equipment. The resulting parts are clear to white or colorful depending upon the added filler materials. The plastics formed are water resistant, high strength and biodegradable.

Claims

1. A biodegradable plastic comprising:

between about 10% to 60% by weight starch which contains more than 3% intact starch granules;

between 30% to 70% cellulose acetate which has a molecular weight ranging from 28,000 to 62,000 Daltons and a viscosity of 3 to 44 seconds; and

between 5% and 35% of a plasticizer selected from the group consisting of triacetin, diacetin, monoacetin, ethylene glycol, propylene glycol and glycerol.

2. The biodegradable plastic of claim 1 wherein the said plasticizer is a blend of two or more of those listed in the group consisting of triacetin, diacetin, monoacetin, ethylene glycol, propylene glycol and glycerol.

3. The biodegradable plastic of claim 1 further comprising between about 0.1% to 3% by weight boric acid.

4. The biodegradable plastic of claim 1 further comprising between about 0.5% and 8% by weight gelling agent selected from the group consisting of gellan gum, xanthum gum, alkali alginates and Carrageenan.

5. The biodegradable plastic of claim 1 further comprising between about 0.5% and 8% by weight shellac.

6. The biodegradable plastic of claim 1 further comprising between about 0.5% and 10% by weight of an agricultural filler selected from the group consisting of milled crustacean shell and nut shell powders.

7. The biodegradable plastic of claim 1 wherein the said starch is selected from the group consisting of corn, tapioca, potato, sago, wheat, rye, pea, sorghum, rice and arrowroot starch.

8. The biodegradable plastic of claim 1 wherein the said starch is cornstarch.

9. The biodegradable plastic of claim 8 wherein the said cornstarch contains between about 30% and 75% amylose.

10. The biodegradable plastic of claim 1 wherein the said cellulose acetate is partially substituted with paper acetate in the weight range of 1% to 40% by weight.

11. The biodegradable plastic of claim 1 wherein the said cellulose acetate is partially substituted with natural fiber acetate in the weight range of 1% to 8% by weight.

12. The biodegradable plastic of claim 1 wherein the said cellulose acetate is partially substituted with starch acetate in the weight range of 1% to 40% by weight.

13. The biodegradable plastic of claim 1 wherein the said cellulose acetate is partially substituted with flour acetate in the weight range of 1% to 40% by weight.

14. The biodegradable plastic of claim 1 wherein the said cellulose acetate is partially substituted with a blend of acetate materials and wherein the total acetate substitution blend is in the weight range of 1% to 40%.

15. An extruded or molded product formed from the biodegradable plastic of claim 1 wherein the said extruded or molded product has a tensile strength of at least about 2,400 psi.

16. A method of forming a biodegradable plastic, the method comprising the following steps:

combining on a per weight basis between about 10% to 60% by weight whole starch granules, and between 30% to 70% cellulose acetate which has a molecular weight ranging from 28,000 to 62,000 and a viscosity of 3 to 44 seconds to form a first mixture of dry ingredients;

combining between 5% and 35% of a plasticizer selected from the group consisting of triacetin, diacetin, monoacetin, ethylene glycol, propylene glycol and glycerol, with said first mixture of dry ingredients to form a free flowing second mixture;

extruding said second mixture through a die to form pellets of plastic having at least 3% intact starch granules; and

processing the pellets through an injection molder to produce molded items.

17. The method of claim 16 wherein a temperature between 100°

C. and 170°

C. is maintained for all heated zones including the die.

18. A method of forming a biodegradable plastic, the method comprising the following steps:

combining on a per weight basis between about 10% to 60% by weight whole starch granules, and between 30% to 70% cellulose acetate which has a molecular weight ranging from 28,000 to 62,000 and a viscosity of 3 to 44seconds to form a first mixture of dry ingredients;

combining between 5% and 35% of a plasticizer selected from the group consisting of triacetin, diacetin, monoacetin, propylene glycol, glycerol and ethylene glycol, to said first mixture of dry ingredients to form a second mixture which is a free flowing uniform powder; and

extruding said second mixture through a heated barrel directly into injection molds to form a plastic having at least 3% intact starch granules.

19. The method of claim 18 wherein a temperature between 100°

C. and 170°

C. is maintained for all heated zones including the heated barrel.